Pressure sensitive adhesive particle and method of producing printed matter
A pressure sensitive adhesive particle includes a styrene resin; and a (meth)acrylate resin, wherein the (meth)acrylate resin contains two kinds of (meth)acrylates as a polymerization component in which the weight proportion of the (meth)acrylate to the total polymerization components is 90% by weight or more, and has two glass transition points in which a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or higher.
1. A pressure sensitive adhesive particle comprising:
a styrene resin; and
a (meth)acrylate resin,
wherein the styrene resin is derived from styrene resin polymerization components, the styrene resin polymerization components including styrene and at least one selected from the group consisting of 2-ethyl hexyl acrylate and n-butyl acrylate,
wherein the (meth)acrylate resin is derived from alkyl (meth)acrylate polymerization components, the alkyl (meth)acrylate polymerization components including 2-ethyl hexyl acrylate and n-butyl acrylate,
a weight proportion of the alkyl (meth)acrylate polymerization components to a total polymerization components of the (meth)acrylate resin is 90% by weight or more,
the pressure sensitive adhesive has two glass transition points,
a difference between a lowest glass transition temperature and a highest glass transition temperature of the pressure sensitive adhesive is 30° C. or higher,
a weight ratio among the 2-ethyl hexyl acrylate and n-butyl acrylate of the alkyl (meth)acrylate polymerization components of the (meth)acrylate resin is from 80:20 to 20:80,
the pressure sensitive adhesive particle includes:
a core portion that contains the styrene resin and the (meth)acrylate resin; and
a shell layer that covers the core portion and contains the styrene resin,
a glass transition temperature of the (meth)acrylate resin is −10° C. or lower,
the core portion comprises:
a sea phase that contains the styrene resin; and
an island phase that contains the (meth)acrylate resin dispersed in the sea phase, and
an average diameter of the island phases is from 200 nm to 500 nm.
2. The pressure sensitive adhesive particle according to claim 1 ,
wherein a weight proportion of styrene to total polymerization components for the styrene resin is from 60% by weight to 95% by weight.
3. The pressure sensitive adhesive particle according to claim 1 ,
wherein a content of the styrene resin is larger than a content of the (meth)acrylate resin.
4. The pressure sensitive adhesive particle according to claim 1 ,
wherein a temperature at which the toner has a viscosity of 10,000 Pa's under a pressure of 4 MPa is 90° C. or lower.
5. The pressure sensitive adhesive particle according to claim 1 ,
wherein the average thickness of the shell layer is 120 nm or more and 550 nm or less.
6. The pressure sensitive adhesive particle according to claim 1 , wherein a temperature difference (T1−T3) between a temperature T1 at which the adhesive particle has a viscosity of 10,000 Pa·s under a pressure of 1 MPa and a temperature T3 at which the adhesive particle has a viscosity of 10,000 Pa·s under a pressure of 4 MPa is 5° C. or higher.
7. The pressure sensitive adhesive particle according to claim 1 , wherein a temperature difference (T1−T3) between a temperature T1 at which the adhesive particle has a viscosity of 10,000 Pa·s under a pressure of 1 MPa and a temperature T3 at which the adhesive particle has a viscosity of 10,000 Pa·s under a pressure of 4 MPa is 10° C. or higher.
8. The pressure sensitive adhesive particle according to claim 1 , further comprising:
silica particles having an average primary particle diameter of 1 nm to 300 nm or titanium oxide particles as an external additive.
9. The pressure sensitive adhesive particle according to claim 8 ,
wherein an average primary particle diameter of the titanium oxide particles is from 10 nm to 100 nm.
10. The pressure sensitive adhesive particle according to claim 8 ,
wherein an external addition amount of the silica particles is 1 part by weight to 3 parts by weight with respect to 100 parts by weight of toner particles included in the toner.
11. The pressure sensitive adhesive particle according to claim 8 ,
wherein a content of the titanium oxide particles is 0.5 parts by weight to 5 parts by weight with respect to 100 parts by weight of toner particles included in the toner.
12. A method of producing a printed matter, the method comprising:
arranging a pressure sensitive adhesive particle according to claim 1 on a recording medium; and
folding and pressure-bonding the recording medium or stacking and pressure-bonding the recording medium and another recording medium.