Bicomponent composition
The instant disclosure generally relates to a bicomponent composition for coloring mammalian or synthetic keratin fibers, the bicomponent composition comprising first, second, components. The first component includes an organic polymer, the second component includes a pretreatment base compound. One or more of the components includes pigment microparticles. The bicomponent composition combines upon application to treated material such as hair, forms a solid coating thereon and has a substantially long color fastness following development (setting). Methods of using such compositions are also described herein.
1. A bicomponent composition for coloring keratin material comprising a first component of at least one organic copolymer with functional groups, at least one pigment and a second component comprising a base compound having functional groups capable of forming dipolar or electrostatic interactions with the organic copolymer,
wherein:
the organic copolymer comprises repeating units of at least one hydrophobic olefinic carboxylate ester monomer and at least one hydrophilic olefinic monomer;
the hydrophobic olefinic carboxylate ester monomer comprises an ester of (meth)acrylic acid or crotonic acid, or a combination thereof and a linear or branched alkanol of 1 to 30 carbons or a combination thereof;
the hydrophilic olefinic monomer comprises a hydroxy alkyl ester of an olefinic carboxylic acid and a linear or branched alkyl diol of 2 to 24 carbons, or an aminoalkyl ester of an olefinic carboxylic acid and a linear or branched amino alkyl alcohol of 2 to 24 carbons, or an olefinic acid, or a combination of any two or more of the hydroxyl alkyl ester, the amino alkyl ester and the olefinic acid; and
the olefinic acid comprises (meth)acrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid or gluconic acid or a combination of any two or more of the olefinic acids; and,
the base compound comprises an aminosilane, aminosiloxane, or mixture thereof.
2. A bicomponent composition of claim 1 wherein the first and second components are separate and one or both of the components further comprises a medium.
3. A bicomponent composition of claim 1 wherein the weight average molecular weight of the base compound is in a range of about 150 Da to 2 kDa.
4. A bicomponent composition of claim 1 wherein the organic copolymer further comprises at least one olefin monomer, wherein:
the olefin monomer has the formula
H 2 C═CHR
wherein R is selected from linear or branched alkyl of one to six carbons, unsubstituted phenyl or phenyl substituted by a linear or branched alkyl of 1 to six carbons, carboxylic acid, methyl or ethyl carboxylate, carboxamide or hydroxyl.
5. A bicomponent composition of claim 4 wherein the olefinic acid is (meth)acrylic acid or crotonic acid.
6. A bicomponent composition of claim 5 wherein the olefinic acid is (meth)acrylic acid.
7. A bicomponent composition according to claim 1 wherein the olefinic acid is (meth)acrylic acid or crotonic acid.
8. A bicomponent composition of claim 7 wherein the olefinic acid is (meth)acrylic acid.
9. A bicomponent composition of claim 4 wherein the olefin monomer is styrene or carboxystrene methyl or ethyl ester.
10. A bicomponent composition of claim 4 wherein the olefin monomer is hydroxystyene, carboxystyrene or carboxamidostyrene.
11. A bicomponent composition according to claim 4 wherein the weight percent of the base compound is 0.1-5 wt. % relative to the total composition.
12. A bicomponent composition of claim 1 wherein the weight percent of the base compound is 0.1-5 wt. % relative to the total composition.
13. A bicomponent composition of claim 1 wherein
the organic polymer has an acid value of from about zero to about 250;
the organic polymer has a glass transition temperature of from about −120° C. to about −40° C.;
the organic polymer has a weight average molecular weight in the range of about 2 KDa to about 10 MDa; and
the composition has a pH of from about 3 to about 12.
14. A bicomponent composition of claim 4 wherein
the organic polymer has an acid value of from about zero to about 250;
the organic polymer has a glass transition temperature of from about −120° C. to about −40° C.;
the organic polymer has a weight average molecular weight in the range of about 2 KDa to about 10 MDa; and
the composition has a pH of from about 3 to about 12.
15. A kit comprising separate compartments in which the first component and the second component of claim 1 are separately contained, wherein the first component, the second component, or both comprise pigment microparticles.
16. A method for coloring keratin material comprising applying first to the keratin material the second component of claim 15 to form a pretreated keratin material, then applying the first component of claim 15 to the pretreated keratin material and drying the coated keratin material with optional heat to form a colored coating on the keratin material.
17. A method of claim 16 wherein the first and second components are applied as foams to portions of the keratin material.
18. A kit comprising separate compartments in which the first component and the second component of claim 4 are separately contained, wherein the first component, the second component, or both comprise pigment microparticles.
19. A method for coloring keratin material comprising applying first to the keratin material the second component of claim 18 to form a pretreated keratin material, then applying the first component of claim 18 to the pretreated keratin material and drying the coated keratin material with optional heat to form a colored coating on the keratin material.
20. A method of claim 19 wherein the first and second components are applied as foams to portions of the keratin material.