Methods and materials for the functionalization of polymers and coatings including functionalized polymer
The disclosure provides a functionalized polymer for use in coating compositions and a method for making the functionalized polymer. In some embodiments, the functionalized polymer is a water-dispersible polymer, more preferably a water-dispersible polyester polymer, having one or more side groups including one or more salt groups. Packaging containers (e.g., food or beverage cans) comprising the functionalized polymer and methods of making such containers are also provided.
1. A coating composition comprising:
a functionalized polymer having a number average molecular weight of at least 2,000, wherein the polymer includes one or more functional-group-containing structural units that are the reaction product of a pericyclic reaction or a non-pericyclic Ene reaction, and wherein the one or more functional-group-containing structural units includes a functional group that is a salt or salt-forming group; and
one or more ingredients selected from a liquid carrier, a lubricant, a pigment, a crosslinker, a flow control agent, an adhesion promoter, or a catalyst to increase the rate of cure and/or extent of crosslinking.
2. The composition of claim 1 , wherein the functionalized polymer has a number average molecular weight of at least 4,000.
3. The composition of claim 2 , wherein the composition is a liquid coating composition that includes at least 50 weight percent of liquid carrier.
4. The composition of claim 2 , wherein the functionalized polymer comprises a polyester polymer that has a glass transition temperature of at least 25° C.
5. The composition of claim 1 , wherein the functional-group-containing structural unit is a Diels-Alder or Ene reaction product.
6. The composition of claim 1 , wherein the functionalized polymer comprises a polyester polymer.
7. The composition of claim 6 , wherein the polyester polymer is an aromatic water-dispersible polyester polymer.
8. The composition of claim 6 , wherein the polyester polymer is a water-dispersible polymer, and wherein the coating composition includes at least 50 weight percent of polyester polymer, based on total resin solids.
9. The composition of claim 1 , wherein the one or more functional-group-containing structural units includes functional group selected form an active hydrogen group, an isocyanate group, a blocked isocyanate group, a ketone group, or a mixture thereof.
10. The composition of claim 1 , wherein a cured coating composition formed from the coating composition has a glass transition temperature of at least 20° C.
11. The composition of claim 1 , wherein a cured coating composition formed from the coating composition has a glass transition temperature of at least 30° C. to less than about 80° C.
12. The composition of claim 1 , wherein the coating composition includes a crosslinker selected from an aminoplast, a phenoplast, a blocked isocyanate, or a combination thereof.
13. The composition of claim 1 , wherein the coating composition includes a lubricant in an amount of about 0.1% to about 5% by weight of nonvolatile material.
14. The composition of claim 1 , wherein the coating composition includes a lubricant comprising a Carnauba wax, a polyethylene-type lubricant, a polytetrofluoroethylene (PTFE)-modified polyethylene lubricant, or a Fisher-Tropsch lubricant.
15. The composition of claim 1 , wherein the coating composition is a water-based coating composition that is storage stable at ambient temperature for at least one week without separating into layers.
16. The composition of claim 1 , wherein the coating composition is a powder coating composition.
17. The composition of claim 1 , wherein the coating composition prior to cure includes less than 200 ppm of ethylenically unsaturated compounds having molecular weights of less than 500 g/mol.
18. A coating composition comprising:
a functionalized polymer having a number average molecular weight of at least 2,000, wherein the polymer includes one or more functional-group-containing structural units that are the reaction product of a pericyclic reaction or a non-pericyclic Ene reaction; and
one or more ingredients selected from a liquid carrier, a lubricant, a pigment, a crosslinker, a flow control agent, an adhesion promoter, or a catalyst to increase the rate of cure and/or extent of crosslinking, wherein a cured coating composition formed from the coating composition has a glass transition temperature of at least 20° C.
19. A coating composition comprising:
a functionalized polymer having a number average molecular weight of at least 2,000, wherein the polymer includes one or more functional-group-containing structural units that are the reaction product of a pericyclic reaction or a non-pericyclic Ene reaction; and
one or more ingredients selected from a liquid carrier, a lubricant, a pigment, a crosslinker, a flow control agent, an adhesion promoter, or a catalyst to increase the rate of cure and/or extent of crosslinking, wherein the coating composition is a powder coating composition.