Thermally conductive thermoplastic compositions with good dielectric property and the shaped article therefore
A polymer composition includes: from about 20 wt. % to about 80 wt. % of a polymer base resin; from about 10 wt. % to about 60 wt. % of a thermally conductive filler; and from about 5 wt. % to about 60 wt. % of a dielectric ceramic filler having a Dk of at least 20 when measured at 1.1 GHz or greater. The polymer composition exhibits a dielectric constant greater than 3.0 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150. The polymer composition exhibits a dissipation factor of less than 0.002 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150.
1. A polymer composition comprising:
from about 20 wt. % to about 80 wt. % of a polymer base resin comprising a polyarylene ether, a polystyrene, a polypropylene, or a combination thereof;
from about 10 wt. % to about 60 wt. % of a thermally conductive filler;
from about 5 wt. % to about 30 wt. % of an impact modifier, wherein the impact modifier comprises a styrene-based copolymer; and
from about 5 wt. % to about 60 wt. % of a dielectric ceramic filler,
wherein the polymer composition exhibits a dielectric constant greater than 3.0 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150,
wherein the polymer composition exhibits a dissipation factor of less than 0.002 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150, and
wherein the combined weight percent value of all components does not exceed about 100 wt. %, and all weight percent values are based on the total weight of the composition.
2. The polymer composition of claim 1 , wherein the dielectric ceramic filler has a Dk of at least 20 when measured at 1.1 GHz or greater.
3. The polymer composition of claim 1 , wherein the polymer composition exhibits a dissipation factor at 1.1 GHz that is less than that of a substantially similar polymer composition in the absence a thermally conductive filler when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150.
4. The polymer composition of claim 1 , wherein the polymer composition exhibits a dissipation factor that is less than 0.002 at 1.9 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150.
5. The polymer composition of claim 1 , wherein the thermally conductive filler comprises zinc sulfide, calcium oxide, magnesium oxide, zinc oxide, titanium dioxide, tin dioxide, chromium oxide, calcium carbonate, mica, barium oxide, barium sulfate, calcium sulfate, wollastonite, zirconium oxide, silicon oxide, glass beads, glass fiber, magnesium aluminate, dolomite, coated graphite, magnesium hydroxide, talc, boehmite, diaspore, gibbsite, -clay, aluminum nitride, aluminum carbide, aluminum oxide, boron nitride, aluminum oxynitride, magnesium silicon nitride, silicon carbide, silicon nitride, tungsten oxide, aluminum phosphide-, beryllium oxide, boron-phosphide-, cadmium sulfide, gallium nitride, zinc silicate, tungsten oxide, or a combination thereof.
6. The polymer composition of claim 1 , wherein the thermally conductive filler comprises boron nitride.
7. The polymer composition of claim 1 , wherein the thermally conductive filler comprises magnesium hydroxide, boron nitride, or a combination thereof.
8. The polymer composition of claim 1 , wherein the thermally conductive filler comprises talc.
9. The composition of claim 1 , wherein the thermally conductive filler has a thermal conductivity of at least about 5 W/m*K.
10. The polymer composition of claim 1 , wherein the dielectric ceramic filler comprises barium titanate, titanium dioxide, boron nitride, silicon carbide, silicon nitride, zinc oxide, or a combination thereof.
11. The composition of claim 1 , wherein the dielectric ceramic filler comprises inorganic oxides, silicates, or a combination thereof.
12. The polymer composition of claim 1 , wherein the impact modifier comprises a styrene-based copolymer selected from the group consisting of styrene ethylene butylene styrene copolymer (SEBS), styrene butadiene styrene (SBS), styrene ethylene propylene styrene (SEPS), and combinations thereof.
13. The polymer composition of claim 1 , wherein the composition further comprises an additive selected from a pigment, a dye, a filler, a plasticizer, a fiber, a flame retardant, an antioxidant, a lubricant, wood, glass, metal, an ultraviolet agent, an anti-static agent, an anti-microbial agent, or a combination thereof.
14. An article comprising the polymer composition of claim 1 .
15. The article of claim 14 , wherein the article is a component of an electronic device.
16. A method of forming a polymer composition comprising:
combining:
from about 20 wt. % to about 80 wt. % of a polymer base resin comprising a polyarylene ether, a polystyrene, a polypropylene, or a combination thereof;
from about 10 wt. % to about 60 wt. % of a thermally conductive filler;
from about 5 wt. % to about 30 wt. % of an impact modifier, wherein the impact modifier comprises a styrene-based copolymer; and
from about 5 wt. % to about 60 wt. % of a dielectric ceramic filler,
wherein the polymer composition exhibits a dielectric constant greater than 3.5 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150,
wherein the polymer composition exhibits a dissipation factor of less than 0.001 at 1.1 GHz when tested using a split post dielectric resonator and network analyzer on a sample size of 120 mm by 120 mm and 6 mm thickness according to ASTM D150, and
wherein the combined weight percent value of all components does not exceed about 100 wt. %, and all weight percent values are based on the total weight of the composition.