Heterophasic polypropylene with propylene hexene random copolymer as matrix
The present invention is directed to a heterophasic polypropylene composition with improved sterilization resistance and optical properties for blow molding applications, in particular for use in the blow-fill-seal process for preparing bottles. The present invention is further directed to a process for producing such a polypropylene composition using a single-site catalyst and to a container produced from such a polypropylene composition by blow molding, like a bottle, in particular a blow-fill-seal bottle, with improved haze before and after sterilization. The polypropylene composition comprises a blend of a propylene copolymer comprising 2.5 to 12.0 wt % of 1-hexene as a comonomer, and having a melt flow rate MFR 2 of 0.5 to 20.0 g/10 min, and an ethylene homo- or copolymer having a melt flow rate MFR 2 of 0.05 to 30.0 g/10 min and a density of 850 to 940 kg/m 3 , wherein the xylene cold solubles (XCS) content of the polypropylene composition is from 5.0 to 30.0 wt %.
1. A polypropylene composition comprising a blend of:
(a) a propylene copolymer comprising 2.5 to 12.0 wt %, based on the weight of the propylene copolymer, of 1-hexene as a comonomer, and having a melt flow rate MFR 2 of 0.5 to 20.0 g/10 min, and
(b) an ethylene homo- or copolymer having a melt flow rate MFR 2 of 0.05 to 30.0 g/10 min and a density of 850 to 940 kg/m 3 , wherein the ethylene copolymer comprised by the ethylene homo- or copolymer (b) is an ethylene propylene copolymer comprising 6.0 to 25.0 wt % of ethylene,
wherein the xylene cold solubles (XCS) content of the polypropylene composition is from 5.0 to 30.0 wt %, and
wherein the content of hexane extractables according to FDA of the polypropylene composition is below 1.5 wt %.
2. The polypropylene composition according to claim 1 , wherein the blend comprises 70.0 to 95.0 wt %, based on the weight of the blend, of the propylene copolymer (a), and 5.0 to 30.0 wt %, based on the weight of the blend, of the ethylene homo- or copolymer (b).
3. The polypropylene composition according to claim 1 , wherein the melting temperature T m of the polypropylene composition is higher than 120° C.
4. The polypropylene composition according to claim 1 , wherein the melt flow rate MFR 2 of the polypropylene composition is from 1.0 to 12.0 g/10 min.
5. The polypropylene composition according to claim 1 , wherein the propylene copolymer (a) comprises in addition 0.1 to 3.0 wt %, based on the weight of the propylene copolymer, of ethylene as a comonomer.
6. The polypropylene composition according to claim 1 , wherein the content of 1-hexene of the polypropylene composition is 2.0 to 7.0 wt %.
7. The polypropylene composition according to claim 1 , further comprising from 0.001 to 0.50 wt % of an α-nucleating agent.
8. The polypropylene composition according to claim 1 , wherein the propylene copolymer (a) comprises two propylene copolymer fractions produced in two different polymerization steps, wherein the first fraction has a lower melt flow rate MFR 2 than the second fraction, and wherein the polymerization step for obtaining the second fraction is carried out in the presence of the first fraction.
9. A process for preparing a polypropylene composition according to claim 1 , comprising the following steps:
(i) polymerising propylene and 1-hexene, and optionally ethylene, in the presence of a single-site catalyst to obtain a fraction (a) having a content of 1-hexene of 2.5 to 12.0 wt %, and optionally a content of ethylene of 0.1 to 3.0 wt %, and having a melt flow rate MFR 2 of 0.5 to 20.0 g/10 min, and
(ii) polymerising ethylene, or ethylene and propylene, to obtain a fraction (b) having a melt flow rate MFR 2 of 0.05 to 30.0 g/10 min and a density of 850 to 940 kg/m 3 .
10. The process according to claim 9 , wherein the polymerization step (ii) is carried out in the presence of fraction (a).
11. The process according to claim 9 , wherein the polymerization step (i) is carried out in the absence of fraction (b) and the polymerization step (ii) is carried out in the absence of fraction (a), and fraction (a) and fraction (b) are mixed by compounding to obtain the blend.
12. The process according to claim 1 , wherein the single-site catalyst is a metallocene catalyst with the metal being Zr or Hf, and the ligand being based on two 4-phenylindene moieties being linked by the moiety —SiR 2 —, wherein each R is independently a C 1 -C 20 -hydrocarbyl group or tri(C 1 -C 20 -alkyl)silyl.
13. A container comprising a polypropylene composition according to claim 1 , wherein the container is produced from the polypropylene composition by blow molding.