Non-oriented electrical steel sheet and method for preparing same
A non-oriented electrical steel sheet according to an exemplary embodiment of the present invention includes at least one of 2.0 to 3.5% of Si, 0.3 to 3.5% of Al, 0.2 to 4.5% of Mn, 0.0030 to 0.2% of Sn, 0.0030 to 0.15% of Sb, 0.0040 to 0.18% of P, 0.0005 to 0.02% of Zn, and 0.0005 to 0.01% of Y for wt %, a remainder of Fe, and inevitable impurities, and satisfying Formula 1: 0.05≤([Sn]+[Sb])/[P]≤25 [Formula 1] (here, [Sn], [Sb], and [P] represent contents (wt %) of Sn, Sb, and P.)
1. A non-oriented electrical steel sheet comprising:
in wt % 2.0 to 3.5% of Si, 0.3 to 3.5% of Al, 0.2 to 4.5% of Mn, 0.0030 to 0.2% of Sn, 0.0030 to 0.15% of Sb, 0.0040 to 0.18% of P, and at least one of 0.0005 to 0.02% of Zn, and 0.0005 to 0.01% of Y; and a remainder of Fe, and inevitable impurities,
wherein:
the non-oriented electrical steel sheet includes inclusions, and inclusions with a diameter of 0.5 to 1.0 μm occupy 40 vol % or more of the entire inclusions, and
the non-oriented electrical steel sheet satisfies Formula 1:
0.05≤([Sn]+[Sb])/[P]≤25 wherein [Sn], [Sb], and [P] represent contents of Sn, Sb, and P in wt %. [Formula 1]
2. The non-oriented electrical steel sheet of claim 1 , wherein, in wt %, 0.0005 to 0.02% of Zn and 0.0005 to 0.01% of Y are included.
3. The non-oriented electrical steel sheet of claim 2 , wherein Formula 2 is satisfied:
[Zn]/[Y]>1 wherein [Zn] and [Y] represent contents of Zn and Y in wt %. [Formula 2]
4. The non-oriented electrical steel sheet of claim 2 , wherein Formula 3 is satisfied:
[Zn]+[Y]≤0.025 wherein [Zn] and [Y] represent contents of Zn and Y in wt %. [Formula 3]
5. The non-oriented electrical steel sheet of claim 1 , further comprising:
in wt %, at least one of equal to or less than 0.0040% of N excluding 0%, equal to or less than 0.0040% of C excluding 0%, equal to or less than 0.0040% of S excluding 0%, equal to or less than 0.0040% of Ti excluding 0%, equal to or less than 0.0040% of Nb excluding 0%, and equal to or less than 0.0040% of V excluding 0%.
6. The non-oriented electrical steel sheet of claim 1 , wherein
inclusions with a diameter of 2 μm or less occupy 80 vol % or more of the entire inclusions.
7. The non-oriented electrical steel sheet of claim 1 , wherein
the non-oriented electrical steel sheet includes inclusions, and an area of the entire inclusions for an area of the entire non-oriented electrical steel sheet is equal to or less than 0.2%.
8. The non-oriented electrical steel sheet of claim 1 , wherein an average crystal grain size is 50 to 95 μm.
9. The non-oriented electrical steel sheet of claim 1 , wherein the inclusions with a diameter of 0.5 to 1.0 μm occupy 48 vol % or more of the entire inclusions.
10. A method for manufacturing a non-oriented electrical steel sheet, comprising:
manufacturing a slab including, in wt %, 2.0 to 3.5% of Si, 0.3 to 3.5% of Al, 0.2 to 4.5% of Mn, 0.0030 to 0.2% of Sn, 0.0030 to 0.15% of Sb, 0.0040 to 0.18% of P, and at least one of 0.0005 to 0.02% of Zn, and 0.0005 to 0.01% of Y; a remainder of Fe, and inevitable impurities, and satisfying Formula 1;
heating the slab;
manufacturing a hot-rolled steel sheet by hot rolling the slab;
manufacturing a cold-rolled steel sheet by cold rolling the hot-rolled steel sheet; and
finally annealing the cold-rolled steel sheet,
wherein:
after the finally annealing, the non-oriented electrical steel sheet includes inclusions, and inclusions with a diameter of 0.5 to 1.0 μm occupy 40 vol % or more of the entire inclusions, and
the Formula 1 is:
0.05≤([Sn]+[Sb])/[P]≤25 wherein [Sn], [Sb], and [P] represent contents of Sn, Sb, and P in wt %. [Formula 1]
11. The method of claim 10 , wherein the slab includes, in wt %, 0.0005 to 0.02% of Zn and 0.0005 to 0.01% of Y.
12. The method of claim 11 , wherein the slab satisfies Formula 2:
[Zn]/[Y]>1 wherein [Zn] and [Y] represent contents of Zn and Y in wt %. [Formula 2]
13. The method of claim 11 , wherein the slab satisfies Formula 3:
[Zn]+[Y]≤0.025 wherein [Zn] and [Y] represent contents of Zn and Y in wt %. [Formula 3]
14. The method of claim 10 , wherein
the slab further includes in wt %, at least one of equal to or less than 0.0040% of N excluding 0%, equal to or less than 0.0040% of C excluding 0%, equal to or less than 0.0040% of S excluding 0%, equal to or less than 0.0040% of Ti excluding 0%, equal to or less than 0.0040% of Nb excluding 0%, and equal to or less than 0.0040% of V excluding 0%.