Azeotrope or azeotrope-like compositions of trifluoroiodomethane (CF
The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF 3 I) and trifluoroacetyl chloride (CF 3 COCl), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I) to form an azeotrope or azeotrope-like composition.
1. A composition comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I).
2. The composition of claim 1 , wherein the azeotrope or azeotrope-like composition has a boiling point between about −46.0° C. and about 90.0° C. at a pressure of between about 4.9 psia and about 348 psia.
3. The composition of claim 2 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 0.5 wt. % to about 99.0 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 1.0 wt. % to about 99.5 wt. % trifluoroiodomethane (CF 3 I).
4. The composition of claim 1 , wherein the azeotrope or azeotrope-like composition has a boiling point of about −22.50° C.±0.30° C. at a pressure of about 14.41 psia±0.30 psia.
5. The composition of claim 2 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 0.5 wt. % to about 25 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 75 wt. % to about 99.5 wt. % trifluoroiodomethane (CF 3 I).
6. The composition of claim 2 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 2 wt. % to about 21 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 79 wt. % to about 98 wt. % trifluoroiodomethane (CF 3 I).
7. The composition of claim 2 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 14 wt. % to about 18 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 82 wt. % to about 86 wt. % trifluoroiodomethane (CF 3 I).
8. The composition of claim 1 , comprising an azeotrope or azeotrope-like composition consisting essentially of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I) and having a boiling point of about −22.50° C.±0.30° C. at a pressure of about 14.41 psia±0.30 psia.
9. The composition of claim 8 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 0.5 wt. % to about 25 wt. % trifluoroacetyl chloride (CF 3 COCl)) and from about 75 wt. % to about 99.5 wt. % trifluoroiodomethane (CF 3 I).
10. The composition of claim 8 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 2 wt. % to about 21 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 79 wt. % to about 98 wt. % trifluoroiodomethane (CF 3 I).
11. The composition of claim 8 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 14 wt. % to about 18 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 82 wt. % to about 86 wt. % trifluoroiodomethane (CF 3 I).
12. A method of separating an azeotrope or azeotrope-like mixture of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I), comprising:
conveying a feed stream comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I) to a low-pressure column to provide a first bottoms product and a first distillate;
collecting the first bottoms product from the low-pressure column;
conveying the first distillate from the low-pressure column to a high-pressure column, the first distillate comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I); and
collecting a second bottoms product from the high-pressure column.
13. The method of claim 12 , wherein the azeotrope or azeotrope-like composition consists essentially of from about 0.5 wt. % to about 99.0 wt. % trifluoroacetyl chloride (CF 3 COCl) and from about 1.0 wt. % to about 99.5 wt. % trifluoroiodomethane (CF 3 I).
14. The method of claim 13 , wherein the azeotrope or azeotrope-like composition has a boiling point between about −46.0° C. and about 90.0° C. at a pressure of between about 4.9 psia and about 348 psia.
15. The method of claim 12 , wherein the first bottoms product consists essentially of trifluoroacetyl chloride (CF 3 COCl).
16. The method of claim 12 , wherein the second bottoms product consists essentially of trifluoroiodomethane (CF 3 I).
17. The method of claim 12 , wherein the first bottoms product consists essentially of trifluoroiodomethane (CF 3 I).
18. A method of separating trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I) from a primary composition comprising trifluoroacetyl chloride (CF 3 COCl), trifluoroiodomethane (CF 3 I) and at least one impurity, comprising the steps of:
forming, within the primary composition, a secondary composition which is an azeotrope or azeotrope-like composition consisting essentially of effective amounts of trifluoroacetyl chloride (CF 3 COCl) and trifluoroiodomethane (CF 3 I) having a boiling point between about −46.0° C. and about 90.0° C. at a pressure of between about 4.9 psia and about 348 psia; and
separating the secondary composition from the primary composition and the at least one impurity.
19. The method of claim 18 , comprising the additional steps, prior to the forming step, of:
providing a composition which includes one of trifluoroiodomethane (CF 3 I) and trifluoroacetyl chloride (CF 3 COCl), together with at least one impurity; and
adding a sufficient amount of the other of trifluoroiodomethane (CF 3 I) and trifluoroacetyl chloride (CF 3 COCl).