Tungsten heavy metal alloy powders and methods of forming them
In various embodiments, metallic alloy powders are formed at least in part by spray drying to form agglomerate particles and/or plasma densification to form composite particles.
1. A method of forming a powder comprising a refractory metal alloy, wherein the refractory metal alloy (i) comprises (a) one or more refractory metals selected from the group consisting of niobium, tantalum, rhenium, tungsten, and molybdenum, and (b) one or more additional metals each having a melting point lower than a melting point of each said refractory metal, and (ii) has a theoretical density corresponding to a weighted average of the densities of the one or more refractory metals and the one or more additional metals, the method comprising:
forming a powder blend by blending together powders of the one or more refractory metals and the one or more additional metals;
forming a slurry by mixing the powder blend with a liquid;
spraying the slurry and a heated gas into a drying chamber to form a plurality of agglomerate particles each comprising a mixture of the one or more refractory metals and the one or more additional metals; and
to form the powder, densifying at least a portion of the plurality of agglomerate particles by passing the at least a portion of the plurality of agglomerate particles through a plasma to thereby heat the at least a portion of the plurality of agglomerate particles to a temperature greater than a melting point of at least one of the additional metals and less than a melting point of at least one of the refractory metals,
wherein the powder comprises a plurality of substantially spherical composite particles, each composite particle comprising a plurality of grains (i) comprising at least one said refractory metal element and (ii) surrounded by a matrix comprising the one or more additional metals.
2. The method of claim 1 , wherein the liquid comprises water and/or one or more organic binders.
3. The method of claim 1 , wherein the at least a portion of the plurality of agglomerate particles is heated to a temperature greater than a melting point of each of the additional metals.
4. The method of claim 1 , wherein at least one said additional metal comprises a transition metal.
5. The method of claim 1 , wherein at least one said additional metal is selected from the group consisting of copper, cobalt, nickel, iron, manganese, silver, gold, cadmium, vanadium, palladium, zirconium, and yttrium.
6. The method of claim 1 , wherein a Hall flow rate of the powder ranges from approximately 1 s/50 g to approximately 15 s/50 g.
7. The method of claim 1 , wherein the powder has a particle-size distribution d10 between 2 microns and 8 microns, d50 between 15 microns and 25 microns, and d90 between 50 microns and 70 microns, wherein a particle-size distribution dX of Y denotes that X% of particles have a size less than Y.
8. The method of claim 1 , wherein the bulk density of the powder is approximately 45% or more of the theoretical density.
9. The method of claim 1 , wherein the bulk density of the powder is approximately 65% or less of the theoretical density.
10. The method of claim 1 , further comprising disposing at least a some of the composite particles within a powder bed of an additive manufacturing apparatus.
11. The method of claim 10 , further comprising, with the additive manufacturing apparatus:
forming a first layer of a shaped part by (i) dispersing a binder into the powder bed, and (ii) curing the binder, the first layer of the shaped part comprising composite particles bound together by cured binder;
disposing a layer of the composite particles over the first layer of the shaped part; and
forming subsequent layers of the shaped part by (i) dispersing binder over the composite particles, and (ii) curing the binder, additional composite particles being disposed over the shaped part between layers.
12. The method of claim 11 , further comprising sintering the shaped part.
13. The method of claim 12 , wherein the shaped part is sintered in a hydrogen-containing atmosphere.
14. The method of claim 12 , wherein the shaped part is sintered at a temperature ranging between approximately 1400° C. and approximately 1500° C.
15. The method of claim 11 , wherein, during formation of each layer of the shaped part, the binder is cured via application of at least one of light or heat.
16. The method of claim 1 , further comprising fabricating a wire from the powder.
17. The method of claim 16 , wherein fabricating the wire comprises:
placing the powder in a tube or a mold to form a wire preform; and
reducing a diameter of the wire preform to form the wire.
18. The method of claim 17 , wherein the tube comprises one of the elements present in the powder, and the tube forms a portion of the wire after the diameter of the wire preform is reduced.
19. The method of claim 17 , wherein the tube comprises an element not present in the powder, and the tube forms a portion of the wire after the diameter of the wire preform is reduced.
20. The method of claim 17 , wherein the tube comprises a sacrificial tube, and further comprising removing the sacrificial tube after the wire is formed.
21. The method of claim 1 , wherein a concentration, within the powder, of at least one of sodium, magnesium, phosphorus, sulfur, potassium, calcium, or antimony is less than 10 ppm.