Polypropylene resin for insulating electric cables
An ethylene-propylene block copolymer resin is provided that is suitable as an insulation layer of an electric power cable. The ethylene-propylene block copolymer is obtained by polymerization of a propylene homopolymer or an ethylene-propylene random copolymer with an ethylene-propylene rubber copolymer in stages in reactors in the presence of a Ziegler-Natta catalyst obtained using two internal electron donors, wherein one of the two internal electron donors is a compound comprising an ester group and an alkoxy group, the ethylene-propylene block copolymer has a melting temperature of 150 to 160° C., the content of the solvent extract thereof when extracted at room temperature with xylene is 30 to 50% by weight, and the intrinsic viscosity of the solvent extract is 1.5 to 3.0 dl/g.
1. An ethylene-propylene block copolymer resin obtained by polymerization of a propylene homopolymer or an ethylene-propylene random copolymer with an ethylene-propylene rubber copolymer in stages in reactors in the presence of a Ziegler-Natta catalyst obtained comprising an internal electron donor composed of a combination of a non-aromatic alkoxy ester-based compound and a phthalic acid ester-based compound, wherein the ethylene-propylene block copolymer resin has a melting temperature (Tm) of 150 to 160° C., the content of the solvent extract when it is extracted at room temperature with xylene is 30 to 50% by weight, and the intrinsic viscosity of the solvent extract is 1.5 to 3.0 dl/g.
2. The ethylene-propylene block copolymer resin of claim 1 , wherein the Ziegler-Natta catalyst is prepared by reacting a dialkoxy magnesium with a titanium compound in the presence of an organic solvent, and then reacting the resultant product with the internal electron donor composed of a combination of a non-aromatic alkoxy ester-based compound and a phthalic acid ester-based compound.
3. The ethylene-propylene block copolymer resin of claim 1 , wherein the non-aromatic alkoxy ester-based compound comprises a compound represented by the following Formula 1:
in the above formula, n is 1 to 6, and R 1 , R 2 , R 3 , and R 4 are identically or each independently a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 3 to 12 carbon atoms, a vinyl group, a linear or branched alkenyl group having 3 to 12 carbon atoms, a linear alkyl group having 1 to 12 carbon atoms substituted with halogen, a branched alkyl group having 3 to 12 carbon atoms substituted with halogen, a linear or branched alkenyl group having 3 to 12 carbon atoms substituted with halogen, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms substituted with halogen, or a cycloalkenyl group having 3 to 12 carbon atoms substituted with halogen.
4. The ethylene-propylene block copolymer resin of claim 1 , wherein the phthalic acid ester-based compound is a benzene-1,2-dicarboxylate compound.
5. The ethylene-propylene block copolymer resin of claim 1 , wherein triethylaluminum as a co-catalyst and a dicyclopentyldimethoxysilane as an external electron donor are used as mixed with the catalyst during the polymerization.
6. The ethylene-propylene block copolymer resin of claim 1 , wherein when the ethylene-propylene block copolymer resin is extracted with xylene at room temperature, the intrinsic viscosity of the solvent insoluble is 2.0 to 4.0 dl/g.
7. The ethylene-propylene block copolymer resin of claim 6 , wherein the ratio of intrinsic viscosities between the solvent extract and the solvent insoluble (i.e., (intrinsic viscosity of the solvent extract)/(intrinsic viscosity of the solvent insoluble)) is 0.5 to 1.0.
8. The ethylene-propylene block copolymer resin of claim 1 , which has a melt index of 0.2 to 3.0 g/10 minutes.
9. The ethylene-propylene block copolymer resin of claim 1 , which further comprises at least one additive selected from the group consisting of an antioxidant and a neutralizing agent.
10. The ethylene-propylene block copolymer resin of claim 9 , wherein the content of the additive is 0.2 to 1.0% by weight based on the total weight of the ethylene-propylene block copolymer resin.
11. An electric power cable comprising an insulation layer, wherein the insulation layer comprises the ethylene-propylene block copolymer of claim 1 .