Organic electroluminescent compound and organic electroluminescent device comprising the same
View Patent ↗The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound of the present disclosure provides an organic electroluminescent device having high efficiency and/or long lifespan.
1. An organic electroluminescent compound represented by the following formula 2:
wherein
X 2 represents O, or S;
Z 1 and Z 2 each independently represent hydrogen, deuterium, or -L 1 -Het, with the proviso that, at least one of Z 1 and Z 2 represents -L 1 -Het;
R represents a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted 3- to 30-membered heteroaryl containing at least one heteroatom selected from N, O and S;
R 1 to R 4 each independently represent hydrogen, deuterium, a substituted or unsubstituted (C1-C10)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted 3- to 30-membered heteroaryl containing at least one heteroatom selected from N, O and S;
L 1 represents a direct bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted 3- to 30-membered heteroarylene containing at least one heteroatom selected from N, O and S;
Het represents a substituted or unsubstituted 3- to 30-membered heteroaryl containing at least one heteroatom selected from N, O and S.
2. The organic electroluminescent compound according to claim 1 , wherein formula 2 is represented by any one of the following formulae 4 and 5:
wherein X 2 , Z 1 , Z 2 , and R are as defined in claim 1 .
3. The organic electroluminescent compound according to claim 1 , wherein substituents of the substituted alkyl, the substituted aryl(ene), and the substituted heteroaryl(ene) in R, R 1 to R 4 , L 1 , and Het each independently are at least one selected from the group consisting of deuterium, a halogen, a cyano, a carboxyl, a nitro, a hydroxyl, a (C1-C30)alkyl, a halo(C1-C30)alkyl, a (C2-C30)alkenyl, a (C2-C30)alkynyl, a (C1-C30)alkoxy, a (C1-C30)alkylthio, a (C3-C30)cycloalkyl, a (C3-C30)cycloalkenyl, a 3- to 7-membered heterocycloalkyl, a (C6-C30)aryloxy, a (C6-C30)arylthio, a 3- to 30-membered heteroaryl unsubstituted or substituted with a (C6-C30)aryl, a (C6-C30)aryl unsubstituted or substituted with a 3- to 30-membered heteroaryl, a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, an amino, a mono- or di-(C1-C30)alkylamino, a mono- or di-(C6-C30)arylamino, a (C1-C30)alkyl(C6-C30)arylamino, a (C1-C30)alkylcarbonyl, a (C1-C30)alkoxycarbonyl, a (C6-C30)arylcarbonyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, and a (C1-C30)alkyl(C6-C30)aryl.
4. The organic electroluminescent compound according to claim 1 , wherein
X 2 represents O or S;
Z 1 and Z 2 each independently represent hydrogen or -L 1 -Het, with the proviso that at least one of Z 1 and Z 2 represents -L 1 -Het;
R represents a substituted or unsubstituted (C6-C18)aryl, or a substituted or unsubstituted 5- to 18-membered heteroaryl containing at least one heteroatom selected from N, O and S;
R 1 to R 4 each independently represent hydrogen;
L 1 represents a direct bond, a substituted or unsubstituted (C6-C18)arylene, or a substituted or unsubstituted 5- to 18-membered heteroarylene containing at least one heteroatom selected from N, O and S; and
Het represents a substituted or unsubstituted 5- to 18-membered heteroaryl containing at least one heteroatom selected from N, O and S.
5. The organic electroluminescent compound according to claim 1 , wherein
X 2 represents O, or S;
Z 1 and Z 2 each independently represent hydrogen or -L 1 -Het, with the proviso that at least one of Z 1 and Z 2 represents -L 1 -Het;
R represents an unsubstituted (C6-C18)aryl, or an unsubstituted 5- to 18-membered heteroaryl containing at least one heteroatom selected from N, O and S;
R 1 to R 4 each independently represent hydrogen;
L 1 represents a direct bond, a (C6-C18)arylene unsubstituted or substituted with a (C1-C6)alkyl, or an unsubstituted 5- to 18-membered heteroarylene containing at least one heteroatom selected from N, O and S; and
Het represents a 5- to 18-membered heteroaryl unsubstituted or substituted with a (C6-C12)aryl, containing at least one heteroatom selected from N, O and S.
6. The organic electroluminescent compound according to claim 1 , wherein Het represents a substituted or unsubstituted pyridine, a substituted or unsubstituted pyrimidine, a substituted or unsubstituted triazine, a substituted or unsubstituted quinoline, a substituted or unsubstituted isoquinoline, a substituted or unsubstituted quinazoline, a substituted or unsubstituted quinoxaline, a substituted or unsubstituted triazole, a substituted or unsubstituted pyrazole, a substituted or unsubstituted benzofuran, a substituted or unsubstituted dibenzofuran, a substituted or unsubstituted benzothiophene, or a substituted or unsubstituted dibenzothiophene.
7. The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the group consisting of:
8. An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 .
9. The organic electroluminescent device according to claim 8 , wherein the organic electroluminescent compound according to claim 1 is comprised in at least one of an electron transport material, an electron buffer material, and a phosphorescent host material.