POSITIVE ELECTRODE PLATE AND ELECTROCHEMCIAL DEVICE
This application relates to a positive electrode plate and an electrochemical device. The positive electrode plate includes a current collector, a positive electrode active material layer and a safety coating disposed between the current collector and the positive electrode active material layer; wherein the safety coating includes a polymer matrix, a conductive material and an inorganic filler; and wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure. When the electrochemical device (such as a capacitor, a primary battery, or a secondary battery) is in a high temperature condition or an internal short circuit occurs, the positive electrode plate can quickly disconnect the circuit, thereby improving the high temperature safety of the electrochemical device.
1 . A positive electrode plate, comprising a current collector, a positive electrode active material layer and a safety coating disposed between the current collector and the positive electrode active material layer; wherein the safety coating comprises a polymer matrix, a conductive material and an inorganic filler; and wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure.
2 . The positive electrode plate according to claim 1 , wherein based on the total weight of the polymer matrix, the conductive material and the inorganic filler as 100%,
the polymer matrix is present in an amount of from 35 wt % to 75 wt %,
the conductive material is present in an amount of from 5 wt % to 25 wt %, and
the inorganic filler is present in an amount of from 10 wt % to 60 wt %.
3 . The positive electrode plate according to claim 1 , wherein the fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure is obtained by crosslinking with a crosslinking agent; and the crosslinking agent is selected from at least one of polyisocyanates, polyamines, polyols, glycidyl ethers, glyoxal, aziridine, inorganic substances, organosilicons, benzenesulfonic acids, olefinically unsaturated compounds, organic peroxides, and metal organic compounds.
4 . The positive electrode plate according to claim 1 , wherein the polymer matrix is selected from at least one of polyvinylidene fluoride (PVDF), carboxylic acid modified PVDF, acrylic acid modified PVDF, polyvinylidene chloride (PVDC), carboxylic acid modified PVDC, acrylic acid modified PVDC, PVDF copolymers, and PVDC copolymers, all having a crosslinked structure.
5 . The positive electrode plate according to claim 1 , wherein the conductive material is selected from at least one of a conductive carbon-based material, a conductive metal material, and a conductive polymer material.
6 . The positive electrode plate according to claim 1 , wherein the inorganic filler is selected from at least one of metal oxides, a non-metal oxides, metal carbides, non-metal carbides, and inorganic salts, all optionally modified with at least one of a conductive carbon coating, a conductive metal coating or a conductive polymer coating.
7 . The positive electrode plate according to claim 6 , wherein the inorganic filler is selected from at least one of magnesium oxide, aluminum oxide, titanium dioxide, zirconium oxide, silicon dioxide, silicon carbide, boron carbide, calcium carbonate, aluminum silicate, calcium silicate, potassium titanate, barium sulfate, lithium cobalt oxide, lithium manganese oxide, lithium nickel oxide, lithium nickel manganese oxide, lithium nickel manganese cobalt oxide, lithium nickel manganese aluminum oxide, lithium iron phosphate, lithium vanadium phosphate, lithium cobalt phosphate, lithium manganese phosphate, lithium iron silicate, lithium vanadium silicate, lithium cobalt silicate, lithium manganese silicate, and lithium titanate, all optionally modified with at least one of a conductive carbon coating, a conductive metal coating or a conductive polymer coating.
8 . The positive electrode plate according to claim 1 , wherein the safety coating has a thickness H of 1 μm≤H≤20 μm.
9 . The positive electrode plate according to claim 1 , wherein the current collector is a porous aluminum-containing current collector.
10 . An electrochemical device, comprising the positive electrode plate according to claim 1 , wherein the electrochemical device is a capacitor, a primary battery or a secondary battery.
11 . A battery module, comprising the battery as described in claim 10 .
12 . A battery pack, comprising the battery module according to claim 11 .
13 . A device, comprising the battery as defined in claim 10 as a power source of the device.
14 . The positive electrode plate according to claim 3 , wherein the polyisocyanates are selected from at least one of JQ-1, JQ-1E, JQ-2E, JQ-3E, JQ-4, JQ-5, JQ-6, PAPI, emulsifiable MDI, and tetraisocyanate.
15 . The positive electrode plate according to claim 3 , wherein the polyols are selected from at least one of polyethylene glycol, polypropylene glycol, and trimethylolpropane.
16 . The positive electrode plate according to claim 3 , wherein the olefinically unsaturated compounds are selected from at least one of styrene, α-methylstyrene, acrylonitrile, acrylic acid, methacrylic acid, acrylates.
17 . The positive electrode plate according to claim 5 , wherein the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, and carbon nanofibers.
18 . The positive electrode plate according to claim 5 , wherein the conductive metal material is selected from at least one of Al powder, Ni powder, and gold powder.
19 . The positive electrode plate according to claim 5 , wherein the conductive polymer material is selected from at least one of conductive polythiophene, conductive polypyrrole, and conductive polyaniline.
20 . The positive electrode plate according to claim 7 , wherein the inorganic filler has an average particle size D of 100 nm≤D≤10 μm, and/or the conductivity σ of the inorganic filler satisfies 10 −3 S/m≤σ≤10 2 S/m.