IP Library Granted Patent US 11,685,699
Granted Patent B2
US 11,685,699 · App. 16/928,554 · Granted Jun 27, 2023

Coating methods and materials to reduce aging of SiC hot surface ignitors

Inventors: Michael J. Hanagan (Grafton, MA); Al Marshall (Merrimack, NH)
Assignee: CoorsTek, Inc.
C04B41/5035C04B35/565C04B41/009C04B41/524C04B41/87F23Q7/22
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Quick Facts
Patent No.
US 11,685,699
App. No.
16/928,554
Granted
Jun 27, 2023
Kind
B2
Abstract

An ignitor that includes at least one layer of silicon dioxide coating a silicon carbide material, methods of making and using the ignitor, and a kit that includes the ignitor are provided. The silicon dioxide coating is not intended to be removed prior to use. Rather, it is intended to remain on the ignitor during use.

Claims (29)

1. A method to apply a silicon dioxide coating to a silicon carbide ignitor, comprising:

coating at least a portion of a silicon carbide material of the silicon carbide ignitor with a silicon dioxide material to produce a silicon carbide ignitor coated with a first layer of the silicon dioxide, wherein the silicon dioxide material is not produced by oxidizing the silicon carbide material of the silicon carbide ignitor; and

drying the first layer of the silicon dioxide material to form a silicon dioxide layer.

2. The method of claim 1 , further comprising applying at least one additional coating of silicon dioxide material to the first layer of the silicon dioxide of the silicon carbide ignitor to produce a silicon carbide ignitor comprising at least two layers of silicon dioxide material, wherein a total thickness of the at least two layers of the silicon dioxide material is between about 0.1 μm and about 5 μm.

3. The method of claim 1 , wherein the coating comprises dipping the silicon carbide ignitor in a solution comprising the silicon dioxide material for between about 10 seconds and about 60 seconds.

4. The method of claim 1 , further comprising applying the silicon dioxide material to at least one void in the silicon dioxide layer.

5. The method of claim 1 , wherein the silicon dioxide layer is adhered to the silicon carbide material of the silicon carbide ignitor.

6. The method of claim 1 , wherein the at least a portion of the silicon dioxide layer covers between about 25% and about 100% of a surface area of the silicon carbide material of the silicon carbide ignitor.

7. The method of claim 1 , wherein the drying occurs at a temperature between about 50° C. and about 130° C. for between about 5 and about 60 minutes.

8. The method of claim 1 , wherein the drying does not occur in a nitrogen environment.

9. The method of claim 1 , wherein the drying does not occur in an oxygen rich environment, wherein a concentration of the oxygen is greater than the oxygen concentration in air.

10. The method of claim 1 , wherein the silicon carbide material comprises a second recrystallized SiC coating.

11. The method of claim 1 , wherein the silicon dioxide material comprises at least one of a silicon dioxide sol, a solution comprising a solvent and the silicon dioxide material, or a solution comprising a silicon dioxide precursor.

12. An ignitor, comprising:

a silicon dioxide coating applied to at least a portion of a silicon carbide material of a silicon carbide containing ignitor, wherein a thickness of the silicon dioxide coating is between about 0.1 μm and about 5 μm, and wherein the silicon dioxide coating is not formed from the silicon carbide material.

13. The ignitor of claim 12 , wherein the silicon dioxide coating is not a sacrificial layer.

14. The ignitor of claim 12 , wherein the ignitor further comprises a second recrystallized SiC coating.

15. The ignitor of claim 12 , wherein silicon dioxide coating is substantially continuous and the thickness of the silicon dioxide coating varies by no more than about 20%.

16. The ignitor of claim 12 , wherein the ignitor consists of the silicon carbide coated with the silicon dioxide.

17. The ignitor of claim 12 , wherein a lifetime of the ignitor is at least about 10% longer than a lifetime of an ignitor that is not coated with the silicon dioxide coating.

18. The ignitor of claim 12 , wherein the silicon dioxide coating covers between about 25% and about 100% of the silicon carbide material.

19. The ignitor of claim 12 , wherein the silicon carbide material is substantially free of fine SiC particles.

20. A kit, comprising:

a silicon carbide ignitor comprising:

a silicon carbide material; and

at least one layer of a silicon dioxide material,

wherein a thickness of the silicon dioxide material is between about 0.1 and about 5 μm,

wherein the silicon dioxide covers between about 25% and about 100% of a surface area of the silicon carbide material of the silicon carbide ignitor,

and wherein the silicon dioxide coating is not formed from the silicon carbide material.

Assignments (4)
TERMINATION AND RELEASE OF CONFIRMATORY GRANT OF SECURITY INTEREST IN PATENTS Recorded Oct 29, 2025
From: JPMORGAN CHASE BANK, N.A.
To: COORSTEK, INC.
Reel/Frame 073414/0270 →
SECURITY INTEREST Recorded Oct 28, 2025
From: COORSTEK, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 072705/0315 →
SECURITY INTEREST Recorded Nov 23, 2022
From: COORSTEK, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 061860/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2022
From: HANAGAN, MICHAEL J.; MARSHALL, ALAN E.
To: COORSTEK, INC.
Reel/Frame 058781/0560 →