Silicon-based energy storage devices with silyl amine compounds or derivatives of silyl amine containing electrolyte additives
Electrolytes and electrolyte additives for energy storage devices comprising silyl amine compounds or derivatives thereof are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from silyl amine compounds or derivatives thereof.
1. An energy storage device comprising:
a first electrode and a second electrode, wherein one or both of the first electrode and the second electrode is a Si-based electrode;
a separator between the first electrode and the second electrode;
an electrolyte; and
at least one electrolyte additive comprising a silyl amine compound or derivative thereof; wherein said silyl amine compound or derivative thereof is selected from the group consisting of (Dimethylaminomethylsilyl)bis(trimethylsilyl)amine;
Bis(dimethylaminomethylsilyl)(trimethylsilyl)amine; and N,N′-Bis(trimethylsilyl)-N,N′-bis[[(trimethylsilyl)amino]dimethylsilyl]ethylenediamine.
2. The energy storage device of claim 1 , wherein the second electrode is a Si-dominant electrode.
3. The energy storage device of claim 1 , wherein the second electrode comprises a self-supporting composite material film.
4. The energy storage device of claim 3 , wherein the composite material film comprises:
greater than 0% and less than about 90% by weight of silicon particles, and
greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases is a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.
5. The energy storage device of claim 1 , wherein the electrolyte further comprises fluoroethylene carbonate (FEC).
6. The energy storage device of claim 5 , wherein the electrolyte is substantially free of non-fluorine containing cyclic carbonate.
7. A method of forming an energy storage device, the method comprising:
forming an energy storage device comprising a cathode, an electrolyte, and an anode, wherein said electrolyte is formed by adding an electrolyte additive to an electrolyte composition and wherein said electrolyte additive is a silyl amine compound or derivative thereof; wherein said silyl amine compound or derivative thereof is selected from the group consisting of (Dimethylaminomethylsilyl)bis(trimethylsilyl)amine; Bis(dimethylaminomethylsilyl)(trimethylsilyl)amine; and N,N′-Bis(trimethylsilyl)-N,N′-bis[[(trimethylsilyl)amino]dimethylsilyl]ethylenediamine.
8. The method of claim 7 , wherein the anode is a Si-dominant electrode.
9. The method of claim 7 , wherein the anode comprises a self-supporting composite material film.
10. The method of claim 9 , wherein the composite material film comprises:
greater than 0% and less than about 90% by weight of silicon particles, and
greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases is a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.
11. The method of claim 7 , wherein the electrolyte further comprises fluoroethylene carbonate (FEC).
12. The method of claim 11 , wherein the electrolyte is substantially free of non-fluorine containing cyclic carbonate.