IP Library Granted Patent US 11,643,524
Granted Patent B2
US 11,643,524 · App. 17/015,621 · Granted May 9, 2023

Lightweight reinforced composite formulation and method of making the same

Inventors: Santosh K. Yadav (Geneva, OH); Paul A. Rettinger (Ashtabula, OH); Cheryl L. Ludwig (Ashtabula, OH)
C08K7/28C08J3/212C08K3/40C08L67/06C08L2312/08
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Quick Facts
Patent No.
US 11,643,524
App. No.
17/015,621
Granted
May 9, 2023
Kind
B2
Abstract

A composite formulation for use in lightweight molded components includes an untreated low density filler, such as glass bubbles, a solvated polymer mixture, and polymer paste. In one embodiment the solvated polymer mixture is used to treat the low density filler to form a treated low density filler. The solvated polymer mixture many include a thermoplastic resin or a reactive resin and an additive package. The additive package may include a dispersing agent and a silane carrier composition.

Claims (33)

1. A composite formulation for use in lightweight molded components, wherein the composite formulation comprises

a treated low density filler comprising

an untreated low density filler and

a solvated polymer mixture, wherein the solvated polymer mixture comprises a thermoplastic resin or a reactive resin and an additive package, the additive package comprising a dispersing agent;

wherein the solvated polymer mixture is present in an amount of about 0.5% to about 20% by weight based on the weight of the untreated low density filler; and

wherein the solvated polymer mixture is combined with about 80% to about 99.5% by weight of the untreated low density filler to form the treated low density filler.

2. The composite formulation of claim 1 , wherein the additive package further comprises a silane carrier composition.

3. The composite formulation of claim 1 , wherein the composite formulation further comprises a polymer paste.

4. The composite formulation of claim 1 , wherein the solvated polymer mixture comprises about 20% to about 97% by weight of the additive package and about 3% to about 80% by weight of the thermoplastic resin or a reactive resin.

5. The composite formulation of claim 4 , wherein the solvated polymer mixture comprises about 60% by weight of the additive package and about 40% by weight of the thermoplastic resin or reactive resin.

6. A composite formulation for use in lightweight molded components, wherein the composite formulation comprises:

an untreated low density filler;

a solvated polymer mixture, wherein the solvated polymer mixture comprises a thermoplastic resin or a reactive resin and an additive package, the additive package comprising a dispersing agent and a silane carrier composition;

wherein the solvated polymer mixture is present in an amount of about 0.5% to about 20% by weight based on the weight of the untreated low density filler; and

wherein the additive package comprises about 68% to about 96% by weight of the dispersing agent and from about 4% to about 32% by weight of the silane carrier composition.

7. The composite formulation of claim 6 , wherein the additive package comprises about 85% by weight of the dispersing agent and about 15% by weight of the silane carrier composition.

8. The composite formulation of claim 3 , wherein the polymer paste comprises a low density sheet molded compound, a bulk molding compound, a pultrusion compound, or a cast polymer compound.

9. The composite formulation of claim 1 , wherein the dispersing agent is an alkyl amine-based or fluorocarbon-based polymer.

10. The composite formulation of claim 1 , wherein the untreated low density filler comprises hollow spheres.

11. A treated low density filler for use in lightweight molded components, wherein the treated low density filler comprises:

an untreated low density filler;

from about 0.5% to about 20% by weight of a solvated polymer mixture based on the weight of the untreated low density filler, wherein the solvated polymer mixture comprises a thermoplastic resin or a reactive resin and an additive package, the additive package including a dispersing agent and optionally, a silane carrier composition; and

wherein the solvated polymer mixture is combined with about 80% to about 99.5% by weight of the untreated low density filler to form the treated low density filler.

12. The treated low density filler of claim 11 , wherein the solvated polymer mixture comprises about 20% to about 97% by weight of the additive package and about 3% to about 80% by weight of the thermoplastic resin or a reactive resin.

13. The treated low density filler of claim 12 , wherein the solvated polymer mixture comprises about 60% by weight of the additive package and about 40% by weight of the thermoplastic resin or reactive resin.

14. A treated low density filler for use in lightweight molded components, wherein the treated low density filler comprises:

an untreated low density filler;

from about 0.5% to about 20% by weight of a solvated polymer mixture based on the weight of the untreated low density filler, wherein the solvated polymer mixture comprises a thermoplastic resin or a reactive resin and an additive package, the additive package including a dispersing agent and a silane carrier composition;

wherein the solvated polymer mixture is combined with about 80% to about 99.5% by weight of the untreated low density filler to form the treated low density filler; and

wherein the additive package comprises about 68% to about 96% by weight of the dispersing agent and from about 4% to about 32% by weight of the silane carrier composition.

15. The treated low density filler of claim 14 , wherein the additive package comprises about 85% by weight of the dispersing agent and about 15% by weight of the silane carrier composition.

16. The treated low density filler of claim 11 , wherein the untreated low density filler comprises hollow spheres.

17. The treated low density filler of claim 11 , wherein the dispersing agent is an alkyl amine-based or a fluorocarbon-based polymer.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 17, 2026
From: VIBRANTZ COLOR SOLUTIONS INC., F/K/A CHROMAFLO TECHNOLOGIES
To: VIBRANTZ COLOR SOLUTIONS LLC
Reel/Frame 073809/0134 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 8, 2025
From: YADAV, SANTOSH K.; RETTINGER, PAUL A.
To: CHROMAFLO TECHNOLOGIES CORP,
Reel/Frame 071063/0233 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 8, 2025
From: CHROMAFLO TECHNOLOGIES CORP
To: VIBRANTZ TECHNOLOGIES
Reel/Frame 071063/0925 →
SECURITY INTEREST Recorded May 2, 2022
From: CHROMAFLO TECHNOLOGIES CORPORATION; FERRO CORPORATION; FERRO ELECTRONIC MATERIALS INC.; PRINCE ENERGY LLC; PRINCE MINERALS LLC; PRINCE SPECIALTY PRODUCTS LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 059845/0082 →