Silicon composites using zintl salts for silicon anode batteries
Systems and methods are disclosed that provide for a silicon-carbon composite material that includes nanoparticulate (e.g., nanocrystalline) silicon derived from a reaction between a zintl salt and metal halide. The nanoparticulate silicon-carbon composite material can be used to provide electrode materials (e.g., anode) and cells.
1. A method of forming nanoparticulate silicon comprising:
reacting an amount of a silicon zintl salt with an amount of a silicon halide under conditions effective to form the nanoparticulate silicon.
2. The method according to claim 1 , further comprising isolating the nanoparticulate silicon.
3. The method according to claim 1 , wherein the reacting comprises a dipolar aprotic solvent.
4. The method according to claim 3 , wherein the dipolar aprotic solvent comprises N-Methyl-2-pyrrolidone (NMP).
5. The method according to claim 1 , wherein the nanoparticulate silicon comprises a D 50 size distribution of about 10 nm to about 200 nm.
6. The method according to claim 1 , comprising reacting BaSi 2 , CaSi 2 , SrSi 2 , NbSi 2 , MoSi 2 , CrSi 2 , VSi 2 , FeSi 2 , TaSi 2 , or WSi 2 .
7. The method according to claim 1 , wherein the silicon zintl salt comprises Mg 2 Si and the silicon halide comprises SiCl 4 .
8. The method according to claim 1 , wherein the nanoparticulate silicon comprises Si x Mg y Cl z , wherein x is greater than 0.2 and less than 0.45, y is greater than 0.25 and less than 0.50, and z is greater than 0.35 and less than 0.60.
9. The method according to claim 1 , wherein the amount of silicon zintl salt and the amount of silicon halide are added to the reaction at molar ratio of about 1:1.
10. The method according to claim 1 , wherein the reacting comprises:
dispersing the silicon zintl salt in a reaction solvent;
adding the silicon halide to the dispersed silicon zintl salt to form a reaction mixture; and
stirring the reaction mixture for 1-12 hours under a low moisture or moisture-free atmosphere to form the nanoparticulate silicon.