IP Library Granted Patent US 11,305,232
Granted Patent B2
US 11,305,232 · App. 16/892,171 · Granted Apr 19, 2022

Filtration systems and methods

Inventors: Ru Chen (Dublin, CA); Franklin Paul Barcinas (Stockton, CA); Ian W. Kaye (Livermore, CA)
Assignee: ULTRACELL LLC
B01D61/025B01D61/027B01D61/58H01M8/1011B01D2311/04
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Quick Facts
Patent No.
US 11,305,232
App. No.
16/892,171
Granted
Apr 19, 2022
Kind
B2
Abstract

Filtration systems and methods for purifying windshield washer fluid to yield methanol pure enough for fueling methanol fuel cell systems. Pumping commercially available windshield washer fluid through filtration systems having one or more filters can remove additives from the windshield washer fluid. The filtration systems include filters, such as activated carbon filters, nanofiltration filters, reverse osmosis filters, and ion exchange resin filters.

Claims (30)

1. A purified windshield washer fluid having evaporation residue less than 1000 ppmW, wherein the purified windshield washer fluid is produced by a process comprising the steps of:

providing a windshield washer fluid comprising methanol and at least one other compound, wherein a concentration of the methanol is 50 wt % or higher; and

passing the windshield washer fluid through a filtration system comprising at least one filter, wherein the at least one filter is selected from the group consisting of: an activated carbon filter, a membrane separation filter, and an ion exchange resin filter, wherein the windshield washer fluid contains 1.3 wt % 2-butoxyethanol and the purified windshield washer fluid contains 0.31 wt % 2-butoxyethanol.

2. A purified windshield washer fluid having evaporation residue less than 1000 ppmW, wherein the purified windshield washer fluid is produced by a process comprising the steps of:

providing a windshield washer fluid comprising methanol and at least one other compound, wherein a concentration of the methanol is 50 wt % or higher; and

Passing the windshield washer fluid through a filtration system comprising at least one filter, wherein the at least one filter is selected from the group consisting of: an activated carbon filter, a membrane separation filter, and an ion exchange resin filter, wherein the windshield washer fluid contains 1.3 wt % 2-butoxyethanol and the purified windshield washer fluid contains 0.26 wt % 2-butoxyethanol.

3. A purified windshield washer fluid having evaporation residue less than 1000 ppmW, wherein the purified windshield washer fluid is produced by a process comprising the steps of:

providing a windshield washer fluid comprising methanol and at least one other compound, wherein a concentration of the methanol is 50 wt % or higher; and

passing the windshield washer fluid through a filtration system comprising at least one filter, wherein the at least one filter is selected from the group consisting of: an activated carbon filter, a membrane separation filter, and an ion exchange resin filter, wherein the windshield washer fluid contains 1.3 wt % 2-butoxyethanol and the purified windshield washer fluid contains 0.26 wt %-0.31 wt % 2-butoxyethanol.

4. A purified windshield washer fluid having evaporation residue less than 1000 ppmW, wherein the purified windshield washer fluid is produced by a process comprising the steps of:

providing a windshield washer fluid comprising methanol and at least one other compound, wherein a concentration of the methanol is 50 wt % or higher; and

passing the windshield washer fluid through a filtration system comprising at least one filter, wherein the at least one filter is selected from the group consisting of: an activated carbon filter, a membrane separation filter, and an ion exchange resin filter, wherein the windshield washer fluid contains 2-butoxyethanol and a mass fraction of the 2-butoxyethanol in the purified windshield washer fluid contains about 20%-23.8% of a mass fraction of 2-butoxyethanol in the windshield washer fluid before passing the windshield washer fluid through the filtration system.

5. The purified windshield washer fluid as recited in claim 3 , wherein the at least one filter is an activated carbon filter and the filtration system further comprises a membrane separation filter.

6. The purified windshield washer fluid as recited in claim 5 , wherein the membrane separation filter is a nanofiltration filter.

7. The purified windshield washer fluid as recited in claim 5 , wherein the membrane separation filter is a reverse osmosis filter.

8. The purified windshield washer fluid as recited in claim 5 , wherein the filtration system further comprises an ion exchange resin filter.

9. The purified windshield washer fluid as recited in claim 8 , wherein the filtration system comprises two membrane separation filters in series.

10. The purified windshield washer fluid as recited in claim 3 , wherein the purified windshield washer fluid has evaporation residue less than 500 ppmW.

11. The purified windshield washer fluid as recited in claim 3 , wherein the purified windshield washer fluid has evaporation residue less than 100 ppmW.

12. The purified windshield washer fluid as recited in claim 3 , wherein the purified windshield washer fluid has evaporation residue less than 10 ppmW.

13. The purified windshield washer fluid as recited in claim 3 , wherein evaporation residue of the windshield washer fluid is reduced from over 4,000 ppmW to less than 10 ppmW after passing through the filtration system.

14. The purified windshield washer fluid as recited in claim 2 , wherein the at least one filter comprises an activated carbon filter and a membrane separation filter.

15. The purified windshield washer fluid as recited in claim 4 , wherein evaporation residue of the windshield washer fluid is over 4,000 ppmW and evaporation residue of the purified windshield washer fluid is less than 10 ppmW.

16. The purified windshield washer fluid as recited in claim 1 , wherein the at least one filter comprises an activated carbon filter and a membrane separation filter.

17. The purified windshield washer fluid as recited in claim 4 , wherein the windshield washer fluid contains 1.3 wt % 2-butoxyethanol and the purified windshield washer fluid contains 0.26 wt %.

18. The purified windshield washer fluid as recited in claim 4 , wherein the windshield washer fluid contains 1.3 wt % 2-butoxyethanol and the purified windshield washer fluid contains 0.31 wt %.

19. The purified windshield washer fluid as recited in claim 4 , wherein the at least one filter is an activated carbon filter and the filtration system further comprises a reverse osmosis filter.

20. The purified windshield washer fluid as recited in claim 4 , wherein the purified windshield washer fluid has evaporation residue less than 500 ppmW.

21. The purified windshield washer fluid as recited in claim 4 , wherein the purified windshield washer fluid has evaporation residue less than 100 ppmW.

22. The purified windshield washer fluid as recited in claim 4 , wherein the purified windshield washer fluid has evaporation residue less than 10 ppmW.

Assignments (2)
CHANGE OF NAME Recorded Sep 30, 2022
From: ULTRACELL LLC
To: ADVENT TECHNOLOGIES, LLC
Reel/Frame 061587/0539 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2020
From: CHEN, RU; BARCINAS, FRANKLIN PAUL; KAYE, IAN W.
To: ULTRACELL LLC
Reel/Frame 052831/0267 →