Positive electrode plate and electrochemical device
The present application relates to a positive electrode plate and an electrochemical device. The positive electrode plate includes a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating including a polymer matrix and a conductive material, wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin, and when the safety coating and the positive active material layer are collectively referred to as a positive film layer, the positive film layer includes Na ions and/or K ions at a content of 100 ppm or more, and has an absorption peak at 1646 cm −1 in infrared absorption spectrum. The positive electrode plate may improve safety performance at elevated temperature of the electrochemical device by quickly disconnecting the circuit at high temperature conditions or when an internal short circuit occurs.
1. A positive electrode plate comprising a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating comprising a polymer matrix and a conductive material, wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin, and when the safety coating and the positive active material layer are collectively referred to as a positive film layer, the positive film layer comprises Na ions and/or K ions at a content of 100 ppm or more, and has an absorption peak at 1646 cm −1 in infrared absorption spectrum.
2. The positive electrode plate as claimed in claim 1 , wherein the safety coating further comprises an inorganic filler, and based on the total weight of the polymer matrix, the conductive material and the inorganic filler being 100%,
weight percentage of the polymer matrix is from 35 wt % to 75 wt %;
weight percentage of the conductive material is from 5 wt % to 25 wt %; and
weight percentage of the inorganic filler is from 10 wt % to 60 wt %.
3. The positive electrode plate as claimed in claim 1 , wherein the polymer matrix is selected from at least one of polyvinylidene fluoride (PVDF), carboxylic acid modified PVDF, acrylic acid modified PVDF, polyvinylidene chloride (PVDC), carboxylic acid modified PVDC, acrylic acid modified PVDC, PVDF copolymers, and PVDC copolymers.
4. The positive electrode plate as claimed in claim 1 , wherein the conductive material is selected from at least one of a conductive carbon-based material, a conductive metal material, and a conductive polymer material,
preferably, the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, and carbon nanofibers;
preferably, the conductive metal material is selected from at least one of Al powder, Ni powder, and gold powder; and
preferably, the conductive polymer material is selected from at least one of conductive polythiophene, conductive polypyrrole, and conductive polyaniline.
5. The positive electrode plate as claimed in claim 2 , wherein the inorganic filler is selected from at least one of metal oxides, non-metal oxides, metal carbides, non-metal carbides, and inorganic salts, all optionally modified with at least one of a conductive carbon coating, a conductive metal coating and a conductive polymer coating:
preferably, the inorganic filler of the safety coating is at least one of magnesium oxide, aluminum oxide, titanium dioxide, zirconium oxide, silicon dioxide, silicon carbide, boron carbide, calcium carbonate, aluminum silicate, calcium silicate, potassium titanate, barium sulfate, lithium cobalt oxide, lithium nickel manganese cobalt oxide, lithium nickel manganese aluminum oxide, lithium iron phosphate, lithium vanadium phosphate, lithium cobalt phosphate, lithium manganese phosphate, lithium manganese iron phosphate, lithium iron silicate, lithium vanadium silicate, lithium cobalt silicate, lithium manganese silicate, spinel lithium manganese oxide, spinel lithium nickel manganese oxide, and lithium titanate, all optionally modified with a conductive carbon coating, a conductive metal coating, or a conductive polymer coating;
preferably the inorganic filler has an average particle diameter D of 100 nm≤D≤10 μm, and
preferably the inorganic filler has a specific surface area (BET) of not more than 500 m 2 /g.
6. The positive electrode plate as claimed in claim 2 , wherein based on the total weight of the polymer matrix, the conductive material and the inorganic filler being 100%,
the weight percentage of the polymer matrix is from 50 wt % to 75 wt %;
the weight percentage of the conductive material is from 5 wt % to 20 wt %; and
the weight percentage of the inorganic filler is from 15 wt % to 45 wt %.
7. The positive electrode plate as claimed in claim 1 , wherein the weight ratio of the polymer matrix to the conductive material is 2 or more and 8 or less.
8. The positive electrode plate as claimed in claim 1 , wherein the safety coating has a thickness H of 1 μm≤H≤20 μm.
9. The positive electrode plate as claimed in claim 1 , wherein the positive film layer has an elongation of 30% or more, preferably of 80% or more, more preferably of 80% or more and 300% or less.
10. An electrochemical device comprising the positive electrode plate as claimed in claim 1 , which is a capacitor, a primary battery or a secondary battery.
11. A battery module comprising the battery as described in claim 10 .
12. A battery pack comprising the battery module according to claim 11 .
13. A device comprising the battery as described in claim 10 , wherein the battery is used as a power source of the device; preferably, the device comprises an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, an electric bicycle, an electric scooter, an electric golf cart, an electric truck, an electric ship, or an energy storage system.
14. The positive electrode plate as claimed in claim 4 , wherein the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, and carbon nanofibers.
15. The positive electrode plate as claimed in claim 4 , wherein the conductive metal material is selected from at least one of Al powder, Ni powder, and gold powder.
16. The positive electrode plate as claimed in claim 4 , wherein the conductive polymer material is selected from at least one of conductive polythiophene, conductive polypyrrole, and conductive polyaniline.
17. The positive electrode plate as claimed in claim 5 , wherein the inorganic filler of the safety coating is at least one of magnesium oxide, aluminum oxide, titanium dioxide, zirconium oxide, silicon dioxide, silicon carbide, boron carbide, calcium carbonate, aluminum silicate, calcium silicate, potassium titanate, barium sulfate, lithium cobalt oxide, lithium nickel manganese cobalt oxide, lithium nickel manganese aluminum oxide, lithium iron phosphate, lithium vanadium phosphate, lithium cobalt phosphate, lithium manganese phosphate, lithium manganese iron phosphate, lithium iron silicate, lithium vanadium silicate, lithium cobalt silicate, lithium manganese silicate, spinel lithium manganese oxide, spinel lithium nickel manganese oxide, and lithium titanate, all optionally modified with a conductive carbon coating, a conductive metal coating, or a conductive polymer coating.
18. The positive electrode plate as claimed in claim 5 , wherein the inorganic filler has an average particle diameter D of 100 nm≤D≤10 μm.
19. The positive electrode plate as claimed in claim 5 , wherein the inorganic filler has a specific surface area (BET) of not more than 500 m 2 /g.
20. The positive electrode plate as claimed in claim 9 , wherein the positive film layer has an elongation of 80% or more and 300% or less.