IP Library Granted Patent US 12,239,936
Granted Patent B2
US 12,239,936 · App. 17/048,504 · Granted Mar 4, 2025

Hydration of gas streams

Inventors: Kenton Robert Heidel (Squamish, CA); David St. Angelo (Squamish, CA); Jane Anne Ritchie (Calgary, CA)
Assignee: Carbon Engineering ULC
B01D53/1475B01D53/78B01D2251/304B01D2251/306B01D2251/606B01D2252/103B01D2257/504B01D2258/0283
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,239,936
App. No.
17/048,504
Granted
Mar 4, 2025
Kind
B2
Abstract

Techniques for humidifying a gas stream using a hydration system includes directing a gas stream through a contact zone of at least one hydration system; directing a hydration solution into the contact zone using a pump; contacting the gas stream with the hydration solution; evaporating water from the hydration solution into the gas stream to form a humidified gas stream, transporting the humidified gas stream out of the at least one hydration system; and collecting the remaining hydration solution in a hydration solution collection basin below the contact zone. The at least one hydration system is fluidly coupled to at least one downstream process and the humidified gas stream from the at least one hydration system is transported as a feed stream to the at least one downstream process.

Claims (60)

1. An apparatus for humidifying a gas stream, comprising:

inlet ports arranged to receive at least one feed stream into a hydration housing vessel;

a gas inlet section configured to receive at least one gas feed stream into the hydration housing vessel, the inlet ports and the gas inlet section coupled to the hydration housing vessel;

a hydration solution having a capacity for hydrating the at least one gas feed stream;

a contact zone coupled to the hydration housing vessel and configured for gas-liquid contact;

a solution distribution system coupled to the hydration housing vessel and comprising a pump configured for flowing the hydration solution over at least a portion of the contact zone;

a hydration solution collection basin coupled to the hydration housing vessel and configured to receive the hydration solution leaving the contact zone;

a drift elimination section coupled to the hydration housing vessel and configured to prevent hydration solution from leaving with a humidified gas stream;

at least one outlet coupled to the hydration housing vessel and configured to dispense the humidified gas stream;

at least one outlet port coupled to the hydration housing vessel and configured to discharge at least a portion of the hydration solution;

a CO 2 capture packing section;

a capture solution drift elimination section; and

an open plenum at least partially delimited by the capture solution drift elimination section, the at least one gas feed stream configured to flow sequentially through the gas inlet section, the contact zone, the drift elimination section, the CO 2 capture packing section, the capture solution drift elimination section and into the open plenum.

2. The apparatus of claim 1 , wherein the contact zone comprises packing material comprising at least one of loose fill or structured fill.

3. The apparatus of claim 1 , wherein the apparatus is coupled to a downstream process, and at least a portion of a humidified gas stream exiting the apparatus is fluidly connected to the downstream process.

4. The apparatus of claim 3 , wherein the drift elimination section is configured to isolate the hydration solution from the downstream process, and comprises one or more of drift eliminators, inlet louvers, demisters, or a combination thereof.

5. The apparatus of claim 3 , wherein the downstream process comprises at least one of a fan or blower configured to move at least a portion of the humidified gas stream through the apparatus, and into the downstream process.

6. The apparatus of claim 5 , wherein the fan or blower comprises a fan cowling defining a fan cowling outlet, the fan cowling outlet positioned vertically above the solution distribution system.

7. The apparatus of claim 3 , wherein the downstream process comprises a process solution, a process solution evaporator unit, and a condenser and collection unit configured to evaporate and collect water from at least a portion of the process solution.

8. The apparatus of claim 3 , wherein one or more of the apparatus and the downstream process are fluidly connected to a water treatment and filtration system.

9. The apparatus of claim 3 , comprising a temperature control system configured to control the temperature of the hydration solution, wherein the temperature control system comprises at least one of a heat exchanger and a gas analysis unit.

10. The apparatus of claim 3 , comprising:

a control system coupled to the apparatus and the downstream process; and

at least one process solution level measurement device coupled to the apparatus and the downstream process, the control system being configured to perform operations comprising:

receiving an output from the at least one process solution level measurement device; and

controlling, based on the received output, a water content of the downstream process.

11. The apparatus of claim 1 , wherein the hydration solution collection basin comprises:

at least one or more solid collection zones; and

a solids transfer system coupled to the hydration solution collection basin and configured to remove solid material from the at least one or more solid collection zones.

12. The apparatus of claim 11 , wherein the solids transfer system comprises at least one of an auger, screw conveyor, progressive cavity pump, screw pump, high density solids pump, or reciprocating pump.

13. The apparatus of claim 11 , wherein the hydration solution collection basin comprises an inclined bottom basin area and a liquid level, wherein the inclined bottom basin area is sloped down towards the at least one or more solid collection zones.

14. The apparatus of claim 1 , wherein the drift elimination section further comprises:

a pre-fabricated mechanical frame; and

a drift eliminator material coupled to the pre-fabricated mechanical frame.

15. The apparatus of claim 14 , comprising a flexible sealant pressed against the drift eliminator material configured for sealing the hydration housing vessel and the drift eliminator material.

16. The apparatus of claim 1 , wherein the hydration solution comprises non-potable water, off-spec water, brackish water, saline water, sea water, waste water, gray water, rain water, storm water, non-process water, or a combination thereof.

17. The apparatus of claim 1 , comprising a CO 2 capture solution collection basin configured to receive CO 2 capture solution from the CO 2 capture packing section, the hydration solution collection basin being positioned adjacent to the CO 2 capture solution collection basin and fluidly separated therefrom;

the hydration solution collection basin being fluidly coupled to the pump; and

the CO 2 capture solution collection basin being fluidly coupled to a capture solution pump.

18. The apparatus of claim 17 , wherein:

the pump is configured to flow the hydration solution from the hydration solution collection basin to the contact zone; and

the capture solution pump is configured to flow the CO 2 capture solution from the CO 2 capture solution collection basin to the CO 2 capture packing section.

19. The apparatus of claim 17 , comprising:

a hydration solution makeup in fluid communication with the hydration solution collection basin; and

a CO 2 capture solution makeup in fluid communication with the CO 2 capture solution collection basin.

20. The apparatus of claim 17 , wherein the CO 2 capture solution comprises a hydroxide or an amine.

21. The apparatus of claim 17 , wherein the CO 2 capture solution collection basin is at least partially positioned beneath the CO 2 capture packing section.

22. The apparatus of claim 21 , wherein the CO 2 capture solution collection basin is positioned beneath the open plenum.

23. The apparatus of claim 1 , comprising a dual-cell, cross-flow gas-liquid contactor, the gas-liquid contactor comprising the open plenum and an induced-draft fan disposed above the open plenum.

24. The apparatus of claim 23 , wherein:

the contact zone comprises a first contact zone and a second contact zone;

a first hydration solution collection basin is positioned below the first contact zone; and

a second hydration solution collection basin is positioned below the second contact zone.

25. The apparatus of claim 1 , wherein the CO 2 capture packing section is configured for capturing CO 2 from air.

26. The apparatus of claim 1 , wherein the CO 2 capture packing is adjacent to the hydration housing vessel and downstream of the hydration housing vessel relative to a direction of flow of the at least one gas feed stream.

27. The apparatus of claim 1 , wherein the solution distribution system is positioned above the hydration housing vessel.

28. The apparatus of claim 1 , comprising a CO 2 capture solution distribution unit positioned above the CO 2 capture packing section.

29. The apparatus of claim 28 , wherein the CO 2 capture solution distribution unit abuts a top portion of the CO 2 capture packing section.

30. The apparatus of claim 1 , comprising at least one seal positioned between the capture solution drift elimination section and a structural housing of the apparatus.

31. The apparatus of claim 30 , wherein the at least one seal abuts the capture solution drift elimination section and is positioned downstream thereof relative to a direction of flow of the at least one gas feed stream.

Assignments (2)
CHANGE OF NAME Recorded Feb 28, 2024
From: CARBON ENGINEERING LTD.
To: CARBON ENGINEERING ULC
Reel/Frame 066593/0551 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 20, 2021
From: HEIDEL, KENTON ROBERT; RITCHIE, JANE ANNE; ANGELO, DAVID ST.
To: CARBON ENGINEERING LTD.
Reel/Frame 054962/0225 →
Continuity (2)
Provisional Application 62658679 · Apr 17, 2018
Related Publication 20210101107A1 · Apr 8, 2021
References Cited (140)
US 3363885A · Meek · 1968 [cited by examiner]
US 3707277A · Phelps · 1972 [cited by examiner]
US 3748832A · Furlong · 1973 [cited by applicant]
US 4000264A · Nagano et al. · 1976 [cited by applicant]
US 4031180A · Bohanon · 1977 [cited by applicant]
US 4049399A · Teller · 1977 [cited by applicant]
US 4183901A · Ilardi et al. · 1980 [cited by applicant]
US 4251494A · Say · 1981 [cited by applicant]
US 4344650A · Pinsky et al. · 1982 [cited by applicant]
US 4401635A · Frint · 1983 [cited by applicant]
US 4632760A · Hanson et al. · 1986 [cited by applicant]
US 4994210A · Lucero · 1991 [cited by applicant]
US 5283054A · Copenhafer et al. · 1994 [cited by applicant]
US 5316744A · Haehn · 1994 [cited by examiner]
US 5364604A · Spink et al. · 1994 [cited by applicant]
US 5484471A · Schwab · 1996 [cited by examiner]
US 5582683A · Bonsu et al. · 1996 [cited by applicant]
US 5679131A · Obushenko · 1997 [cited by applicant]
US 5695548A · Truta · 1997 [cited by applicant]
US 5879434A · Kiss · 1999 [cited by applicant]
US 6070860A · Kinney, Jr. · 2000 [cited by examiner]
US 6409157B1 · Lundin · 2002 [cited by applicant]
US 6428759B1 · Smith et al. · 2002 [cited by applicant]
US 6524843B1 · Blais et al. · 2003 [cited by applicant]
US 6582498B1 · Sass et al. · 2003 [cited by applicant]
US 6840987B1 · Gonzalez et al. · 2005 [cited by applicant]
US 7214290B2 · Duesel, Jr. et al. · 2007 [cited by applicant]
US 7297182B2 · Ray et al. · 2007 [cited by applicant]
US 7314847B1 · Siriwardare · 2008 [cited by applicant]
US 7318857B2 · Ray et al. · 2008 [cited by applicant]
US 7329298B1 · Hasinski · 2008 [cited by applicant]
US 7731781B2 · Berry et al. · 2010 [cited by applicant]
US 7833010B2 · Baker et al. · 2010 [cited by applicant]
US 7906089B2 · Gosh et al. · 2011 [cited by applicant]
US 8119091B2 · Keith et al. · 2012 [cited by applicant]
US 8273158B2 · Jarrier · 2012 [cited by applicant]
US 8574354B2 · Keith et al. · 2013 [cited by applicant]
US 8602397B2 · Daley · 2013 [cited by examiner]
US 8966924B2 · Pichai · 2015 [cited by examiner]
US 9095813B2 · Keith et al. · 2015 [cited by applicant]
US 9550142B2 · Roestenberg et al. · 2017 [cited by applicant]
US 9751039B2 · Gebald et al. · 2017 [cited by applicant]
US 10421039B2 · Heidel et al. · 2019 [cited by applicant]
US 20010022952A1 · Rau et al. · 2001 [cited by applicant]
US 20030205039A1 · Terlson · 2003 [cited by applicant]
US 20040094037A1 · Maleeny et al. · 2004 [cited by applicant]
US 20060000196A1 · Beier et al. · 2006 [cited by applicant]
US 20060051274A1 · Wright et al. · 2006 [cited by applicant]
US 20060186562A1 · Wright et al. · 2006 [cited by applicant]
US 20070157806A1 · Cash · 2007 [cited by applicant]
US 20080011161A1 · Finkenrath et al. · 2008 [cited by applicant]
US 20080031801A1 · Lackner et al. · 2008 [cited by applicant]
US 20090053040A1 · Chillar · 2009 [cited by applicant]
US 20100034724A1 · Keith et al. · 2010 [cited by applicant]
US 20100064890A1 · Keith et al. · 2010 [cited by applicant]
US 20110079504A1 · Govindan et al. · 2011 [cited by applicant]
US 20110092355A1 · Iijima · 2011 [cited by examiner]
US 20110239862A1 · Davydov · 2011 [cited by examiner]
US 20120195816A1 · Dube · 2012 [cited by examiner]
US 20130095016A1 · Miyagawa et al. · 2013 [cited by applicant]
US 20130204066A1 · Chretien · 2013 [cited by examiner]
US 20140123621A1 · Driessens · 2014 [cited by examiner]
US 20140284002A1 · Sparrow · 2014 [cited by applicant]
US 20150330710A1 · Curtis · 2015 [cited by examiner]
US 20150336044A1 · Keith et al. · 2015 [cited by applicant]
US 20160096743A1 · Duesel, Jr. · 2016 [cited by examiner]
US 20160303513A1 · Bijl et al. · 2016 [cited by applicant]
US 20160362307A1 · Shiner · 2016 [cited by examiner]
US 20170203249A1 · Gebald et al. · 2017 [cited by applicant]
US 20170246588A1 · Roestenberg et al. · 2017 [cited by applicant]
US 20170354925A1 · Heidel · 2017 [cited by applicant]
US 20190336909A1 · Keith · 2019 [cited by applicant]
US 20190344217A1 · Heidel · 2019 [cited by applicant]
US 20190374898A1 · Panaccione · 2019 [cited by examiner]
CA 2734786 · 2017 [cited by applicant]
CN 101091864 · 2007 [cited by applicant]
CN 101128248A · 2008 [cited by applicant]
CN 102202766A · 2011 [cited by applicant]
CN 106621705A · 2017 [cited by applicant]
EP 2782657B1 · 2016 [cited by applicant]
EP 2321034 · 2018 [cited by applicant]
IN 2007 · 2007 [cited by applicant]
JP 2014018776A · 2014 [cited by applicant]
KR 1020130137473A · 2013 [cited by applicant]
MX 299407 · 2012 [cited by applicant]
WO WO2006009600 · 2006 [cited by applicant]
WO WO2006034339 · 2006 [cited by applicant]
WO WO2006084008 · 2006 [cited by applicant]
WO WO2007075399 · 2007 [cited by applicant]
WO WO200842919 · 2008 [cited by applicant]
WO WO2010022339 · 2010 [cited by applicant]
WO WO2017009241 · 2017 [cited by applicant]
WO WO2017148782 · 2017 [cited by applicant]
Gulf Coop Council Examination Report in GCC Appln. No. 201937396, dated Nov. 25, 2021, 3 pages. [cited by applicant]
Communication pursuant to Article 94(3) EPC in European Patent Application No. 19788037.0, dated Jan. 2, 2024, 5 pages. [cited by applicant]
Baciocchi et al., “Process design and energy requirement for the capture of carbon dioxide from air,” Chem. Eng. Proc., 2006, 45:1047-1058. [cited by applicant]
Canadell et al., “Contributions to accelerating atmospheric CO2 growth from economic activity, carbon intensity, and efficiency of natural sinks,” Proc. Natl. Acad. Sci. USA, 2007, 104(47):18866-18870. [cited by applicant]
Chen and van Heiningen, “Kinetics of the direct causticizing reaction between sodium carbonate and titanium dioxide or sodium tri-titanate,” J. Pulp Paper Sci., 2006, 32(4):245-251. [cited by applicant]
Chinese Decision on Rejection, Application No. 200980137997.2, issued Mar. 12, 2014, 22 pages. [cited by applicant]
Chinese First Office Action, Application No. 200980137997.2, issued Jan. 28, 2013, 13 pages. [cited by applicant]
Chinese First Office Action, Application No. 201610825390.5, issued Nov. 1, 2018, 13 pages. [cited by applicant]
Chinese Second Office Action, Application No. 200980137997.2, issued Aug. 26, 2013, 26 pages. [cited by applicant]
Covey, “Development of the direct alkali recovery system and potential application,” Pulp Pap. Canada, 1982, 83(12):T350-T354. [cited by applicant]
European Office Action, Application No. 09808878.4, dated Dec. 20, 2012, 5 pages. [cited by applicant]
European Search Report, Application No. 09767848.6, dated Feb. 17, 2012, 7 pages. [cited by applicant]
Hoddenbagh et al., “Borate causticizing: a cost effective technology,” Pulp Pap. Canada, 2002, 103(11):T283-T289. [cited by applicant]
International Preliminary Report on Patentability and Written Opinion of the International Searching Authority from International Application No. PCT/US2009/047999, mailed Dec. 21, 2010, 6 pages. [cited by applicant]
International Preliminary Report on Patentability and Written Opinion of the International Searching Authority from International Application No. PCT/US2009/054626, mailed Feb. 22, 2011, 6 pages. [cited by applicant]
International Search Report and Written Opinion of the International Searching Authority, PCT Application Serial No. PCT/US2009/0054626, Apr. 5, 2010, 11 pp. [cited by applicant]
International Search Report and Written Opinion of the International Searching Authority, PCT Application Serial No. PCT/US2009/047999, Jan. 29, 2010, 11 pp. [cited by applicant]
Kiiskilä, “Recovery of sodium hydroxide from alkaline pulping liquors by smelt causticizing, Part II. Recations between sodium carbonate and titanium dioxide,” Paperi ja Puu, Papper och Trä, 1979, 5:394-401. [cited by applicant]
Kiiskilä, “Recovery of sodium hydroxide from alkaline pulping liquors by smelt causticizing, Part III. Alkali distribution in titanium dioxide causticizing,” Paperi ja Puu, Papper och Trä, 1979, 6:453-464. [cited by applicant]
Kutare, Examination Report, Indian Application No. 1814/CHENP/2011, dated Apr. 13, 2018, 5 pages. [cited by applicant]
Lackner et al., “Carbon dioxide from air,” 24th Annual Technical Conference on Coal Utilization, 1999, Clearwater, FL, 12 pages. [cited by applicant]
Maddern, “Mill-scale development of the DARS direct causticization process,” Pulp Pap. Candada, 1986, 87(10):T395-T399. [cited by applicant]
Mahmoudkhani and Keith, “Low-energy sodium hydroxide recovery for CO2 capture from atmospheric air-Thermodynamic analysis,” Int. J. Greenhouse Gas Control, 2009, 3:376-384. [cited by applicant]
Mahmoudkhani et al. “Low energy packed tower and caustic recovery for direct capture of CO2 from air,” Energy Procedia, 2009, 1:1535-1542. [cited by applicant]
Marley, Variflow nozzle cup, SPX Cooling Technologies, Inc., SP-VF, Dec. 2016, 2 pgs. [cited by applicant]
Nohlgren et al., “Model study of the direct causticization reaction between sodium trititanate and sodium carbonate,” The Canadian Journal of Chemical Engineering, Jun. 2000, vol. 78, pp. 529-539. [cited by applicant]
Nohlgren, “Recovery of kraft black liquor with direct causticization using titanates,” Ph.D. Thesis, Lulea University of Technology, Lulea, Sweden, 2002, 164 pages. [cited by applicant]
Non-Final Office Action dated Aug. 2, 2013 mailed from USPTO for U.S. Appl. No. 12/545,579, 16 pages. [cited by applicant]
Non-Final Office Action dated Jan. 6, 2011 mailed from USPTO for U.S. Appl. No. 12/488,230, 14 pages. [cited by applicant]
Non-Final Office Action dated May 17, 2011 mailed from USPTO for U.S. Appl. No. 12/545,579, 16 pages. [cited by applicant]
Palm et al., “Kinetic study of the direct causticization reaction involving titanates and titanium dioxide,” Chemical Engineering Journal. 1997, vol. 68, pp. 87-94. (Same as Above). [cited by applicant]
PCT International Preliminary Report on Patentability in International Appln. No. PCT/US2019/027698, dated Oct. 20, 2020, 8 pages. [cited by applicant]
Restriction Requirement dated Mar. 11, 2011 mailed from USPTO for U.S. Appl. No. 12/545,579, 8 pages. [cited by applicant]
Sinquefield et al., “Borate auto-causticization for low and high temperature black liquor gasification,” International Chemical Recovery Conference, Jun. 6-10, 2004, Charleston, SC, 6 pages. [cited by applicant]
Spector and Dodge, “Removal of carbon dioxide from atmospheric air,” Trans. Am. Inst. Chem. Eng., 1946, 42:827-848. [cited by applicant]
Stolaroff et al., “Carbon dioxide capture from atmospheric air using sodium hydroxide spray,” Environ. Sci. Technol., 2008, 42:2728-2735. [cited by applicant]
Supplementary European Search Report, Application No. 09808878.4, dated Oct. 25, 2012, 4 pages. [cited by applicant]
Tepe and Dodge, “Absorption of carbon dioxide by sodium hydroxide solutions in a packed column,” Trans. Am. Inst. Chem. Eng., 1943, 39:255-276. [cited by applicant]
Variable Flow Over Cooling Towers for Energy Savings, Connecticut ASHRAE Chapter, Nov. 2016, retrieved from the Internet: URL<http://ctashrae.org/downloads/Meeting_Presentations/variable_flow_presentation_connecticut_as… [cited by applicant]
Yusuf and Cameron, “Decarbonization reactions between sodium metaborate and sodium carbonate,” Ind. Eng. Chem. Res., 2004, 43:8148-8154. [cited by applicant]
Zeman and Lackner, “Capturing carbon dioxide directly from the atmosphere,” World Resource Review, 2004, 16(2):157-172. [cited by applicant]
Zeman, “Direct Extraction of CO2 from Air, a Fixed Solution for a Mobile Problem,” The First Regional Symposium on Carbon Management, May 23, 2006, Dhahran, Saudi Arabia, 12 pages. [cited by applicant]
Zeman, “Energy and material balance of CO2 capture from ambient air,” Environ. Sci. Technol., 2007, 41(21):7558-7563. [cited by applicant]
Zeng and van Heiningen, “Pilot fluidized-bed testing of kraft black liquor gasification and its direct causticization with TiO2,” J. Pulp Paper Sci., 1997, 23(11):J511-J516. [cited by applicant]
Zeng et al., “A Mathematic Model for Direct Causticization of Na2C03 with Ti02 in a Semi-batch Reactor,” The Canadian Journal of Chemical Engineering, Oct. 2002, vol. 80, pp. 948-953. [cited by applicant]
Zou, “Recovery of kraft black liquor including direct causticization,” Ph.D. Thesis, McGill University, Montreal, Quebec, 1991, 231 pages. [cited by applicant]
European Extended Search Report in EP Appln. No. 19788037.0, dated Apr. 23, 2021, 8 pages. [cited by applicant]