Two-part urethane adhesive composition
A two-part urethane adhesive composition that provides excellent initial adhesiveness and excellent long-term adhesiveness. An embodiment of the present invention is a two-part urethane adhesive composition including a main agent containing a urethane prepolymer having an isocyanate group, and a curing agent containing a compound (A) having two or more active hydrogen-containing groups per molecule, the compound (A) including a polyol compound (a1), the polyol compound (a1) having three active hydrogen-containing groups per molecule, having ethylene oxide at a terminal, having a number average molecular weight of greater than 1000 and 20000 or less, having a degree of unsaturation of 0.01 meq/g or less, and having molecular weight distribution (Mw/Mn) of 1.05 or less, and a molar ratio of a total amount of active hydrogen in the compound (A) with respect to an amount of the isocyanate group being 0.2 or greater and less than 0.8.
1. A two-part urethane adhesive composition comprising:
a main agent containing a urethane prepolymer having an isocyanate group; and
a curing agent containing a compound (A) having two or more active hydrogen-containing groups per molecule;
the compound (A) comprising a polyol compound (a1) and a polyol compound (a2), the polyol compound (a1) having three active hydrogen-containing groups per molecule, having ethylene oxide at a terminal, having a number average molecular weight of greater than 1000 and 20000 or less, having a degree of unsaturation of 0.01 meq/g or less, and having molecular weight distribution (Mw/Mn) of 1.05 or less, and
the polyol compound (a2), having three or more active hydrogen-containing groups per molecule and having a number average molecular weight of from 200 to 1000, and
a molar ratio of a total amount of active hydrogen in the compound (A) with respect to an amount of the isocyanatc group being 0.2 or greater and less than 0.8,
wherein an amount (H1) of active hydrogen in the polyol compound (a1) is from 20 to 80 mol % with respect to a total of the amount (H1) and an amount (H2) of active hydrogen in the polyol compound (a2), and
the amount (H2) is from 80 to 20 mol % with respect to the total of the amount (H1) and the amount (H2).
2. The two-part urethane adhesive composition according to claim 1 , wherein each of the active hydrogen-containing groups in the polyol compound (a1) is a hydroxyl group,
the ethylene oxide in the polyol compound (a1) is represented by —(CH 2 CH 2 -0) r1 -, where the r1 moiety is 1 or 2 or greater, and
the hydroxy group and the —(CH 2 CH 2 -0) r1 - moiety are linked to form —(CH 2 CH 2 -0) r1 -H.
3. The two-part urethane adhesive composition according to claim 2 , wherein the polyol compound (a1) has three —(CH 2 CH 2 —O) r1 —H moieties per molecule.
4. The two-part urethane adhesive composition according to claim 1 , wherein, in the polyol compound (a1), each of the active hydrogen-containing groups is bonded to a linking group via the ethylene oxide.
5. The two-part urethane adhesive composition according to claim 1 , wherein the polyol compound (a2) has ethylene oxide at a terminal.
6. The two-part urethane adhesive composition according to claim 1 , wherein
each of the active hydrogen-containing groups in the polyol compound (a2) is a hydroxyl group,
the polyol compound (a2) has ethylene oxide at a terminal,
the ethylene oxide in the polyol compound (a2) is represented by —(CH 2 CH 2 -0) r2 -, where the r2 moiety is 1 or 2 or more, and
the hydroxy group and the —(CH 2 CH 2 -0) r2 - moiety are linked to form —(CH 2 CH 2 -0) r2 -H.
7. The two-part urethane adhesive composition according to claim 6 , wherein the polyol compound (a2) has four or more —(CH 2 CH 2 -0) r2 -H moieties per molecule.
8. The two-part urethane adhesive composition according to claim 1 , wherein
the polyol compound (a2) has ethylene oxide at a terminal and,
in the polyol compound (a2), each of the active hydrogen-containing groups is bonded to a linking group via the ethylene oxide.
9. The two-part urethane adhesive composition according to claim 1 , used for adhering of a base material.
10. The two-part urethane adhesive composition according to claim 9 , wherein the base material comprises a polyolefin.
11. The two-part urethane adhesive composition according to claim 1 , wherein
the composition further comprises an amine-based curing catalyst, and
the amine-based curing catalyst is contained at an amount of 0.05 to 0.5 parts by mass with respect to 100 parts by mass of the urethane prepolymer.
12. The two-part urethane adhesive composition according to claim 1 , wherein the compound A consists of the polyol compound (a1) and the polyol compound (a2).
13. The two-part urethane adhesive composition according to claim 1 , wherein the polyol compound (a2) has a number average molecular weight of from 200 to 500.