IP Library Granted Patent US 12,263,890
Granted Patent B2
US 12,263,890 · App. 16/875,472 · Granted Apr 1, 2025

High-forming multi-layer aluminum alloy package

Inventors: Guillaume Florey (Veyras, CH); Cyrille Bezencon (Chermignon, CH); Corrado Bassi (Salgesch, CH); Juergen Timm (Steisslingen, DE); Jean-Francois Despois (Grone, CH); Jacques Stadlin (Pont-de-la-Morge, CH)
Assignee: NOVELIS INC.
B62D29/008B22D7/005B32B15/016C22C21/00C22C21/02C22C21/08C22F1/04C22F1/043C22F1/047
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Quick Facts
Patent No.
US 12,263,890
App. No.
16/875,472
Granted
Apr 1, 2025
Kind
B2
Abstract

Provided herein are novel, high-forming multi-layer aluminum alloy packages that include a core layer and one or more cladding layers. The alloy packages have excellent bake-hardening properties and are highly recyclable. The packages also display exceptional bendability and elongation properties. Also provided herein are novel aluminum alloy compositions for use as cladding layers. The compositions contain up to 0.6 wt. % Fe and one or more of Mn, Ni, Ti, Co, Nb, Cr, V, Zr, Hf and Ta.

Claims (24)

1. An aluminum alloy for a cladding layer, the aluminum alloy comprising 0.2 to 0.6 wt. % Fe, 0.06 to 0.25 wt. % Mn, up to 0.25 wt. % Si, up to 0.5 wt. % Cu, up to 1.5 wt. % Mg, up to 0.4 wt. % Zn, one or more additional elements selected from the group consisting of Ni, Ti, Co, Nb, Cr, V, Zr, Hf and Ta, up to 0.15 wt. % impurities, and Al; wherein the aluminum alloy comprises a total amount of Ni, V, and Co greater than 0.20 wt. %; wherein at least one of Ni or Co is present in an amount of 0.05 to 0.60 wt. %; wherein the aluminum alloy comprises grains having an average grain size from 10 microns to less than 30 microns;

wherein the aluminum alloy is subjected to hot rolling to produce a rolled aluminum alloy product;

wherein the rolled aluminum alloy product exhibits an elongation at break of at least 20% in directions longitudinal, transverse, and diagonal to a rolling direction of the rolled aluminum alloy product; and

wherein the rolled aluminum alloy product exhibits a bend angle of lower than 9° after being subjected to uniaxial pre-straining at 15% at 90° to the rolling direction and/or ageing at 180° C. for up to 10 hours.

2. The aluminum alloy of claim 1 , comprising 0.25 to 0.55 wt. % Fe, 0.08 to 0.20 wt. % Mn, up to 0.25 wt. % Si, up to 0.25 wt. % Cu, up to 0.25 wt. % Mg, up to 0.20 wt. % Zn, one or more additional elements selected from the group consisting of Ni, Ti, Co, Nb, Cr, V, Zr, Hf and Ta, up to 0.15 wt. % impurities, and Al.

3. The aluminum alloy of claim 1 , comprising 0.25 to 0.55 wt. % Fe, 0.08 to 0.20 wt. % Mn, up to 0.12 wt. % Si, up to 0.05 wt. % Cu, 0.3 to 1.2 wt. % Mg, up to 0.05 wt. % Zn, one or more additional elements selected from the group consisting of Ni, Ti, Co, Nb, Cr, V, Zr, Hf and Ta, up to 0.15 wt. % impurities, and Al.

4. The aluminum alloy of claim 1 , wherein the one or more additional elements comprises Ti in an amount of from 0.01 to 0.15 wt. %.

5. The aluminum alloy of claim 1 , wherein the one or more additional elements comprises V in an amount of from 0.01 to 0.2 wt. %.

6. The aluminum alloy of claim 1 , wherein the one or more additional elements comprises Ni in an amount of from 0.01 to 0.60 wt. %.

7. The aluminum alloy of claim 1 , wherein the one or more additional elements comprises Co in an amount of from 0.01 to 0.60 wt. %.

8. The aluminum alloy of claim 1 , wherein the one or more additional elements comprises Nb in an amount of from 0.01 to 0.3 wt. %, Cr in an amount of from 0.01 to 0.2wt. %, Zr in an amount of from 0.01 to 0.25 wt. %, Hf in an amount of from 0.01 to 0.30 wt. %, or Ta in an amount of from 0.01 to 0.20 wt. %.

9. The aluminum alloy of claim 1 , comprising 0.2 to 0.5 wt. % Fe, up to 0.25 wt. % Si, up to 0.25 wt. % Cu, 0.1 to 0.2 wt. % Mn, up to 0.1 wt. % Mg, up to 0.15 wt. % Cr, up to 0.20 wt. % Zn, up to 0.6 wt. % Ni, up to 0.12 wt. % Ti, up to 0.6 wt. % Co, up to 0.2 wt. % Nb, up to 0.18 wt. % V, up to 0.25 wt. % Zr, up to 0.30 wt. % Hf, up to 0.15 wt. % Ta, up to 0.15 wt. % impurities, and Al.

10. The aluminum alloy of claim 1 , wherein the combined content of Fe, Mn, Cr, Ti, Co, Ni, and V present in the aluminum alloy ranges from 0.60 wt. % to 0.90 wt. %.

11. The aluminum alloy of claim 1 , wherein the average grain size is from 15 microns to 25 microns.

12. The aluminum alloy of claim 1 , wherein the aluminum alloy comprises 0.05 wt. % to 0.15 wt. % Ti.

13. A multi-layer metal sheet comprising:

a core layer,

a first cladding layer comprising an aluminum alloy comprising 0.2 to 0.6 wt. % Fe, 0.06 to 0.25 wt. % Mn, up to 0.20 wt. % Si, up to 0.5 wt. % Cu, up to 0.45 wt. % Mg, up to 0.4 wt. % Zn, one or more additional elements selected from the group consisting of Ni, Ti, Co, Nb, Cr, V, Zr, Hf and Ta, up to 0.15 wt. % impurities, and Al, and

a second cladding layer,

wherein the core layer comprises a first side and a second side, and the first cladding layer is adjacent to the first side of the core layer to form a first interface and the second cladding layer is adjacent to the second side of the core layer to form a second interface,

wherein the first cladding layer comprises Fe, Mn, Cr, Ti, Co, Ni and V such that the total weight-percent (wt. %) of the Fe, Mn, Cr, Ti, Co, Ni, and V is between 0.60 wt. % and 0.90 wt. %.

14. The multi-layer metal sheet of claim 13 , wherein the core layer comprises an AA6xxx alloy, an AA2xxx alloy, an AA5xxx alloy, or an AA7xxx alloy.

15. A product prepared from the multi-layer metal sheet of claim 13 , wherein the product is a motor vehicle body part.

16. The product of claim 15 , wherein the motor vehicle body part is a body side panel.

Assignments (3)
SECURITY INTEREST Recorded Mar 12, 2025
From: NOVELIS INC.; NOVELIS DEUTSCHLAND GMBH; NOVELIS KOBLENZ GMBH
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 070495/0110 →
SECURITY INTEREST Recorded Mar 11, 2025
From: NOVELIS DEUTSCHLAND GMBH; NOVELIS INC.; NOVELIS KOBLENZ GMBH
To: CITIBANK, N.A.
Reel/Frame 070481/0417 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2020
From: FLOREY, GUILLAUME; BEZENCON, CYRILLE; BASSI, CORRADO; TIMM, JUERGEN; DESPOIS, JEAN-FRANCOIS; STADLIN, JACQUES
To: NOVELIS INC.
Reel/Frame 052682/0312 →
Continuity (4)
Division 15288088 · Oct 7, 2016
Provisional Application 62302218 · Mar 2, 2016
Provisional Application 62241958 · Oct 15, 2015
Related Publication 20200277011A1 · Sep 3, 2020
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