Cross-linkable composition
View Patent ↗The present application relates to a cross-linkable composition. The present application can provide a cross-linkable composition without degradation of cross-linking efficiency while exhibiting conductivity by containing an ionic compound, and its use.
1. An optical laminate comprising an optical film; and a pressure-sensitive adhesive layer formed on one side of the optical film and including a cross-linked product of a cross-linkable composition,
the optical film comprising a polyvinyl alcohol polarizer, in which the polyvinyl alcohol polarizer comprising a potassium component and a zinc component, and a ratio of the potassium component to the zinc component is in a range of 0.2 to 6,
the cross-linkable composition comprising an acrylic polymer having a carboxyl group; an ionic compound containing an alkali metal cation; a compound of Formula 1 below; and an epoxy cross-linking agent,
wherein,
R 1 and R 2 are each independently an alkyl group having 1 to 4 carbon atoms, R 3 and R 4 are each independently a hydrogen atom;
the cross-linkable composition does not comprise a metal chelate cross-linking agent and a metal-containing cross-linking catalyst;
the acrylic polymer comprises a polymerized unit of an alkyl (meth)acrylate monomer and a polymerized unit of a carboxyl group-containing monomer;
the carboxyl group-containing monomer is 2-(meth)acryloyloxyacetic acid, 3-(meth)acryloyloxypropyl acid, 4-(meth) acryloyloxybutyric acid, an acrylic acid dimer, itaconic acid, maleic acid, or maleic anhydride.
2. The optical laminate according to claim 1 , wherein the alkali metal cation is a lithium cation.
3. The optical laminate according to claim 1 , wherein the ionic compound comprises an anion of Formula 2 below:
[X(YO m R f ) n ] − [Formula 2]
wherein, X is nitrogen or carbon, Y is carbon or sulfur, R f is a perfluoroalkyl group, in is 1 or 2, and n is 2 or 3.
4. The optical laminate according to claim 1 , wherein the ionic compound is any one anion of Formulas 3 to 5 below:
[OSO 2 C n F 2n+1 ] − [Formula 3]
[N(SO 2 C n F 2n+1 ) 2 ] − [Formula 4]
[C(SO 2 C n F 2n+1 ) 3 ] − [Formula 5]
wherein, n of formula 4 is a number in a range of 0 to 4, n of formula 3 and formula 5 is a number in a range of 1 to 4.
5. The optical laminate according to claim 1 , wherein the ionic compound is in an amount of 0.001 to 20 parts by weight relative to 100 parts by weight of the acrylic polymer.
6. The optical laminate according to claim 1 , wherein the ionic compound is in an amount of 3 parts by weight or more relative to 100 parts by weight of the acrylic polymer.
7. The optical laminate according to claim 1 , wherein the compound of Formula 1 is in amount of 0.01 to 30 parts by weight relative to 100 parts by weight of the ionic compound.
8. The optical laminate according to claim 1 , wherein the epoxy cross-linking agent is in amount of 10 parts by weight or less relative to 100 parts by weight of the acrylic polymer.
9. The optical laminate according to claim 8 , wherein the cross-linking agent is in amount of 1 part by weight or less relative to 100 parts by weight of the acrylic polymer.
10. A display device comprising a display panel to which the optical laminate of claim 1 is attached via the pressure-sensitive adhesive layer.
11. The optical laminate according to claim 1 , wherein the polymerized unit of a carboxyl group-containing monomer is in a range of about 0.01 to 10 parts by weight relative to 100 parts by weight of the polymerized unit of the alkyl (meth)acrylate monomer.
12. The optical laminate according to claim 1 , wherein the acrylic polymer further comprises a polymerized unit of an aromatic group-containing monomer represented by the following formula 6:
in Formula 6, R 1 represents hydrogen or an alkyl group, A represents an alkylene group, n represents an integer in a range of 0 to 3, Q represents a single bond, —O—, —S— or an alkylene group, and P represents an aryl group.
13. The optical laminate according to claim 1 , wherein the acrylic polymer has a weight-average molecular weight (Mw) of 500,000 or more.
14. An optical laminate comprising an optical film; and a pressure-sensitive adhesive laver formed on one side of the optical film and including a cross-linked product of a cross-linkable composition,
the optical film comprising a polyvinyl alcohol polarizer, in which the polyvinyl alcohol polarizer comprising a potassium component and a zinc component, and a ratio of the potassium component to the zinc component is in a range of 0.2 to 6,
the cross-linkable composition comprising an acrylic polymer having a carboxyl group; an ionic compound containing an alkali metal cation; a compound of Formula 1 below; and an epoxy cross-inking agent,
wherein,
R 1 and R 2 are each independently an alkyl group having 1 to 4 carbon atoms, R 3 and R 4 are each independently a hydrogen atom;
the cross-inkable composition does not comprise a metal chelate cross-linking agent and a metal-containing cross-linking catalyst;
the acrylic polymer comprises a polymerized unit of an alkyl (meth)acrylate monomer and a polymerized unit of a carboxyl group-containing monomer;
the carboxyl group-containing monomer is 2-(meth)acryloyloxyacetic acid, 3-(meth)acryloyloxypropyl acid, 4-(meth) acryloyloxybutyric acid, an acrylic acid dimer, itaconic acid, maleic acid, or maleic anhydride;
wherein the ionic compound is in an amount of 3 parts by weight or more relative to 100 parts by weight of the acrylic polymer;
wherein the polymerized unit of the carboxyl group-containing monomer is in a range of about 0.01 to 10 parts by weight relative to 100 parts by weight of the polymerized unit of the alkyl (meth)acrylate monomer.