Separator for lead acid battery
[Problem] A separator for a valve-regulated lead acid battery that has suppressed losing the thickness (reduction of compressive force) of the separator and prolonged a cycle lifetime is provided. [Solution] The separator for a valve-regulated lead acid battery includes a sheet formed through wet papermaking mainly containing glass fibers, and has an MD/CD strength ratio shown by the following expression (1) of 1.5 or less and 60 kPa compressive force in liquid immersion shown by the following expression (2) of 65% or more: MD/CD strength ratio=MD strength/CD strength (Expression 1) 60 kPa compressive force in liquid immersion(%) (pressure force after liquid immersion/compressive force in liquid immersion)×100. (Expression 2)
1 . A separator for a valve-regulated lead acid battery, comprising:
a sheet initially formed through wet papermaking substantially containing at least glass fibers, the sheet having a length, width, and thickness,
the orientation of the glass fibers being randomized to allow for strengthening compressive force for the sheet,
the glass fibers substantially overlapping with each other for suppressing a loss in the thicknesses of the glass fibers,
the sheet having surface tension being dispersed in many directions for suppressing the lost in the thickness of the separator, and
the proportion of glass fibers that are in the vertical direction is higher than the proportion of glass fibers that are in the non-vertical direction with respect to the horizontal plane of the sheet resulting in the enhancement of the pressure force of the sheet,
wherein a paper machine controller is configured to control the jet-wire ratio and the inclination angle of the forming wire, so as to provide the resulting separator for a lead acid battery having an MD/CD strength ratio shown by the following expression (1) of 1.5 or less and a 60 kPa compressive force in liquid immersion shown by the following expression (2) of 65% or more to secure a prolonged cycle lifetime for the separator:
MD/CD strength ratio=MD strength/CD strength, (Expression 1)
wherein the sheet formed through wet papermaking cut in a direction in parallel to the flow direction in the papermaking to a length of 15 cm and a width of 2.5 cm is designated as an MD specimen, and the sheet formed through wet papermaking cut in a direction perpendicular to the flow direction in the papermaking to a length of 15 cm and a width of 2.5 cm is designated as a CD specimen, which are measured with a tensile tester under conditions of a chuck distance of 10 cm and a tensile speed of 25 mm/min, and the maximum breaking strengths of the MD specimen and the CD specimen are designated as the MD strength and the CD strength respectively,
60 kPa compressive force in liquid immersion(%)=(pressure force after liquid immersion/compressive force in liquid immersion)×100, (Expression 2)
wherein 10 sheets of the sheet formed through wet papermaking are cut into 10 cm×10 cm and are laminated to prepare a specimen, which is sandwiched between a fixed plate and a movable plate, the movable plate is moved toward the fixed plate at a moving speed of 1 mm/min to compress the sheet under pressure of 60 kPa, which is designated as the compressive force in liquid immersion, and the pressure force of the specimen after immersing in a sulfuric acid solution having a specific gravity of 1.3 and allowing to stand for 1 hour is designated as the pressure force after liquid immersion.
2 . The separator for a valve-regulated lead acid battery according to claim 1 , wherein the glass fibers have an average fiber diameter of 1.5 μm or less.
3 . The separator for a valve-regulated lead acid battery according to claim 2 , wherein the glass fibers have an average fiber diameter of 1.0 μm or less.
4 . The separator for a valve-regulated lead acid battery according to claim 1 , wherein the separator contains no binder component.
5 . The separator for a valve-regulated lead acid battery according to claim 1 , which further includes controlling the jet-wire ratio close to 1, and controlling the inclination angle of the forming wire to 10 degrees or more.