Amorphous Silicon in Solid Electrolytes, Compositions and Anodes
Herein are described compositions, anodes and batteries utilizing a plurality of amorphous silicon nanocrystals and a solid electrolyte. These compositions provide anode and batteries that have improved first columbic efficiencies when compared to analogous systems prepared with crystalline silicon nanocrystals. The methods of the production of the admixtures, the anodes and the cells/batteries are also provided.
1 . An admixture for use in an anode of a lithium ion battery, the admixture comprising:
about 20 wt. % to about 75 wt. % of a plurality of amorphous silicon nanocrystals; and
about 80 wt. % to about 25 wt. % of a solid electrolyte.
2 . The admixture of claim 1 further comprising about 1 wt. % to about 15 wt. % of a conducting agent.
3 . The admixture of claim 2 , wherein the admixture consists essentially of the amorphous silicon nanocrystals, the solid electrolyte, and the conducting agent.
4 . The admixture of claim 1 further comprising about 1 wt. % to about 15 wt. % of a binder.
5 . The admixture of claim 4 , wherein the admixture consists essentially of the amorphous silicon nanocrystals, the solid electrolyte, and the binder.
6 . The admixture of claim 4 , wherein the admixture consists essentially of the amorphous silicon nanocrystals, the solid electrolyte, about 1 wt. % to about 15 wt. % of a conducting agent, and the binder.
7 . The admixture of claim 1 , wherein the amorphous silicon nanocrystals individually comprise amorphous silicon domains and crystalline silicon domains;
wherein the crystalline silicon domains have an average crystalline domain size of less than 20 nm; and
wherein an atom ratio of silicon in the amorphous silicon domains to silicon in the crystalline silicon domains is in the range of about 1:1 to about 1000:1.
8 . The admixture of claim 7 , wherein the ratio of amorphous silicon domains to crystalline silicon domains is in the range of about 2:1 to about 10:1.
9 . The admixture of claim 7 , wherein the average crystalline silicon domain size is between about 10 nm and about 20 nm.
10 . The admixture of claim 1 , wherein the solid electrolyte includes a sulfide solid electrolyte.
11 . The admixture of claim 1 , wherein the solid electrolyte includes an oxide solid electrolyte.
12 . The admixture of claim 1 , wherein the solid electrolyte includes an oxysulfide solid electrolyte.
13 . An anode for use in lithium ion batteries, the anode comprising:
the admixture of claim 1 ; wherein
the admixture is adhered to a current collector and has not undergone an initial-charging cycle.
14 . An admixture for use in an anode of a lithium ion battery, the admixture comprising:
a plurality of amorphous silicon nanocrystals carrying a surface coating that is less than about 50 atom % silicon; and
a solid electrolyte.
15 . The admixture of claim 14 , wherein the surface coating consists essentially of silicon and oxygen, sulfur, selenium, nitrogen, phosphorous, carbon, boron, aluminum, or a mixture thereof.
16 . The admixture of claim 15 , wherein the surface coating includes sulfur.
17 . The admixture of claim 16 , wherein the surface coating further includes carbon.
18 . The admixture of claim 16 , wherein the solid electrolyte includes a sulfide solid electrolyte and/or an oxysulfide solid electrolyte.
19 . The admixture of claim 15 , wherein the surface coating includes oxygen.
20 . The admixture of claim 14 , wherein the surface coating has a thickness of less than about 10 nm, 9 nm, 8 nm, 7 nm, 6 nm, 5 nm, 4 nm, 3 nm, or 2 nm.
21 . The admixture of claim 14 , wherein the admixture includes about 20 wt. % to about 75 wt. % of the plurality of amorphous silicon nanocrystals and about 80 wt. % to about 25 wt. % of the solid electrolyte.
22 . An anode for use in lithium ion batteries, the anode comprising:
the admixture of claim 14 ; wherein
the admixture is adhered to a current collector and has not undergone an initial-charging cycle.