Negative electrode plate, secondary battery, battery module, battery pack, and apparatus
View Patent ↗This application provides a negative electrode plate, a secondary battery, a battery module, a battery pack, and an apparatus. The negative electrode plate includes a negative current collector and a plurality of active substance layers on the negative current collector. The plurality of active substance layers include at least a first active substance layer and a second active substance layer. The first active substance layer includes a first negative active substance, and the second active substance layer includes a second negative active substance. A ratio of gram capacity of the negative active substance of the first active substance layer to thickness of the first active substance layer is 3.5-10.0. A ratio of gram capacity of the negative active substance of the second active substance layer to thickness of the second active substance layer is 6.5-23.0.
1. A secondary battery, comprising a positive electrode plate, a negative electrode plate, a separator, and an electrolyte, wherein the negative electrode plate comprises:
a negative current collector, a first active substance layer disposed on at least one surface of the negative current collector, and a second active substance layer disposed on the first active substance layer,
wherein the first active substance layer comprises a first negative active substance, and the second active substance layer comprises a second negative active substance; and
in the negative electrode plate, the following relationships are satisfied: 3.5≤A/B≤10.0, and 6.5≤C/D≤23.0 and A>C, wherein
A is gram capacity of the first negative active substance, in mAh/g;
B is thickness of the first active substance layer, in μm;
C is gram capacity of the second negative active substance, in mAh/g; and
D is thickness of the second active substance layer, in μm.
2. The secondary battery according to claim 1 , wherein in the negative electrode plate, 6.5≤A/B≤8.5.
3. The secondary battery according to claim 1 , wherein in the negative electrode plate, 8.0≤C/D≤11.0.
4. The secondary battery according to claim 1 , wherein in the negative electrode plate, 0.70≤C/A≤0.98.
5. The secondary battery according to claim 1 , wherein in the negative electrode plate, B≥D.
6. The secondary battery according to claim 5 , wherein in the negative electrode plate, 0.2≤DB≤1.0.
7. The secondary battery according to claim 1 , wherein in the negative electrode plate, C/D≥A/B.
8. The secondary battery according to claim 1 , wherein in the negative electrode plate, 355 mAh/g≤A≤380 mAh/g; or
35 μm≤B≤105 μm; or
250 mAh/g≤C≤350 mAh/g; or
15 μm≤D≤55 μm.
9. The secondary battery according to claim 8 , wherein in the negative electrode plate, 360 mAh/g≤A≤375 mAh/g.
10. The secondary battery according to claim 8 , wherein in the negative electrode plate, 40 μm≤B≤60 μm.
11. The secondary battery according to claim 8 , wherein in the negative electrode plate, 300 mAh/g≤C≤345 mAh/g.
12. The secondary battery according to claim 8 , wherein in the negative electrode plate, 20 μm≤D≤40 μm.
13. The secondary battery according to claim 1 , wherein the first negative active substance and the second negative active substance are independently selected from one or more of artificial graphite, natural graphite, carbonaceous mesophase spherules, soft carbon, and hard carbon.
14. The secondary battery according to claim 13 , wherein a degree of graphitization of the first negative active substance is greater than a degree of graphitization of the second negative active substance.
15. The secondary battery according to claim 1 , wherein the first negative active substance is selected from one or more of artificial graphite and natural graphite.
16. The secondary battery according to claim 1 , wherein the second negative active substance is artificial graphite.
17. A battery module, comprising the secondary battery according to claim 1 .
18. A battery pack, comprising the battery module according to claim 17 .
19. An apparatus, comprising the secondary battery according to claim 1 , wherein the secondary battery is used as a power source of the apparatus.