Polypropylene composition
New polypropylene composition, which combines low sealing initiation temperature (SIT), high hot-tack and good optical properties, like low haze, the use of such polypropylene composition and articles made therefrom.
1. A polypropylene composition comprising:
(A) at least 50.0 wt % of a propylene terpolymer comprising:
(i) ethylene-derived comonomer units in an amount of from 0.5 to 1.5 wt % and
(ii) comonomer units derived from a C4 to C10 α-olefin in an amount of from 5.5 to 15.0 wt %,
whereby the terpolymer has been visbroken with a visbreaking ratio (VR)
as defined by equation (I)
VR=MFR final /MFR start >1.5
wherein
“MFR final ” is the MFR 2 (230° C./2.16 kg) of the propylene terpolymer copolymer after visbreaking and
“MFR start ” is the MFR 2 (230° C./2.16 kg) of the propylene terpolymer copolymer before visbreaking,
whereby the MFR final (230° C., 2.16 kg, ISO1133) is in a range of 1.5 to 15.0 g/10 min and
(B) optionally one or more additives in a total amount of from 0.0 up to 5.0 wt %, based on the composition, the one or more additives comprising one or more slip agents, one or more anti-block agents, one or more UV stabilizers, one or more alpha and/or beta nucleating agents, one or more antistatic agents, or one or more antioxidants;
wherein the polypropylene composition has a hot-tack force determined on 50 μm cast film in the range of from 2.0 to 7.0 N.
2. The polypropylene composition according to claim 1 , wherein the comonomer (ii) is selected from 1-butene, 1-hexene or 1-octene.
3. The polypropylene composition according to claim 2 , wherein the comonomer (ii) is 1-butene.
4. The polypropylene composition according to claim 1 , wherein “MFR start ” (230° C./2.16 kg) of the propylene terpolymer copolymer before visbreaking is in the range of 0.5 to lower than 10.0 g/10 min.
5. The polypropylene composition according to claim 1 , wherein the visbroken propylene terpolymer has a xylene cold soluble (XCS) content in the range of 3.0 to below 20.0 wt %.
6. The polypropylene composition according to claim 1 , wherein the difference between the melting temperature Tm of the visbroken propylene terpolymer and the sealing initiation temperature SIT of a cast film of 50 μm thickness is;
Tm −SIT>24° C.
7. The polypropylene composition of claim 1 , being prepared by, the process comprising the steps of:
(i) preparing the propylene terpolymer by polymerizing propylene, ethylene and a C4 to C10 α-olefin in the presence of a Ziegler-Natta catalyst,
(ii) subsequent visbreaking the propylene terpolymer and
(iii) optionally mixing said visbroken propylene terpolymer (A) with one or more additives.
8. A method comprising producing articles with a polypropylene composition according to claim 1 .
9. The method according to claim 8 , wherein the articles are sterilizable articles.
10. An article comprising the polypropylene composition according to claim 1 .
11. The article according to claim 10 , wherein the article is an unoriented film comprising more than 90% of the composition according to claim 1 , wherein the film is a cast film or a blown film.
12. The article according to claim 11 , wherein the film is a cast film, said cast film having
(i) a sealing initiation temperature in the range of from 90° C. to 112° C. determined on 50 μm cast film and
(ii) a hot-tack force determined on 50 μm cast film in the range of from 2.0 to 7.0 N.
13. The article according to claim 11 , wherein
the film has a haze determined according to ASTM D 1003-00 measured on a 50 μm cast film of below 3.0% and has a haze determined according to ASTM D 1003-00 measured on a 50 μm cast film after sterilization (steam sterilization at 121° C. for 30 min) of below 12.0%.
14. The article according to claim 11 , wherein the film has an overall performance defined by:
Relation ( I )=Tensile modulus(MD)×Hot-tack/Haze b.s.,
whereby relation (I) is at least 1000 MPa*N/%.
15. The article according to claim 10 ,
comprising a sealing layer in a multi-layer film.