IP Library Granted Patent US 11,060,036
Granted Patent B2
US 11,060,036 · App. 17/040,863 · Granted Jul 13, 2021

Process for the conversion of oxygenates to C5+ hydrocarbons boiling in the gasoline boiling range

Inventor: Martin Dan Palis Sørensen (Taastrup, DK)
Assignee: Haldor Topsoe A/S
C10G3/60C10G3/49C10G2300/4006C10G2300/4025C10G2300/708C10G2400/02
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Quick Facts
Patent No.
US 11,060,036
App. No.
17/040,863
Granted
Jul 13, 2021
Kind
B2
Abstract

Process for the conversion of oxygenates to C 5+ hydrocarbons boiling in the gasoline boiling range, comprising the steps of continuously a) providing one or more feed streams of one or more oxygenate compounds; b) heating the one or more feed streams to an inlet temperature of one or more downstream conversion reactors; c) introducing the one or more heated feed stream into inlet of the one or more conversion reactors; d) converting in the one or more conversion reactors the one or more heated feed stream in presence of catalyst to a converted oxygenate product comprising C 5+ hydrocarbons; e) withdrawing from the one or more conversion reactors the converted oxygenate product; f) determining at outlet of the one or more conversion reactors amount of the one or more unconverted oxygenate compounds in the withdrawn converted oxygenate product; g) separating the converted oxygenate product into a C 4− hydrocarbon fraction, a fraction with the C 5+ hydrocarbons boiling in the gasoline boiling range and a fraction comprising water and the one or more unconverted oxygenate compounds, wherein the inlet temperature of the one or more feed streams in step b is continuously adjusted to maintain a constant amount of the one or more unconverted oxygenate compounds as determined in step f.

Claims (17)

1. Process for the conversion of oxygenates to C 5+ hydrocarbons boiling in the gasoline boiling range, comprising the steps of continuously

a) providing one or more feed streams of one or more oxygenate compounds;

b) heating the one or more feed streams to an inlet temperature of one or more downstream conversion reactors;

c) introducing the one or more heated feed stream into inlet of the one or more conversion reactors;

d) converting in the one or more conversion reactors the one or more heated feed stream in presence of catalyst to a converted oxygenate product comprising C 5+ hydrocarbons;

e) withdrawing from the one or more conversion reactors the converted oxygenate product;

f) determining at outlet of the one or more conversion reactors amount of the one or more unconverted oxygenate compounds in the withdrawn converted oxygenate product; and

g) separating the converted oxygenate product into a C 4− hydrocarbon fraction, a fraction with the C 5+ hydrocarbons boiling in the gasoline boiling range and a fraction comprising water and the one or more unconverted oxygenate compounds, wherein the inlet temperature of the one or more feed streams in step b is continuously adjusted to maintain a constant amount of the one or more unconverted oxygenate compounds as determined in step f, and to maintain a constant level of conversion of the one or more oxygenate compounds of between 95% to 99.9%.

2. The process of claim 1 , wherein the inlet temperature of the one or more feed streams in step b is continuously increased to maintain a conversion of the one or more oxygenate compounds at a constant amount.

3. The process of claim 1 , wherein the inlet temperature of the one or more feed streams in step b is continuously decreased to maintain a conversion of the one or more oxygenate compounds at a constant amount.

4. The process of claim 1 , wherein the inlet temperature of the one or more feed streams in step b is continuously increased between start of run and end of run of the conversion of the one or more heated feed streams in step d.

5. The process of claim 1 , wherein the inlet temperature of the one or more feed streams is adjusted to between 220 and 370° C. at start of run of the conversion in step d.

6. The process of claim 1 , wherein the inlet temperature of the product withdrawn from the one or more conversion reactors in step e in feed effluent heat exchanger(s) and/or by means of trim heater(s).

7. The process of claim 1 , wherein the one or more unconverted oxygenates compounds are recovered from the fraction comprising water and recirculated back to step a.

8. The process of claim 1 , wherein the one or more conversion reactors are operated in parallel or in series.

9. The process of claim 1 , wherein the one or more oxygenate compounds comprise methanol or mixtures of dimethyl ether and methanol.

10. The process of claim 1 , wherein the one or more oxygenate compounds comprise dimethyl ether, ethanol and propanol or mixtures thereof.

Assignments (2)
CHANGE OF NAME Recorded Oct 3, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065108/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2021
From: SORENSEN, MARTIN DAN PALIS
To: HALDOR TOPSOE A/S
Reel/Frame 055862/0788 →
Priority Claims (1)
DK PA 2018 00214 · May 15, 2018 · national
Continuity (1)
Related Publication 20210002557A1 · Jan 7, 2021
Cited By (1)
US 12,668,747