Oxygen scavenging polyester compositions for containers
Disclosed herein is an oxygen scavenging composition for containers. The oxygen scavenging composition for containers may comprise at least one polyester component, a transition metal catalyst, an oxygen scavenger, and a vegetable oil. The vegetable oil preferably comprises at least one molecule having a double allylic structure. The polyester component preferably comprises at least one acid unit and at least one diol unit. The concentration of double allylic structures of the vegetable oil in the composition may be greater than 5.0 meq/kg of all of the polyester components. The oxygen scavenger is preferably present in the composition at a level less than 1.0% by weight of the total composition. The vegetable oil is preferably present in the composition at a level greater than 0.3% by weight relative to the total weight of the polyester components, the transition metal catalyst and the vegetable oil.
1. An oxygen scavenging composition for containers comprising:
at least one polyester component,
a transition metal catalyst,
an oxygen scavenger, and
a vegetable oil comprising at least one molecule having a double allylic structure,
wherein the at least one polyester component comprises at least one acid unit and at least one diol unit, the concentration of the double allylic structures of the vegetable oil in the composition is greater than 7 meq/kg of all of the polyester components, the oxygen scavenger is present in the composition in a traditionally inert amount in the range of between 0.05% by weight and 0.9% by weight of the composition, and the vegetable oil is present in the composition at a level greater than 0.3% by weight relative to the total weight of the polyester components, the transition metal catalyst and the vegetable oil.
2. The composition of claim 1 , wherein the at least one polyester component is a copolyester containing a metal sulfonate salt group.
3. The composition of claim 2 , wherein the metal sulfonate salt group is a metal sulfoisophthalate derived from a metal salt of 5-sulfoisophthalic acid, its dimethyl ester or its glycol ester.
4. The composition of claim 3 , wherein the metal salt of 5-sulfoisophthalic acid, its dimethyl ester or its glycol ester comprises a metal ion selected from the group consisting of Na + , Li + , K + , Zn 2+ , Mn 2+ , Co 2+ and Ca 2+ .
5. The composition of claim 2 , wherein the metal sulfonate salt group is in a range selected from the group consisting of 0.01 to 10.0 mole percent, 0.01 to 2.0 mole percent, 0.05 to 1.1 mole percent, 0.10 to 0.74 mole percent and 0.10 to 0.6 mole percent based upon the total moles of acid units in all of the polyester components.
6. The composition of claim 1 , wherein the transition metal catalyst is a compound containing at least one cobalt atom in a positive oxidation state.
7. The composition of claim 1 , wherein the transition metal catalyst is a salt containing at least one cobalt atom in a positive oxidation state.
8. The composition of claim 1 , wherein the transition metal catalyst is added to the composition at a level in a range selected from the group of between 10 and 600 ppm, between 20 and 400 ppm and between 40 and 200 ppm of metal relative to the total amount of the polyester components and vegetable oil present in the composition.
9. The composition of claim 1 , wherein the vegetable oil is selected from the group consisting of flax seed oil, linseed oil, evening primrose oil, borage oil, sunflower oil, soybean oil, grapeseed oil, corn oil, cotton seed oil, rice bran oil, canola oil and peanut oil.
10. The composition of claim 1 , wherein the oxygen scavenger is a polyamide.
11. The composition of claim 10 , wherein the oxygen scavenger is present in the composition at a level in a range selected from the group consisting of between 0.1 and 0.9% by weight of the total composition, between 0.1 and 0.8% by weight of the total composition, between 0.1 and 0.7% by weight of the total composition and between 0.1 and 0.6% by weight of the total composition.
12. The composition of claim 1 , wherein the oxygen scavenger is poly-metaxylylene adipamide.
13. The composition of claim 1 , wherein the oxygen scavenger is selected from the group consisting of m-xylylenediamine-bis(phthalamide), N,N-bis(phenylmethyl)hexanediamide, N-allylic amide compounds, oligomer or polymers, N-benzylic amide compounds, oligomers or polymers and combinations thereof.
14. The composition of claim 13 , wherein the oxygen scavenger is present in the composition at a level in a range of between 0.1 and 0.5% by weight of the total composition.
15. The composition of claim 1 , wherein the composition further comprises TiO 2 .
16. The composition of claim 15 , wherein the TiO 2 is present in the composition at a level in a range selected from the group consisting of between 0.1 and 15% by weight of the composition, between 0.1 and 10% by weight of the composition, between 0.1 and 5% by weight of the composition and between 0.1 and 2% by weight of the composition.
17. A film manufactured from the composition of claim 1 .
18. A sheet manufactured from the composition of claim 1 .
19. A preform manufactured from the composition of claim 1 .
20. A biaxially oriented container manufactured from the preform of claim 19 .