Phospate recovery by acid retardation
A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.
1. A system comprising:
a vessel comprising a sorption agent;
a source of a process water stream comprising a first concentration of phosphoric acid and at least one salt, the source of the process water stream fluidly connected to an inlet of the vessel;
a source of water having an outlet fluidly connected to the vessel;
an effluent outlet of the vessel;
a valve fluidly coupled to the effluent outlet of the vessel;
a high salts effluent storage unit fluidly coupled to the valve;
a recovered phosphoric acid storage unit fluidly coupled to the valve;
a source of a pH adjuster fluidly connected to the process water stream;
a pH sensor configured to detect a pH of the process water stream and to output a pH signal indicative of the pH; and
a controller operably coupled to the pH sensor and to the source of pH adjuster, the controller configured to receive the pH signal and to send a control signal to the source of pH adjuster causing the source of pH adjuster to dispense pH adjuster into the process water stream to be treated in response to receiving the signal, the controller configured to dispense pH adjuster to adjust the pH of the process water stream to be between about 1 and about 1.5 in a first mode or between about 2 and about 3 in a second mode,
wherein the controller is further operably coupled to the valve and configured to control the valve to output a first effluent stream having a second concentration of phosphoric acid through the effluent outlet to the high salts effluent storage unit for a first period of time and to output a second effluent having a third concentration of phosphoric acid through the effluent conduit to the recovered phosphoric acid storage unit for a second period of time, the third concentration being higher than the second concentration.
2. The system of claim 1 , wherein the vessel comprises a plurality of sorption agent columns arranged one of in series, in parallel, and in a combination of series and parallel.
3. The system of claim 1 , wherein the sorption agent disposed in the vessel comprises cation exchange resin.
4. The system of claim 1 , wherein the sorption agent disposed in the vessel comprises anion exchange resin.