IP Library Granted Patent US 11,547,115
Granted Patent B2
US 11,547,115 · App. 16/972,095 · Granted Jan 10, 2023

Wettable agrochemical composition

Inventors: Yoshinori Muramatsu (Ibaraki, JP); Hidetoshi Shirakura (Ibaraki, JP); Atsushi Sato (Kanagawa, JP); Mitsuyuki Yabuzaki (Kanagawa, JP); Shigeru Ueno (Kanagawa, JP)
Assignees: NIPPON KAYUKU CO., LTD.; MMAG CO., LTD.
A01N47/06A01N25/14A01N25/24A01N25/30
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Quick Facts
Patent No.
US 11,547,115
App. No.
16/972,095
Granted
Jan 10, 2023
Kind
B2
Abstract

Disclosed is a wettable agrochemical composition comprising an agrochemical active component (A), which is a compound represented by the following formula (I) or an agriculturally and horticulturally acceptable acid addition salt thereof, one or more additives, and one or more surfactants, the wettable agrochemical composition being solid at 30° C. This wettable agrochemical composition has excellent physical properties of the formulation and storage stability.

Claims (15)

1. A wettable powder composition, comprising flometoquin as an agrochemical active component (A), a saccharide, a mineral powder carrier, at least one surfactant, and optionally at least one additional additive selected from the group consisting of a binder and an inorganic salt,

wherein the saccharide is at least one selected from the group consisting of lactose, dextrin, a starch derivative and a cellulose derivative, and the mineral powder carrier is at least one selected from the group consisting of white clay, diatomaceous earth and volcanic ash soil,

wherein the wettable powder composition is solid at 30° C., and

wherein the agrochemical active component (A) is in a form of a wet-pulverized product obtained by wet pulverization along with the surfactant, and a volume median diameter of the agrochemical active component (A) in a suspension liquid obtained upon wet pulverization is from 0.1 to 5.0 um.

2. The wettable powder composition according to claim 1 , further comprising one or more other agrochemical active component (B), wherein a mixture of the agrochemical active component (A) and the agrochemical active component (B) is in a form of a wet-pulverized product obtained by wet pulverization along with the surfactant, and a volume median diameter of the agrochemical active component (A) and the agrochemical active component (B) in a suspension liquid obtained upon wet pulverization is from 0.1 to 5.0 μm.

3. The wettable powder composition according to claim 2 , wherein the agrochemical active component (B) is at least one component selected from the group consisting of an insecticide effective component and a fungicide effective component.

4. The wettable powder composition according to claim 2 , wherein the agrochemical active component (B) is at least one agent selected from the group consisting of organophosphorus-based, carbamate-based, pyrethroid-based, neonicotinoid-based, nicotine-based, butenolide-based, cyclic diene organochlorine-based, benzene dicarboxamide-based, nereistoxin-based, IGR-based, pyrrole-based, macrolide-based, juvenile hormone analogue-based, benzoylurea-based, spinosyn-based, quinazoline-based, phenylpyrazole-based, oxadiazine-based, hydrazinecarboxamide-based, phenoxybenzylamide-based, pyridineazomethine-based, pyridinecarboxyamide-based, organosilicon-based, tetronic acid-based, β-ketonitrile derivative-based, phosphine-based, METI agent-based, BT agent-based, copper agent-based, sulfur agent-based, polyhaloalkylthio-based, sodium bicarbonate agent-based, organochlorine-based, benzimidazole-based, dicarboximide-based, carboxyamide-based, phenylamide-based, dimethomorph-based, cymoxanil-based, cyanoimidazole-based, acylalanine-based, oxazolidinone-based, butyrolactone-based, hydroxy-(2-amino-)pyrimidine-based, isoxazole-based, isothiazolone-based, carboxylic acid-based, thiophanate-based, N-phenylcarbamate-based, benzamide-based, thiazolecarboxamide-based, phenylurea-based, pyrimidineamine-based, pyrazolecarboxamide-based, phenylbenzamide-based, phenyloxoethyl thiopheneamide-based, pyridinyl ethyl benzamide-based, furancarboxamide-based, oxathiincarboxamide-based, thiazolecarboxamide-based, pyrazolecarboxamide-based, pyridinecarboxamide-based, methoxyacrylate-based, methoxycarbamate-based, oxyiminoacetic acid-based, oxyiminoacetamide-based, oxazolinedione-based, dihydrodioxazine-based, imidazolinone-based, benzylcarbamate-based, cyanoimidazole-based, sulfamoyltriazole-based, dinitrophenylcrotonic acid-based, 2,6-dinitroaniline-based, triphenyltin-based, thiophenecarboxamide-based, thiophenecarboxamide-based, thiazolopyrimidylamine-based, anilinopyrimidine-based, enopyranuronic acid antibiotic-based, hexopyranosyl antibiotic-based, glucopyranosyl antibiotic-based, tetracycline antibiotic-based, allyloxyquinoline-based, quinazoline-based, phenylpyrrole-based, dicarboximide-based, phosphorothiolate-based, dithiolane-based, aromatic hydrocarbon-based, 1,2,4-thiadiazole-based, carbamate-based, polypeptide-based, piperazine-based, pyrimidine-based, pyridine-based, imidazole-based, triazole-based, triazolinthione-based, morpholine-based, piperidine-based, spiroketalamine-based, hydroxyanilide-based, aminopyrazolinone-based, thiocarbamate-based, allylamine-based, peptidylpyrimidine nucleoside-based, cinnamic acid amide-based, valinamide carbamate-based, mandelic acid amide-based, isobenzofuranone-based, pyrroloquinolinone-based, triazolobenzothiazole-based, cyclopropanecarboxamide-based, carboxamide-based, propionamide-based, benzothiadiazole-based, benzisothiazole-based, thiadiazolecarboxamide-based, polysaccharide-based, cyanoacetamide-oxime-based, ethylphosphonate-based, phthalamic acid-based, benzotriazine-based, benzenesulfonic acid-based, pyridazinone-based, thiocarbamate-based, phenylacetamide-based, benzophenone-based, benzoylpyridine-based, guanidine-based, cyanomethylenethiazolidine-based, pyrimidinonehydrazone-based, dithiocarbamate-based, phthalimide-based, chloronitrile-based, sulfamide-based, triazine-based, quinone-based, quinoxaline-based, maleimide-based, and mesoion-based agents.

5. The wettable powder composition according to claim 2 , wherein the agrochemical active component (B) is at least one agent selected from the group consisting of diazinon, acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, fenitrothion, isoxathion, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, dimeton-S-methyl, dichlorvos, dicrotophos, dimethoate, dimethylvinphos, ethylthiometon, EPN, ethion, ethoprophos, famphur, fenamiphos, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion, methyl parathion, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos-methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon, vamidothion, prothiofos, malathion, PAP, DEP, EPN, methomyl, thiodicarb, benfuracarb, carbosulfan, alanycarb, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, cyfluthrin, cyhalothrin, cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin, prallethrin, cyhalothrin, tefluthrin, phthalthrin, tralomethrin, transfluthrin, DDT, methoxychlor, imidacloprid, thiamethoxam, clothianidin, acetamiprid, nitenpyram, thiacloprid, dinotefuran, nicotine sulfate, sulfoxaflor, flupyradifurone, hydroprene, kinoprene, methoprene, pyriproxyfen, chlordane, benzoepin, flubendiamide, chlorantraniliprole, cyantraniliprole, thiocyclam, cartap, bensultap, thiosultap, chromafenozide, methoxyfenozide, halofenozide, tebufenozide, chlorfluazuron, trigard, amitraz, hydramethylnon, acequinocyl, fluacrypyrim, fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, derris extract, chlorfenapyr, DNOC, sulfluramid, emamectin, lepimectin, milbemectin, abamectin, spinosad, spinetoram, bistrifluron, diflubenzuron, flucycloxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron, buprofezin, cyromazine, pyrifluquinazon, fipronil, ethiprole, fenoxycarb, indoxacarb, metaflumizone, spirodiclofen, spiromesifen, spirotetramat, pymetrozine, flonicamid, chloropicrin, sulfuryl fluoride, clofentezine, hexythiazox, diflovidazin, etoxazole, diafenthiuron, azocyclotin, tricyclohexyltin hydroxide, fenbutatin oxide, propargite, tetradifon, silafluofen, aluminum phosphide, calcium phosphide, hydrogen phosphide, zinc phosphide, cyenopyrafen, cyflumetofen, azadirachtin, benzoximate, bifenazate, bromopropylate, quinomethionate, sodium aluminum fluoride, dicofol, pyridalyl, inorganic copper, organic copper, inorganic sulfur, polycarbamate, benalaxyl, furalaxyl, metalaxyl, oxadixyl, ofurace, bupirimate, dimethirimol, ethirimol, hydroxyisoxazole, octhilinone, oxolinic acid, benomyl, carbendazol, fuberidazole, thiabendazole, thiophanate, thiophanate-methyl, diethofencarb, zoxamide, ethaboxam, pencycuron, fluopicolide, diflumetorim, benodanil, flutolanil, mepronil, isofetamid, fluopyram, fenfuram, carboxin, oxycarboxin, thifluzamide, benzovindiflupyr, bixafen, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, boscalid, azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin, pyraclostrobin, pyrametostrobin, triclopyricarb, kresoxim-methyl, trifloxystrobin, dimoxystrobin, fenaminstrobin, metominostrobin, orysastrobin, famoxadone, fluoxastrobin, fenamidone, pyribencarb, cyazofamid, amisulbrom, binapacryl, meptyldinocap, dinocap, fluazinam, ferimzone, organotin, silthiofam, ametoctradin, cyprodinil, mepanipyrim, pyrimethanil, blasticidin S, kasugamycin, streptomycin, oxytetracycline, quinoxyfen, proquinazid, fenpiclonil, fludioxonil, chlozolinate, iprodione, procymidone, vinclozolin, edifenphos, iprobenfos, pyrazophos, isoprothiolane, biphenyl, chloroneb, dichloran, quintozene, tecnazene, tolclofos-methyl, echlomezol, iodocarb, propamocarb, prothiocarb, Bacillus subtilis, triforine, pyrifenox, pyrixazole, fenarimol, nuarimol, imazalil, oxpoconazole, pefurazoate, prochloraz, triflumizole, azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, prothioconazole, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine, fenhexamid, fenpyrazamine, pyributicarb, naftifine, terbinafine, validamycin, polyoxin, dimethomorph, flumorph, pyrimorph, benthiavalicarb, iprovalicarb, valifenalate, mandipropamid, fthalide, pyroquilon, tricyclazole, carpropamid, diclocymet, fenoxanil, acibenzolar-S-methyl, probenazole, tiadinil, isotianil, laminarin, cymoxanil, fosetyl, tecloftalam, triazoxide, flusulfamide, diclomezine, methasulfocarb, cyflufenamid, metrafenone, pyriofenone, guanidine, flutianil, ferimzone, ferbam, manzeb, maneb, metiram, propineb, thiuram, zineb, captan, difolatan, folpet, TPN, dichlofluanid, tolylfluanid, guazatine, iminoctadine, triazine, dithianon, quinomethionate, fluoroimide, triflumezopyrim, and dicloromezotiaz.

6. The wettable powder composition according to claim 1 , wherein the composition comprises at least one binder selected from the group consisting of polyvinylpyrrolidone, polyvinyl alcohol, methyl cellulose, and carboxymethyl cellulose.

7. The wettable powder composition according to claim 1 , wherein the composition comprises at least one inorganic salt selected from the group consisting of potassium dihydrogen phosphate, sodium chloride, potassium chloride, and ammonium sulfate.

8. The wettable powder composition according to claim 1 , wherein the surfactant is at least one selected from the group consisting of polyoxyethylene alkylether sulfate, polyoxyethylene ether phosphate, polyoxyethylated castor oil, alkylnaphthalenesulfonate-formaldehyde condensate, dioctyl sulfosuccinate, and polycarboxylic acid.

9. A method for producing the wettable powder composition according to claim 1 , comprising a step of wet-pulverizing the agrochemical active component (A) along with the surfactant to obtain a wet-pulverized liquid, wherein a volume median diameter of the agrochemical active component (A) in a suspension liquid obtained by wet pulverization is from 0.1 to 5.0 μm, and combining the wet-pulverized liquid with the saccharide, the mineral powder carrier and optionally the binder and the inorganic salt.

10. A method for producing the wettable powder composition according to claim 2 , comprising a step of wet-pulverizing a mixture of the agrochemical active component (A) and the agrochemical active component (B) along with the surfactant to obtain a wet-pulverized liquid, wherein the volume median diameter of the agrochemical active component (A) and the agrochemical active component (B) in a suspension liquid obtained by wet pulverization is from 0.1 to 5.0 μm, and combining the wet-pulverized liquid with the saccharide, the mineral powder carrier and optionally the binder and the inorganic salt.

11. The wettable powder composition according to claim 1 , wherein the composition is a wettable powder or a granular wettable powder.

12. The wettable powder composition according to claim 1 , wherein the composition is prepared by adding and mixing the saccharide, the mineral powder carrier, and optionally the at least one additive to a pulverized slurry of agrochemical active component (A) to obtain a mixture, and then subjecting the mixture to drying and sieving.

Assignments (3)
CHANGE OF NAME Recorded Feb 7, 2024
From: MITSUI CHEMICALS AGRO, INC.
To: MITSUI CHEMICALS CROP & LIFE SOLUTIONS, INC.
Reel/Frame 066508/0493 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 21, 2022
From: MEIJI SEIKA PHARMA CO., LTD.
To: MMAG CO., LTD.
Reel/Frame 060582/0126 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 30, 2020
From: MURAMATSU, YOSHINORI; SHIRAKURA, HIDETOSHI; SATO, ATSUSHI; YABUZAKI, MITSUYUKI; UENO, SHIGERU
To: NIPPON KAYUKU CO., LTD.; MEIJI SEIKA PHARMA CO., LTD.
Reel/Frame 054774/0416 →