IP Library Granted Patent US 11,118,107
Granted Patent B2
US 11,118,107 · App. 17/024,707 · Granted Sep 14, 2021

Method of using micro-particle amorphous silicate in well stimulation

Inventors: Michael John Caple (Denver, CO); John Stabenau (Denver, CO)
C09K8/92C09K8/665C09K8/80C09K8/805E21B43/267
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Quick Facts
Patent No.
US 11,118,107
App. No.
17/024,707
Granted
Sep 14, 2021
Kind
B2
Abstract

A treatment additive for hydraulic fracturing made of heated silica to create amorphous silicate with a Mohs hardness between 4.5 and 6 and a particles distribution with maximum diameter between 5 and 2600 microns that has been heated and shaped into amorphous shapes with large surface area to weight ratio and ultra-low settling velocity used to prop microfractures distal from well bore, especially in low viscosity and high temperature wells. The microparticle size and shape allow the treatment to effectively hold microfractures open, stimulate backpressure, and prevent leakoff; which has the added benefit of improving primary fracture development; refrac and frac protect productivity; and reduces the likelihood of interference between offset wells. An additional benefit is that the treatment doesn't contain crystalline silica.

Claims (41)

1. A method of using a micro-particle amorphous silicate material for hydraulic fracturing comprising:

selecting aggregate silicate;

heating said aggregate silicate above 1700 degrees Celsius;

cooling said aggregate silicate below 1700 degrees Celsius;

crushing said aggregate silicate into amorphous particles;

screening said particles until at least 97% of said particles have a maximum

diameter between 5 and 2600 microns to produce a micro-particle amorphous silicate material; and

running said micro-particle amorphous silicate material into a ground during a hydraulic fracturing treatment.

2. The method of claim 1 , wherein said method increases hydraulically fractured well production by increasing an effective fractured area.

3. The method of claim 1 , wherein said micro-particle amorphous silicate materials are screened so that less than 9% of particle size distribution is larger than 150 microns in maximum diameter; 39% or more is below 50 microns maximum diameter; and at least 17% is smaller than 5 microns in maximum diameter.

4. The method of claim 1 , wherein said micro-particle amorphous silicate materials are screened so that less than 20% of particle size distribution is larger than 150 microns in maximum diameter, 20% or more is below 50 microns in maximum diameter, and at least 5% is smaller than 5 microns in maximum diameter.

5. The method of claim 1 , wherein said micro-particle amorphous silicate materials are screened so that less than 30% of particle size distribution is larger than 150 microns in maximum diameter, 5% or more is below 50 microns in maximum diameter, and at least 1% is smaller than 20 microns in maximum diameter.

6. The method of claim 1 , wherein said micro-particle amorphous silicate material particles reduce in size during the hydraulic fracturing treatment.

7. The method of claim 6 , wherein a proportion of said micro-particle amorphous silicate material particles smaller than 100 microns in maximum diameter increase from below 60% to above 94% of total particles and particles smaller than 50 microns in maximum diameter increase from below 18% to above 49% of total particles after exposer exposure to 5,000 psi of pressure.

8. The method of claim 1 , wherein said micro-particle amorphous silicate material is run at a concentration of between 0.1 and 4 pounds per gallon range.

9. The method of claim 1 , wherein said micro-particle amorphous silicate material is used as an additive to any current completion design.

10. The method of claim 9 , wherein 50 pounds to 150,000 thousand pounds of said microparticle amorphous silicate material is run during a stage of a well completion.

11. The method of claim 9 , wherein 100 pounds to 20,000 thousand pounds of said microparticle amorphous silicate material is run before a remaining treatment with other proppant.

12. The method of claim 9 , wherein fifty-pound bags of said micro-particle amorphous silicate material is run intermittently throughout a remaining treatment.

13. The method of claim 9 , wherein one to 10,000 pounds of said micro-particle amorphous silicate material is run intermittently throughout a remaining treatment.

14. The method of claim 1 , wherein said aggregate silicate is selected from a material with a Mohs hardness of between 4.5 and 6.

15. The method of claim 14 , wherein said micro-particle amorphous silicate material is 60-70% less abrasive than quartz sand particles on completion pipe perforations.

16. The method of claim 1 , wherein said method limits and prevents fluid loss and pressure dependent leakoff.

17. The method of claim 1 , wherein said method increases hydraulic refracturing well production.

18. The method of claim 1 , wherein said method reduces interference between off-set wells.

19. A method of using a micro-particle amorphous silicate material for hydraulic fracturing comprising:

selecting aggregate silicate;

heating said aggregate silicate above 1700 degrees Celsius;

cooling said aggregate silicate below 1700 degrees Celsius;

crushing said aggregate silicate into amorphous particles;

screening said particles until at least 51% of said particles have a maximum

diameter between 40 and_1,000 microns to produce a micro-particle amorphous silicate material; and

running said micro-particle amorphous silicate material into a ground during a hydraulic fracturing treatment.

20. A method of using a micro-particle amorphous silicate material for hydraulic fracturing comprising:

selecting aggregate silicate;

heating said aggregate silicate above 1700 degrees Celsius;

cooling said aggregate silicate below 1700 degrees Celsius;

crushing said aggregate silicate into amorphous particles;

screening said particles until at least 75% of said particles have a maximum

diameter between 100 and 850 microns to produce a micro-particle amorphous silicate material; and

running said micro-particle amorphous silicate material into a ground during a hydraulic fracturing treatment.

Assignments (5)
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 067211/0001 Recorded Dec 23, 2025
From: UBS AG, STAMFORD BRANCH (AS SUCCESSOR IN INTEREST TO CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH)
To: POTTERS INDUSTRIES, LLC
Reel/Frame 074050/0556 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE DOCUMENT ATTACHED TO THE ORIGINAL FILING PREVIOUSLY RECORDED AT REEL: 67211 FRAME: 1. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 9, 2024
From: POTTERS INDUSTRIES, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 067370/0643 →
SECURITY INTEREST Recorded Apr 24, 2024
From: POTTERS INDUSTRIES, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 067211/0001 →
INTELLECTUAL PROPERTY ASSIGNMENT AGREEMENT Recorded Apr 18, 2024
From: UNIVERSAL COMPLETION MATERIAL LLC; OIL FIELD PACKAGING LLC
To: POTTERS INDUSTRIES, LLC
Reel/Frame 067149/0686 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2020
From: CAPLE, MICHAEL JOHN; STABENAU, JOHN
To: OIL FIELD PACKAGING LLC
Reel/Frame 053879/0790 →