Rubber compositions containing tackifiers
View Patent ↗A composition comprising, a rubber component selected from the group consisting of a rubber polymer, a synthetic rubber polymer, and combinations thereof; and an alkylphenol resin which is a reaction product of: at least one phenolic monomer selected from the group consisting of phenol, cresol, resorcinol, xylenol, ethyl phenol, alkylresorcinols, and combinations thereof; and at least one alkyl aldehyde having from 5 to 12 carbon atom alkyl groups, is disclosed. The composition can be used to prepare articles of manufacture such as tires, tire treads, tire shoulders, tire sidewalls, rubber belts, and rubber hoses.
1. A method of forming a composition, comprising:
making a resole alkylphenol resin comprising:
reacting at least one phenolic monomer selected from the group consisting of phenol, cresol, resorcinol, xylenol, ethyl phenol, alkylresorcinols, and combinations thereof and at least one alkyl aldehyde having from 5 to 12 carbon atom alkyl groups in the presence of an acid catalyst, and optionally, an organic solvent that forms an azeotrope with water;
adding a base catalyst and formaldehyde;
reacting the at least one phenolic monomer, the at least one alkyl aldehyde, and the formaldehyde in the presence of the base catalyst; and
performing a reflux or azeotropic distillation process; and
adding the alkylphenol resin to a composition comprising a rubber component.
2. The method of claim 1 , wherein the rubber component is selected from the group consisting of a rubber polymer, a synthetic rubber polymer, and combinations thereof.
3. The method of claim 1 , wherein the alkylphenol resin acts as a tackifier.
4. The method of claim 1 , wherein the alkyl aldehyde is selected from the group consisting of 3,5,5-trimethyl hexanal, nonanal, 2-ethyl hexanal, and combinations thereof.
5. The method of claim 2 , wherein the synthetic rubber polymer is selected from the group consisting of styrene butadiene rubber, polybutadiene rubber, halogenated butyl rubber, butyl rubber, polyisoprene rubber, styrene/isoprene/butadiene rubber, and combinations thereof.
6. The method of claim 1 , wherein the composition has a tan δ at 0° C. as measured by Dynamic Mechanical Analysis in the range of from 0.12 to 0.17.
7. The method of claim 6 , wherein the composition has a tan δ at 60° C. as measured by Dynamic Mechanical Analysis in the range of from 0.10 to 0.16.
8. The method of claim 1 , wherein the composition has an ultimate elongation as measured by ASTM D412 in the range of from 550% to 800%.
9. The method of claim 1 , wherein the composition has an elastic modulus at 60° C. as measured by Dynamic Mechanical Analysis in the range of from 3.60×10 6 Pa to 5.00×10 6 Pa.
10. The method of claim 1 , wherein the alkylresorcinols comprise dihydroxy benzenes having one or two alkyl chains present on a ring.
11. The method of claim 10 , wherein the alkyl chains comprise from 1 to 3 carbons.
12. The method of claim 1 , wherein the alkylphenol resin can be present in the composition in the range of from 1 to 10 parts per hundred rubber.