Delayed onset fluid gels for use in unit dose laundry detergents containing colloidal particles
Disclosed is a unit dose laundry detergent product containing an in-vitro, delayed onset fluid gel detergent composition and a water soluble film pouch for enclosing the detergent composition. The composition includes a linear alkylbenzene sulfonate and/or an alcohol ethoxy sulfate having a C 8 -C 20 backbone that is ethoxylated with from about 1 to about 10 moles of ethylene oxide, and a non-ionic surfactant comprising an alkoxylated alcohol, in an amount from 20 to 70 wt %, water in an amount from about 10 to about 30 wt %, free fatty acids in an amount from about 2 to 12 wt %, a magnesium cation in an amount of from 0.15 to 1 wt %, and colloidal particles such as an encapsulated fragrance. The composition is opacified and structured yet free of a structuring agent or an opacifying agent. Also disclosed is a method of making such product.
1. A method of preparing a unit dose detergent product comprising the steps of:
A. mixing a surfactant system, a fatty acid or a salt thereof, water, and at least one additive ingredient to form a first mixture, wherein the first mixture does not include a magnesium salt;
wherein the surfactant system is present in an amount of about 20 to about 70 weight percent based on a total weight of said unit dose detergent product and comprises:
(1) at least one anionic surfactant comprising an alcohol ethoxy sulfate having a C 8 -C 20 backbone that is ethoxylated with from about 1 to about 10 moles of ethylene oxide or linear alkylbenzene sulfonate;
(2) at least one non-ionic surfactant comprising an alkoxylated alcohol; and
wherein water is present in a total amount of from about 10 to about 30 weight percent based on a total weight of said detergent product;
wherein the fatty acid or a salt thereof is present in an amount of from about 2 to about 12 weight percent based on a total weight of said detergent product;
B. mixing the first mixture with a magnesium salt to form a second mixture from 0.1 second to 5 hours prior to a step of depositing the second mixture to a pouch space formed by a water-soluble film;
wherein the magnesium salt comprises a magnesium cation component and a counterion component, wherein the magnesium cation component is present in an amount of from about 0.15 to about 1.0 weight percent based on a total weight of said detergent product;
wherein a weight ratio between the fatty acid and the magnesium salt is from 2:1 to 30:1;
C. depositing the second mixture into the pouch formed by a water-soluble film; and
D. sealing the film to enclose the second mixture to form the unit dose detergent product and
E. allowing the resulting enclosed mixture to gel within 1 to 3 days before packaging or shipping said unit dose product.
2. The method of preparing a unit dose detergent product according to claim 1 , further comprising a step of mixing colloidal particles in Step A; wherein the colloidal particles are present in an amount of about 0.02 to 5.0 weight percent based on the total weight of said detergent product.
3. The method of preparing a unit dose detergent product according to claim 1 , wherein the first mixture is free of a structuring polymer and free of an opacifying agent.
4. The method of preparing a unit dose detergent product according to claim 1 , wherein the first mixture is free of crystallized triglycerides.
5. The method of preparing a unit dose detergent product according to claim 1 , wherein the magnesium cation component is derived from magnesium chloride, magnesium sulfite, magnesium bisulfite, or magnesium sulfate.
6. The method of preparing a unit dose detergent product according to claim 2 , wherein the colloidal particles comprise an encapsulated fragrance.