Cathode active material for lithium secondary battery, production method therefor, and lithium secondary battery comprising same
It is related to a positive active material for lithium secondary battery, a manufacturing method thereof, and a lithium secondary battery containing the same, provides that a positive active material for lithium secondary battery, wherein, it is a layered lithium metal compound comprises nickel, cobalt, and manganese, and aluminum, zirconium, and boron are doped.
1. A positive active material for lithium secondary battery, wherein, the positive active material includes a layered lithium metal compound comprising nickel, cobalt, and manganese, and aluminum, zirconium, and boron are doped, wherein the lithium metal compound is represented by Chemical Formula 1 below:
Li a Ni x Co y Mn z (M) 1−(x+y+z) O b
in which a 0.8≤a≤1.3, 1.8≤b≤2.2, 0.8≤x≤0.92, 0<y≤0.15, 0<z≤0.1, and 0<x+y+z<1; and
the doping element M comprises Al, Zr, and B,
wherein with respect to 1 mole of the entire metal containing Ni, Co, Mn, and M, a doping ratio of Al among the doping elements M is 0.0002 to 0.01 mol, a doping ratio of Zr among the doping elements M is 0.0015 to 0.005 mol, and a doping ratio of B among the doping elements M is 0.001 to 0.01 mol.
2. The positive active material of claim 1 , wherein:
the positive active material comprises a core portion and a shell portion of the core portion surface,
the core portion and the shell portion are made of a composition containing Ni, Co, Mn, and M elements in the Chemical Formula 1.
3. The positive active material of claim 1 , wherein:
the core portion is 70 to 80% for 100% of the entire positive active material diameter.
4. The positive active material of claim 2 , wherein:
the content of nickel in the core is higher than that of nickel in the shell.
5. The positive active material of claim 2 , wherein:
a distribution of nickel in the core is uniform.
6. The positive active material of claim 5 , wherein:
a distribution of nickel content in the shell has a concentration gradient that decreases as it approaches the active material surface.
7. The positive active material of claim 1 , wherein:
the positive active material has a crystal size (Crystalline size) of 90 nm or more.
8. The positive active material of claim 1 , wherein:
the positive active material has an I003/I104 value of 1.2 or higher.
9. The positive active material of claim 1 , wherein:
a R factor of the positive active material is 0.52 or less.
10. The positive active material of claim 2 , wherein:
the positive active material further comprises a coating layer positioned on the surface of the shell portion.
11. The positive active material of claim 10 , wherein:
the coating layer comprises boron, boron oxide, lithium boron oxide or combination thereof.
12. The positive active material of claim 1 , wherein:
the positive active material is a bimodal mixed with large particle and small particle.
13. The positive active material of claim 12 , wherein:
a D50 of the large particle is 13 to 17 μm.
14. The positive active material of claim 12 , wherein:
a D50 of the small particle is 4 to 7 μm.
15. A method of manufacturing a positive active material for lithium the positive active material of claim 1 , comprising:
preparing precursor particles comprising nickel, cobalt, and manganese;
obtaining lithium metal oxide by mixing and sintering the precursor particles, lithium raw material, and doping raw material;
forming a coating layer by mixing and heating a coating raw material on the lithium metal oxide;
wherein, the doped raw material comprises Al raw material, Zr raw material, and B raw material.
16. The method of claim 15 , wherein:
in the step of obtaining lithium metal oxide by mixing and sintering the precursor particles, lithium raw material, and doping raw material, a sintering condition continues to primary and secondary temperatures while inflowing oxygen, and
the primary temperature is 450 to 550° C., and the secondary temperature is 700 to 750° C.