IP Library Granted Patent US 11,695,105
Granted Patent B2
US 11,695,105 · App. 17/020,922 · Granted Jul 4, 2023

Rechargeable battery

Inventors: YoungGyu Nam (Woburn, MA); SangOh Jung (Winchester, MA); Qichao Hu (Arlington, MA); Yury Matulevich (Burlington, MA); Mackenzie King (Essex, MA); Yongkyu Son (Bedford, MA); Jeff Francois (Lynn, MA); Jacqueline Hong (Stoneham, MA); Arthur R. Nigro, Jr. (Hopkinton, MA)
Assignee: SES Holdings Pte. Ltd.
H01M4/0447H01M10/0525H01M10/281H01M10/441H01M50/211H01M50/264H01M50/291H01M50/293
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Quick Facts
Patent No.
US 11,695,105
App. No.
17/020,922
Granted
Jul 4, 2023
Kind
B2
Abstract

Battery core packs employing minimum cell-face pressure containment devices and methods are disclosed for minimizing dendrite growth and increasing cycle life of metal and metal-ion battery cells.

Claims (33)

1. A battery core pack, comprising:

a plurality of cells forming a cell stack, each cell comprising at least one anode and at least one cathode, wherein metal ions are stripped from the anode during discharge and re-plated on the anode during charge; and

a containment structure at least partially surrounding the cell stack, wherein said containment structure imparts a substantially uniform surface pressure at certain value to said cell stack;

wherein the substantially uniform surface pressure is at least about 50 psi; and

wherein said anode comprises lithium metal.

2. The battery core pack of claim 1 , wherein said cells maintain a discharge capacity of greater than 2.5 Ah over at least 100 charge/discharge cycles.

3. The battery core pack of claim 2 , comprising at least four cells with a core pack energy density of at least about 590 Wh/L at 30% SoC.

4. The battery core pack of claim 1 , wherein said containment structure comprises a housing into which the cell stack is placed, wherein the housing has openings at two ends.

5. The battery core pack of claim 4 , further comprising at least one compliant pad, wherein the at least one compliant pad is disposed between two cells, and the thickness of the at least one compliant pad is determined by the expansion extent of the cell and is optimized between the variables of allowed battery pack volume and durometer rating of the compliant pad.

6. The battery core pack of claim 5 , wherein said compliant pad comprises polyurethane sheet material with a Shore durometer of between about 40-90, and a Bashore resilience of between about 22-40%.

7. The battery core pack of claim 6 , further comprising a cooling pad disposed between two cells.

8. The battery core pack of claim 1 , wherein said containment structure comprises:

a mounting unit defining a variable space to accommodate the cell stack; and

at least one elastic member surrounding the mounting unit to impart said surface pressure to the mounting unit.

9. The battery core pack of claim 8 , wherein the mounting unit comprises:

first and second endplates opposite to each other, each endplate comprising at least a pair of sliding collars provided on each side, respectively;

guide rods inserted into the sliding collars to limit motion of the cell stack due to expansion and contraction during charge and discharge cycles to a single degree of freedom substantially perpendicular to the cell faces wherein said guide rods are configured to be slidingly received in the sliding collar at each end.

10. The battery core pack of claim 9 , comprising four said guide rods and eight said sliding collars, wherein each sliding collar is disposed on the end plates approximately adjacent a corner of the end plate and wherein said guide rods and sliding collars cooperate to permit expansion and contraction of the cell stack in a direction substantially perpendicular to the cell faces while limiting twist, skew or bending of the cell stack to maintain the substantially uniform minimum pressure across the cell faces.

11. The battery core pack of claim 10 , wherein said at least one elastic member has a spring constant of at least approximately 5.43 lb/in.

12. The battery core pack of claim 1 , wherein each cell further comprises a dielectric separator disposed between each anode and cathode pair.

13. The battery core pack of claim 12 , wherein said lithium metal anodes comprise lithium metal with a thickness in the range of 10 μm-100 μm.

14. The battery core pack of claim 13 , wherein each cell further comprises at least one of an electrolyte and redox shuttle additive impregnating one or more of the dielectric separator, anode and cathode.

15. A battery pack, comprising:

a plurality of cells forming a cell stack, each cell comprising at least one anode and at least one cathode wherein metal ions are stripped from the anode during discharge and re-plated on the anode during charge, wherein said cell stack comprises four cells and the at least one anode comprises lithium metal;

a housing containing the cell stack with a pre-loaded surface pressure of at least about 50 psi, wherein said housing has sufficient stiffness to maintain said surface pressure through plural charge and discharge cycles of said cell stack;

a cooling pad formed of a high conductivity material disposed between cells of said cell stack; and

at least two compliant pads, wherein each compliant pad is disposed between the cells, said compliant pads distributing the cell expansion pressure evenly during charging and pushing back to the cell during discharging.

16. A battery core pack, comprising:

a plurality of cells forming a cell stack, each cell comprising at least one lithium metal anode and at least one cathode, wherein lithium ions are stripped from the anode during discharge and re-plated on the anode during charge, said cells each further comprising—

a separator disposed between the at least one anode and at least one cathode, and

a non-aqueous liquid electrolyte selected to have electrochemical stability at a potential of the cathode material versus lithium; and

a containment structure at least partially surrounding the cell stack, wherein said containment structure imparts a substantially uniform surface pressure of at least about 50 psi across all cells of said cell stack.

17. The battery core pack of claim 16 , wherein said lithium metal anodes comprise lithium metal with a thickness in the range of 10 μm-100 μm and said cathode comprises a material of the general formula of LixMyOz, where M is a transition metal comprising one of Co, Mn, Ni, V, Fe, or Cr, and x, y, z are chosen to satisfy valence requirements.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 15, 2020
From: NAM, YOUNGGYU; MATULEVICH, YURY; JUNG, SANGOH; HONG, JACQUELINE; FRANCOIS, JEFF; HU, QICHAO; SON, YONGKYU; NIGRO, ARTHUR R., JR; KING, MACKENZIE
To: SOLIDENERGY SYSTEMS, LLC
Reel/Frame 053770/0109 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 15, 2020
From: SOLIDENERGY SYSTEMS, LLC
To: SES HOLDINGS PTE. LTD.
Reel/Frame 053770/0165 →
Continuity (6)
Continuation 16708059 · Dec 9, 2019
Provisional Application 62834107 · Apr 15, 2019
Provisional Application 62834101 · Apr 15, 2019
Provisional Application 62812353 · Mar 1, 2019
Provisional Application 62812322 · Mar 1, 2019
Related Publication 20200411916A1 · Dec 31, 2020