Catalytic hot-gas filtration of biomass pyrolysis vapors
The present disclosure relates to a device that includes a filter element and a catalyst, where the filter element is configured to remove particulate from a stream that includes at least one of a gas and/or a vapor to form a filtered stream of the gas and/or the vapor, the catalyst is configured to receive the filtered stream and react a compound in the filtered stream to form an upgraded stream of the gas and/or the vapor, further including an upgraded compound, and both the filter element and the catalyst are configured to be substantially stable at temperatures up to about 500° C.
1. A device for upgrading a pyrolysis vapor, the device comprising:
a filter element; and
a catalyst, wherein:
the filter element removes particulate from a stream comprising the pyrolysis vapor to form a filtered stream of the pyrolysis vapor,
the catalyst receives the filtered stream,
the catalyst comprises a heteropolyacid,
the catalyst reacts with a compound in the filtered stream to form an upgraded stream of the pyrolysis vapor, further comprising an upgraded compound, and
both the filter element and the catalyst are substantially stable at temperatures up to about 500° C.
2. The device of claim 1 , wherein the filter element is selected from the group consisting of a ceramic and a metal.
3. The device of claim 2 , wherein the ceramic is selected from the group consisting of an oxide, a carbide, a nitride, and a phosphide.
4. The device of claim 3 , wherein the oxide is selected from the group consisting of an alumina, a titania, a zirconia, and a silica.
5. The device of claim 3 , wherein the carbide is selected from the group consisting of silicon, titanium, and zinc.
6. The device of claim 1 , wherein the catalyst is selected from the group consisting of a ring-opening catalyst, a metal oxide, a zeolite, platinum, palladium, iridium, and rhodium.
7. The device of claim 1 , wherein the catalyst is positioned on a support.
8. A system for upgrading a pyrolysis vapor, the system comprising:
a catalytic hot-gas filter (CHGF) configured to receive an inlet stream comprising at a pyrolysis vapor, wherein:
the CHGF comprises a filter element and a catalyst,
the filter element is configured to remove particulate from the inlet stream comprising a pyrolysis vapor to form a filtered stream of the pyrolysis vapor,
the catalyst comprises a heteropolyacid,
the catalyst is configured to receive the filtered stream and react a compound in the filtered stream to form an upgraded stream of the pyrolysis vapor, further comprising an upgraded compound, and
both the filter element and the catalyst are configured to be substantially stable at temperatures up to about 500° C.
9. The system of claim 8 , further comprising a pyrolyzer configured to convert a feed stream to the inlet stream comprising an untreated pyrolysis vapor.
10. The system of claim 9 , wherein the pyrolyzer comprises at least one of a fluidized bed, a moving-bed, a circulating fluidized bed, a bubbling bed, an auger/screw system, an ablative reactor, a vacuum reactor, or an entrained flow reactor.
11. The system of claim 8 , further comprising:
a fractional condensation train (FCT) comprising, in series:
a passive-cooler condenser;
an electrostatic precipitator;
an aqueous condenser; and
a coalescing filter, wherein:
the FCT is configured to receive the upgraded stream to produce at least one pyrolysis oil.