Base film, preparation method thereof, and cover window and display device comprising same
Embodiments relate to a base film that is colorless, transparent, and excellent in mechanical properties and optical properties, particularly with low moisture permeability, a process for preparing the same, and a cover window and a display device comprising the same. The cover window comprises a base film comprising a polyamide-based polymer and having a moisture permeability of 300 g/m 2 ·day or less; and a functional layer.
1. A cover window for a display device, which comprises a base film comprising a polyamide-based polymer and having a moisture permeability of 30 g/m 2 ·day to 300 g/m 2 ·day measured in the thickness direction according to ASTM F 372; and a functional layer,
wherein the polyamide-based polymer is formed by polymerizing a diamine compound, a dicarbonyl compound, and optionally a dianhydride compound, and the molar ratio of the dianhydride compound and the dicarbonyl compound is 0:100 to 25:75,
wherein a thickness of the base film is 20 μm to 150 μm,
wherein a content of a residual solvent in the base film is 1,000 ppm or less,
wherein the base film has a modulus of 6.5 GPa or more,
wherein the base film has a yellow index of 3 or less, a transmittance at 550nm of 88% or more, a haze at 550 nm of 1% or less, and
wherein the IS value represented by the following Equation 1 is 10 to 100:
IS
=
IM
+
R
S
1
0
[
Equation
1
]
wherein, in Equation 1, IM stands for the number of moles of the imide repeat unit when the total number of moles of the imide repeat unit and the amide repeat unit in the film is 100; and RS stands for the content (ppm) of the residual solvent in the film.
2. The cover window for a display device of claim 1 , wherein the base film is stretched by 1.01 times to 1.05 times in the transverse direction.
3. The cover window for a display device of claim 1 , wherein the polymer contained in the base film comprises a repeat unit represented by the following Formula A and a repeat unit represented by the following Formula B at a molar ratio of 0:100 to 25:75:
E and J are each independently selected from a substituted or unsubstituted divalent C 6 -C 30 aliphatic cyclic group, a substituted or unsubstituted divalent C 4 -C 30 heteroaliphatic cyclic group, a substituted or unsubstituted divalent C 6 -C 30 aromatic cyclic group, a substituted or unsubstituted divalent C 4 -C 30 heteroaromatic cyclic group, a substituted or unsubstituted C 1 -C 30 alkylene group, a substituted or unsubstituted C 2 -C 30 alkenylene group, a substituted or unsubstituted C 2 -C 30 alkynylene group, —O—, —S—, —C(═O)—, —CH(OH)—, —S(═O) 2 —, —Si(CH 3 ) 2 —, —C(CH 3 ) 2 —, and —C(CF 3 ) 2 —,
e and j are each independently selected from integers of 1 to 5,
when e is 2 or more, then the 2 or more Es are the same as, or different from, each other,
when j is 2 or more, then the 2 or more Js are the same as, or different from, each other, and
G is bonded by a bonding group selected from a substituted or unsubstituted tetravalent C 6 -C 30 aliphatic cyclic group, a substituted or unsubstituted tetravalent C 4 -C 30 heteroaliphatic cyclic group, a substituted or unsubstituted tetravalent C 6 -C 30 aromatic cyclic group, a substituted or unsubstituted tetravalent C 4 -C 30 heteroaromatic cyclic group, wherein the aliphatic cyclic group, the heteroaliphatic cyclic group, the aromatic cyclic group, or the heteroaromatic cyclic group may be present alone or may be bonded to each other to form a condensed ring, a substituted or unsubstituted C 1 -C 30 alkylene group, a substituted or unsubstituted C 2 -C 30 alkenylene group, a substituted or unsubstituted C 2 -C 30 alkynylene group, —O—, —S—, —C(═O)—, —CH(OH)—, —S(═O) 2 —, —Si(CH 3 ) 2 —, —C(CH 3 ) 2 —, and —C(CF 3 ) 2 —.
4. The cover window for a display device of claim 1 , wherein the base film further comprises a filler.
5. The cover window for a display device of claim 4 , wherein the content of the filler is 0.01 to 3% by weight based on the total weight of the base film.
6. A base film for a display device, which comprises a polyamide-based polymer and has a moisture permeability of 30 g/m 2 ·day to 300 g/m 2 ·day measured in the thickness direction according to ASTM F 372,
wherein the polyamide-based polymer is formed by polymerizing a diamine compound, a dicarbonyl compound, and optionally a dianhydride compound, and the molar ratio of the dianhydride compound and the dicarbonyl compound is 0:100 to 25:75,
wherein a thickness of the base film is 20 μm to 150 μμm,
wherein a content of a residual solvent in the base film is 1,000 ppm or less,
wherein the base film has a modulus of 6.5 GPa or more,
wherein the base film has a yellow index of 3 or less, a transmittance at 550 nm of 88% or more, a haze at 550 nm of 1% or less, and
wherein the IS value represented by the following Equation 1 is 10 to 100:
IS
=
I
M
+
R
S
1
0
[
Equation
1
]
wherein, in Equation 1, IM stands for the number of moles of the imide repeat unit when the total number of moles of the imide repeat unit and the amide repeat unit in the film is 100; and RS stands for the content (ppm) of the residual solvent in the film.
7. A display device, which comprises a display panel; and a cover window disposed on the display panel,
wherein the cover window comprises a base film and a functional layer,
wherein the base film comprises a polyamide-based polymer and has a moisture permeability of 30 g/m 2 ·day to 300 g/m 2 ·day measured in the thickness direction according to ASTM F 372,
wherein the polyamide-based polymer is formed by polymerizing a diamine compound, a dicarbonyl compound, and optionally a dianhydride compound, and the molar ratio of the dianhydride compound and the dicarbonyl compound is 0:100 to 25:75,
wherein a thickness of the base film is 20 μm to 150 μm,
wherein a content of a residual solvent in the base film is 1,000 ppm or less,
wherein the base film has a modulus of 6.5 GPa or more,
wherein the base film has a yellow index of 3 or less, a transmittance at 550 nm of 88% or more, a haze at 550 nm of 1% or less, and
wherein the IS value represented by the following Equation 1 is 10 to 100:
IS
=
I
M
+
R
S
1
0
[
Equation
1
]
wherein, in Equation 1, IM stands for the number of moles of the imide repeat unit when the total number of moles of the imide repeat unit and the amide repeat unit in the film is 100; and RS stands for the content (ppm) of the residual solvent in the film.
8. A process for producing the base film for a display device according to claim 6 , which comprises:
preparing a polyamide-based polymer solution in an organic solvent;
charging the polymer solution into a tank;
extruding and casting the polymer solution in the tank and then drying it to prepare a gel sheet; and
thermally treating the gel sheet,
wherein the thermal treatment step of the gel sheet is carried out in two or more treatment steps with hot air,
wherein the thermal treatment comprises a first hot air treatment step carried out for 5 to 30 minutes in the range of 60° C. to 120° C.; and a second hot air treatment step carried out for 10 minutes to 120 minutes in the range of 180° C. to 380°° C.