IP Library Granted Patent US 11,105,007
Granted Patent B2
US 11,105,007 · App. 16/964,763 · Granted Aug 31, 2021

Method for the electrochemical production of a gas product containing CO

Inventors: Clara Delhomme-Neudecker (Munich, DE); Marc Hanebuth (Nuremberg, DE); Andreas Peschel (Wolfratshausen, DE); Günter Schmid (Hemhofen, DE); Nicole Schödel (Munich, DE); Dan Taroata (Erlangen, DE)
Assignees: Siemens Aktiengesellschaft; Linde GMBH
C25B9/19B01D53/04C25B1/00C25B15/08B01D2253/102B01D2253/108B01D2256/20B01D2257/702
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Quick Facts
Patent No.
US 11,105,007
App. No.
16/964,763
Granted
Aug 31, 2021
Kind
B2
Abstract

A device for the electrochemical production of a product containing CO, and a method for the electrochemical production of a product containing CO, in which a return of a material stream containing the educt and CO is carried out after the electrochemical production.

Claims (39)

1. A facility for electrochemical production of a product containing CO, comprising:

an electrolysis cell comprising an anode and a cathode;

a combined feed device, which is connected to the electrolysis cell and supplies the electrolysis cell with a combined flow of material comprising a first educt flow and a flow of material to be returned comprising CO, which is embodied to supply the electrolysis cell with the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO;

a first feed device, which is connected to the combined feed device and feeds the first educt flow to the combined feed device, which is embodied to feed the first educt flow to the combined feed device;

a first discharge device, which is connected to the electrolysis cell and discharges from the electrolysis cell a first product flow comprising CO, which is embodied to discharge from the electrolysis cell the first product flow comprising CO and to feed the first product flow to a separation device;

the separation device, which is connected to the first discharge device and separates the flow of material comprising CO to be returned from the first product flow comprising CO, which is embodied to separate the flow of material comprising CO to be returned from the first product flow comprising CO;

a return device, which is connected to the separation device and is connected to the combined feed device and feeds the flow of material comprising CO to be returned to the combined feed device, which is embodied to feed the flow of material comprising CO to be returned to the combined feed device; and

at least one cleaning device, which removes carbonyls and/or oils from the first product flow comprising CO, the flow of material comprising CO to be returned and/or the combined flow of material comprising the first educt flow and the flow of material comprising CO to be returned and which is embodied to remove carbonyls and/or oils from the first product flow comprising CO, the flow of material comprising CO to be returned and/or the combined flow of material comprising the first educt flow and the flow of material comprising CO to be returned and which is arranged accordingly in the first discharge device, in the return device and/or in the combined feed device;

wherein the at least one cleaning device comprises a heating device to break down carbonyls and/or oils, wherein a moistener is connected in the direction of flow after the at least one cleaning device, in which water is fed to the first product flow comprising CO, to the flow material to be returned comprising CO and/or to the combined flow of material comprising the first educt flow and the flow material to be returned comprising CO and which is embodied to feed water to the first product flow comprising CO, to the flow of material to be returned comprising CO and/or to the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO.

2. The facility as claimed in claim 1 , further comprising:

at least one compressor, which is arranged in the direction of flow in the first product flow comprising CO, in the flow of material to be returned comprising CO and/or in the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO before the at least one cleaning device in the first discharge device, in the return device and/or in the combined feed device.

3. The facility as claimed in claim 2 ,

wherein the at least one compressor is embodied in such a way that the first product flow comprising CO, the flow of material to be returned comprising CO and/or the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO does not come into contact with oil used in the compressor.

4. The facility as claimed in claim 1 ,

wherein the first discharge device, the return device and/or in the combined feed device in the direction of flow behind the at least one cleaning device, at least in parts that come into contact with the first product flow comprising CO, the flow of material to be returned comprising CO and/or the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO consists of a material or is coated with a material that is selected from iron and nickel-free metallic materials, plastic, steels containing Cr and/or mixtures thereof.

5. The facility as claimed in claim 1 ,

wherein the separation device comprises a separation membrane, an adsorbent, an absorbent, a condenser, a distillation unit and/or a second heating device.

6. The facility as claimed in claim 1 ,

wherein the first discharge device, the separation device, the return device, the at least one cleaning device and/or in the combined feed device and/or if necessary at least one compressor, at least in parts that come into contact with the first product flow comprising CO, the flow of material to be returned comprising CO and/or the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO consists of a material or is coated with a material that is selected from iron and nickel-free metallic materials, plastic, steels containing Cr and/or mixtures thereof.

7. The facility as claimed in claim 1 , further comprising:

a deoxo unit, which is located in the first discharge device and which is embodied to remove oxygen from the first product flow comprising CO.

8. A method for electrochemical production of a product containing CO using the facility as claimed in claim 1 , comprising:

introducing the first educt flow into the first feed device of the facility;

feeding the first educt flow to the electrolysis cell;

converting the first educt flow to a first product flow comprising CO;

discharging the first product flow comprising CO from the electrolysis cell;

separating a flow of material to be returned comprising CO from the product flow comprising CO in the separation device; and

returning the flow of material to be returned comprising CO to the combined feed device, and

removing, with the at least one cleaning device, the carbonyls and/or oils from the first product flow comprising CO, the flow of material to be returned comprising CO and/or the combined flow of material comprising the first educt flow and the flow of material to be returned comprising CO.

9. The method as claimed in claim 8 ,

wherein the first educt flow is a gas flow that comprises CO 2 .

10. The method as claimed in claim 8 ,

wherein the first educt flow is a gas flow that is introduced into the first feed device under increased pressure, wherein preferably the at least one cleaning device is provided in the combined feed device.

11. The method as claimed in claim 8 ,

wherein the first educt flow is a gas flow that is introduced into the first feed device at ambient pressure, wherein the first product flow comprising CO is compressed.

12. The method as claimed in claim 11 ,

wherein the at least one cleaning device is arranged after a compressor for compressing the first product flow comprising CO and before the separation device.

13. The method as claimed in claim 8 ,

wherein a second product flow comprising hydrogen and where necessary CO is furthermore separated in the separation device from the first product flow comprising CO.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2021
From: SIEMENS AKTIENGESELLSCHAFT
To: SIEMENS ENERGY GLOBAL GMBH & CO. KG
Reel/Frame 058597/0317 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2020
From: HANEBUTH, MARC; SCHMID, GÜNTER; TAROATA, DAN
To: SIEMENS AKTIENGESELLSCHAFT
Reel/Frame 053402/0647 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2020
From: DELHOMME-NEUDECKER, CLARA; PESCHEL, ANDREAS; SCHÖDEL, NICOLE
To: LINDE AKTIENGESELLSCHAFT
Reel/Frame 053402/0750 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2020
From: LINDE AKTIENGESELLSCHAFT
To: LINDE GMBH
Reel/Frame 053402/0770 →