IP Library Granted Patent US 11,550,235
Granted Patent B2
US 11,550,235 · App. 16/943,389 · Granted Jan 10, 2023

Electrostatic image developing toner, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Inventors: Atsushi Sugawara (Kanagawa, JP); Yosuke Tsurumi (Kanagawa, JP); Yasuko Torii (Kanagawa, JP); Yoshimasa Fujihara (Kanagawa, JP); Moegi Iguchi (Kanagawa, JP)
Assignee: FUJIFILM Business Innovation Corp.
G03G9/0825G03G9/0815G03G9/08708G03G9/08755G03G9/09328G03G9/09342G03G15/0865
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Quick Facts
Patent No.
US 11,550,235
App. No.
16/943,389
Granted
Jan 10, 2023
Kind
B2
Abstract

An electrostatic image developing toner includes toner particles, an external additive A, and an external additive B. At least the external additive A is deposited on the surfaces of the toner particles. At least the external additive B is deposited on the external additive A. The external additive B includes an aggregate of two or more particles. The coverage of the toner particles with the external additive B is 3% by area or more with respect to the total surface area of the toner particles.

Claims (52)

1. An electrostatic image developing toner comprising:

toner particles;

an external additive A; and

an external additive B,

wherein at least the external additive A is deposited on surfaces of the toner particles,

wherein at least the external additive B is deposited on the external additive A,

wherein the external additive B includes an aggregate of two or more primary particles,

wherein a coverage of the toner particles with the external additive B is 3% by area or more with respect to a total surface area of the toner particles,

wherein a number average particle size of the external additive A is 20 nm to 140 nm,

wherein a number average particle size of the primary particles, which in aggregate form the external additive B, is 5 nm to 90 nm,

wherein the number average particle size of the of external additive B minus the number average particle size of the external additive A is 10 nm to 200 nm,

wherein the external additive A includes a siloxane compound having a molecular weight of 200 or more and 600 or less and consisting of a siloxane bond and an alkyl group,

wherein the external additive B has a shape factor SF1 of 135 or more.

2. The electrostatic image developing toner according to claim 1 ,

wherein the shape factor SF1 of the external additive B is 145 or more.

3. The electrostatic image developing toner according to claim 1 ,

wherein a coverage of the toner particles with an external additive including the external additives A and B is 50% by area or more with respect to the total surface area of the toner particles.

4. The electrostatic image developing toner according to claim 2 ,

wherein a coverage of the toner particles with an external additive including the external additives A and B is 50% by area or more with respect to the total surface area of the toner particles.

5. The electrostatic image developing toner according to claim 2 ,

wherein a coverage of the toner particles with an external additive including the external additives A and B is 50% by area or more with respect to the total surface area of the toner particles.

6. The electrostatic image developing toner according to claim 1 ,

wherein a ratio C B /C A is 0.05 or more and 0.30 or less, where C A is a coverage of the toner particles with the external additive A with respect to the total surface area of the toner particles, and C B is the coverage of the toner particles with the external additive B with respect to the total surface area of the toner particles.

7. The electrostatic image developing toner according to claim 1 ,

wherein the external additive A has a shape factor SF1 of 145 or less.

8. The electrostatic image developing toner according to claim 1 ,

wherein the toner particles include a release agent.

9. The electrostatic image developing toner according to claim 8 ,

wherein 50% by mass or more of the release agent is present in a region extending from the surfaces of the toner particles to a distance of 0.8 μm from the surfaces of the toner particles.

10. The electrostatic image developing toner according to claim 8 ,

wherein the toner particles include core-shell particles, and

wherein the core-shell particles include a shell layer including the release agent.

11. The electrostatic image developing toner according to claim 1 ,

wherein the toner particles includes a binder resin including a hybrid resin, the hybrid resin including a polyester resin segment and a styrene acrylate copolymer segment.

12. The electrostatic image developing toner according to claim 11 ,

wherein a content of a constitutional unit derived from styrene in the hybrid resin is 5% by mass or more and 20% by mass or less of a total mass of the hybrid resin.

13. An electrostatic image developer comprising the electrostatic image developing toner according to claim 1 .

14. A toner cartridge detachably attachable to an image forming apparatus, the toner cartridge comprising the electrostatic image developing toner according to claim 1 .

15. A process cartridge detachably attachable to an image forming apparatus, the process cartridge comprising a developing unit that includes the electrostatic image developer according to claim 13 and develops an electrostatic image formed on a surface of an image holding member with the electrostatic image developer to form a toner image.

16. An image forming apparatus comprising:

an image holding member;

a charging unit that charges a surface of the image holding member;

an electrostatic image formation unit that forms an electrostatic image on the charged surface of the image holding member;

a developing unit that includes the electrostatic image developer according to claim 13 and develops the electrostatic image formed on the surface of the image holding member with the electrostatic image developer to form a toner image;

a transfer unit that transfers the toner image formed on the surface of the image holding member onto a surface of a recording medium; and

a fixing unit that fixes the toner image transferred on the surface of the recording medium.

17. An image forming method comprising:

charging a surface of an image holding member;

forming an electrostatic image on the charged surface of the image holding member;

developing the electrostatic image formed on the surface of the image holding member with the electrostatic image developer according to claim 13 to form a toner image;

transferring the toner image formed on the surface of the image holding member onto a surface of a recording medium; and

fixing the toner image transferred on the surface of the recording medium.

Assignments (2)
CHANGE OF NAME Recorded Apr 29, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 056092/0913 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 30, 2020
From: SUGAWARA, ATSUSHI; TSURUMI, YOSUKE; TORII, YASUKO; FUJIHARA, YOSHIMASA; IGUCHI, MOEGI
To: FUJI XEROX CO., LTD.
Reel/Frame 053358/0121 →
Priority Claims (1)
JP JP2020-050050 · Mar 19, 2020 · national
Continuity (1)
Related Publication 20210294227A1 · Sep 23, 2021