Hybrid solid-state cell with a sealed anode structure
A monolithic ceramic electrochemical cell housing is provided. The housing includes two or more electrochemical sub cell housings. Each of the electrochemical sub cell housing includes an anode receptive space, a cathode receptive space, a separator between the anode receptive space and the cathode receptive space, and integrated electron conductive circuits. A first integrated electron conductive circuit is configured as an anode current collector within the anode receptive space. A second integrated electron conductive circuit is disposed as a cathode current collector within the cathode receptive space.
1. A monolithic ceramic electrochemical cell comprising:
a first electrochemical sub cell housing comprising a first anode receptive space, a cathode receptive space, a first separator between the first anode receptive space and the cathode receptive space; and
a second electrochemical sub cell housing comprising a second anode receptive space, the cathode receptive space, and a second separator between the second anode receptive space and the cathode receptive space, the cathode receptive space being the cathode receptive space for the first electrochemical sub-cell housing and the second electrochemical sub-cell housing,
wherein the cathode receptive space is bounded on one side by a first cathode current collector and on the other side by a second cathode current collector.
2. The monolithic ceramic electrochemical cell of claim 1 , wherein the first electrochemical sub cell housing comprises the first cathode current collector and wherein the second electrochemical cell housing comprises the second cathode current collector.
3. The monolithic ceramic electrochemical cell of claim 1 , wherein the cathode receptive space comprises a filling aperture configured to contain catholyte, the filling aperture including a seal and wherein the seal is configured to isolate the catholyte and provide pressure relief from the cathode receptive space.
4. The monolithic ceramic electrochemical cell of claim 1 , wherein the first electrochemical cell sub cell housing comprises a first plurality of integrated electron conductive circuits and wherein the second electrochemical sub cell housing comprises a second plurality of integrated electron conductive circuits.
5. The monolithic ceramic electrochemical cell of claim 4 , wherein the first and second plurality of integrated electron conductive circuits each comprise an anode current collector and a cathode current collector.
6. The monolithic ceramic electrochemical cell of claim 1 , wherein the anode receptive spaces are configured as hermetically sealed volumes, partially filled with a solid-state electrolyte.
7. The monolithic ceramic electrochemical cell of claim 6 , wherein the solid-state electrolyte comprises a ceramic.
8. The monolithic ceramic electrochemical cell of claim 7 , wherein the ceramic is selected from a group consisting of: sulfides, borides, carbides, nitrides, phosphides, oxides, selenides, fluorides, chlorides, bromides, iodides, and combinations thereof.
9. The monolithic ceramic electrochemical cell of claim 6 , wherein the solid-state electrolyte forms a network of continuous ionic conductivity between the separator and a first anode current collector and a second anode current collector.
10. The monolithic ceramic electrochemical cell of claim 9 , wherein the solid-state electrolyte occupies between 20% and 80% volume of the first and second anode receptive spaces.
11. The monolithic ceramic electrochemical cell of claim 5 , wherein the anode current collector serves as a current collector for the first anode receptive spaces of the first electrochemical sub cell housing and the current collector for the second anode receptive spaces of the second electrochemical sub cell housing.
12. The monolithic ceramic electrochemical cell of claim 1 , wherein the cathode receptive space is partially filled with strands of ceramic material between 1% and 60% volume.
13. The monolithic ceramic electrochemical cell of claim 1 , further comprising insulating material between the first electrochemical sub cell housing and the second electrochemical sub cell housing.
14. The monolithic ceramic electrochemical cell of claim 1 , wherein the first and second anode receptive spaces are sealed and the cathode receptive space is partially sealed.
15. The monolithic ceramic electrochemical cell of claim 5 , wherein a first cathode current collector is in direct contact with a surface of the first separator and a second cathode current collector is in direct contact with a surface of the second separator, the first separator and the second separator encompassing the cathode receptive space.
16. The monolithic ceramic electrochemical cell of claim 5 , wherein the cathode current collectors comprise one selected from the group consisting of a metal, a conductive ceramic, and a conductive carbon based material.
17. The monolithic ceramic electrochemical cell of claim 16 , wherein the cathode current collectors further comprise an ion conducting material to conduct the intended charge transfer ion of the specific battery design.
18. The monolithic ceramic electrochemical cell of claim 17 , wherein the ion conducting material comprises lithium lanthanum zirconate.
19. The monolithic ceramic electrochemical cell of claim 16 , wherein the cathode current collectors comprise a porous film that forms an electronic percolating network through the plane of the cathode current collectors.
20. The monolithic ceramic electrochemical cell of claim 16 , wherein the metal, metal alloy, conductive ceramic or conducting carbon material comprises between 20% and 99% by volume of the cathode current collector.