Cracking C
A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.
1. A cracker feedstock composition comprising a recycle content pyrolysis oil composition (r-pyoil), wherein said r-pyoil has a C 8+ content of at least 35 weight percent, based on the total weight of said r-pyoil; wherein said r-pyoil comprises not more than 30 weight percent total aromatics, based on the total weight of said r-pyoil.
2. The composition of claim 1 , wherein at least 1 weight percent of said r-pyoil is obtained from the pyrolysis of recycled waste.
3. The composition of claim 1 , wherein not more than 95 weight percent of said r-pyoil is obtained from the pyrolysis of recycled waste.
4. The composition of claim 3 , wherein said recycled waste comprises recycled waste plastic.
5. The composition of claim 3 , wherein said recycled waste comprises waste plastics, waste textiles, waste carpet fibers, waste modified cellulose, waste biomass, post-industrial waste streams, intermediate industrial waste streams, or combinations thereof.
6. The composition of claim 5 , wherein at least a portion of said r-pyoil is obtained from the pyrolysis of waste plastic.
7. The composition of claim 1 , wherein said cracker feedstock has not been hydrotreated.
8. The composition of claim 7 , wherein said r-pyoil is present in said cracker feedstock in an amount of not more than 40 weight percent and at least about 1 weight percent.
9. The composition of claim 8 , wherein said cracker feedstock composition comprises at least 60 weight percent and not more than 99 weight percent of non-recycle C 2 to C 4 hydrocarbons.
10. The composition of claim 1 , wherein said cracker feedstock composition comprises at least 60 weight percent and not more than 95 weight percent of non-recycle C 5 to C 22 hydrocarbons.
11. The composition of claim 1 , wherein said cracker feedstock composition comprises at least 60 weight percent and not more than 95 weight percent of non-recycle propane, ethane, or combinations thereof.
12. The composition of claim 1 , wherein said cracker feedstock comprises predominantly propane and ethane.
13. The composition of claim 12 , wherein said cracker feedstock has a 90% boiling point of not more than 360° C. and at least 200° C.
14. The composition of claim 13 , wherein said cracker feedstock has a total C 15+ content of not more than 25 weight percent, based on the total weight of the composition.
15. The composition of claim 14 , wherein said cracker feedstock has a total C 15+ content of at least 0.5 weight percent, based on the total weight of the composition.
16. The composition of claim 15 , wherein said r-pyoil comprises not more than 25 weight percent total aromatics, based on the total weight of said r-pyoil.
17. The composition of claim 16 , wherein said r-pyoil comprises at least 1 weight percent of total aromatics, based on the total weight of said r-pyoil.
18. The composition of claim 1 , wherein said r-pyoil comprises at least 15 weight percent and not more than 80 weight percent of paraffins, based on the total weight of said r-pyoil.
19. A method of making one or more olefins, said method comprising:
(a) introducing a cracker feed stream comprising a recycle content pyrolysis oil composition (r-pyoil) into a cracker furnace, wherein said r-pyoil introduced into said cracker furnace has a C 8+ content of at least 35% by weight, based on the total weight of the r-pyoil; wherein said r-pyoil comprises not more than 30 weight percent total aromatics, based on the total weight of said r-pyoil; and
(b) cracking said cracker feed stream in said cracker furnace to thereby form a cracked olefin-containing effluent stream.
20. The method of claim 19 , wherein at least a portion of said r-pyoil is obtained from the pyrolysis of waste plastic.