Polymer composition and molded part made thereof
The invention relates to a polyamide polymer; to a polymer composition comprising the polyamide polymer and a fibrous reinforcing agent or a filler, or a combination thereof; to a molded part made of the polymer composition; and to an automotive vehicle comprising a load-bearing structural part made of the molded part. Herein the polyamide polymer has a glass transition temperature (Tg) of at least 145° C. and a dynamic modulus (E′), measured at a temperature (Tmod) equal to Tg+15° C., in the range of 100 MPa-700 MPa.
1. A polyamide polymer comprising a blend of at least two polyamides having an overall monomer composition represented by one of the notations ZT/CT, ZT/CT/ZI/CI, ZT/CT/BT, and ZT/CT/BT/ZI/CI/BI, wherein
X represents a linear aliphatic C4-C5 diamine
Y represents a linear aliphatic diamine with at least 6 carbon atoms,
Z represents a linear aliphatic diamine with at least 4 carbon atoms,
wherein (Z) is at least one of (X) and (Y);
I represents isophthalic acid;
T represents terephthalic acid;
B represents a branched diamine; and
C represents a cyclic diamine, and wherein
the polyamides comprise:
0-35 mole % (I) and 65-100 mole % (T), relative to the total molar amount of (I)+(T), and either
15 mole %-80 mole % (X), 0-70 mole % (Y), 10-40 mole % (C), and 0-30 mole % (B), relative to the total molar amount of (X)+(Y)+(B)+(C); or
0-20 mole % (X), 10-80 mole % (Y), 15-40 mole % (C) and 0-30 mole % (B) and relative to the total molar amount of (X)+(Y)+(B)+(C) with the proviso that Y represents a linear aliphatic diamine with 9 or 10 carbon atoms, and wherein
the polyamide polymer has a glass transition temperature (Tg) of at least 145° C. and a dynamic modulus (E′), measured at a temperature (Tmod) equal to Tg+15° C., in the range of 100 MPa-700 MPa, wherein both Tg and E are measured by dynamic mechanical thermal analysis (DMTA) according to the method of ASTM-D5026-15.
2. The polyamide polymer according to claim 1 , wherein E′ at Tmod is in the range of 200 MPa-650 MPa, and/or wherein the polyamide polymer has a glass transition temperature (Tg) of at least 150° C.
3. The polyamide polymer according to claim 1 , wherein the polyamide polymer comprises a semi-crystalline semi-aromatic polyamide having a melting temperature (Tm) of at least 280° C.
4. The polyamide polymer according to claim 1 , comprising repeat units, at least 95 mole % of which are derived from diamine and dicarboxylic acid, wherein at least 40 mole % of the repeat units, relative to the molar amount of diamine and dicarboxylic acid, are derived from a cyclic monomer.
5. The polyamide polymer according to claim 4 , wherein the cyclic monomer comprises an aromatic monomer, a cycloaliphatic monomer, or a combination of an aromatic monomer and a cycloaliphatic monomer.
6. A polymer composition comprising:
(a) the polyamide polymer according to claim 1 ; and
(b) a fibrous reinforcing agent or a filler, or a combination thereof; wherein
the polyamide polymer has a glass transition temperature (Tg) of at least 145° C. and a dynamic modulus (E′) at a temperature (Tmod) equal to Tg+15° C., of at most 700 MPa, and wherein both the Tg and E′ are measured by DMTA, with the method according to ASTM-D5026-15.
7. The polymer composition according to claim 6 , wherein the fibrous reinforcing agent comprises glass fibers, carbon fibers, or a combination thereof.
8. The polymer composition according to claim 6 , wherein the polymer composition comprises
(a) 30-80 wt. % of the polyamide polymer, and
(b) 20-70 wt. % of the fibrous reinforcing agent or the filler, or the combination thereof; wherein
the weight percentages are relative to the total weight of the polymer composition.
9. The polymer composition according to claim 6 , wherein the glass transition temperature (Tg) of the polyamide polymer is at least 150° C., and/or the dynamic modulus (E′) at the temperature Tmod equal to Tg+15° C. is in the range of 100 MPa-700 MPa.
10. A molded part comprising the polymer composition according to claim 6 .
11. The molded part according to claim 10 , wherein the molded part is a load bearing structural part for use in an automotive engine compartment.
12. The molded part according to claim 11 , wherein the load bearing structural part is an engine mount, an engine cover or a housing for an engine part.
13. An automotive vehicle which comprises the molded part according to claim 10 .