Aqueous dispersion of ethylene-carboxylic acid copolymer and method of preparing the same
A method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to exemplary embodiments of the present invention includes: mixing 30% by weight or more of an ethylene-(meth)acrylic acid copolymer, a basic compound, and water to form a mixed solution; and adding an inorganic salt compound to the mixed solution. Therefore, the aqueous dispersion of the ethylene-carboxylic acid copolymer may be effectively dispersed.
1. A method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer, comprising:
mixing 30% by weight or more of an ethylene-(meth)acrylic acid copolymer, a basic compound, and water to form a mixed solution; and
adding, as an inorganic salt compound, 0.01 to 0.04% by weight of calcium chloride (CaCl 2 ) or 0.07 to 0.3% by weight of sodium sulfite (Na 2 SO 3 ) to the mixed solution.
2. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the step of forming the mixed solution comprises stirring the mixture at a temperature of 80° C. or higher.
3. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the step of adding the inorganic salt compound comprises adding an aqueous solution of the inorganic salt compound.
4. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the step of adding the inorganic salt compound comprises stirring the mixture at a temperature of 60 to 80° C.
5. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the ethylene-(meth)acrylic acid copolymer comprises 70 to 85% by weight of ethylene-derived unit and 15 to 30% by weight of (meth)acrylic acid-derived unit.
6. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the ethylene-(meth)acrylic acid copolymer has a weight average molecular weight (Mw) of 10,000 to 60,000.
7. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the basic compound is mixed in an amount of 1 to 12% by weight based on the total weight of the mixed solution.
8. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein a viscosity of the mixed solution before adding the inorganic salt compound is 6,000 cPs or more, and the viscosity of the aqueous dispersion solution with the inorganic salt compound added thereto is 5,000 cPs or less.
9. The method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to claim 1 , wherein the aqueous dispersion including the ethylene-(meth)acrylic acid copolymer and the inorganic salt has a viscosity of 60% or less based on the viscosity of the mixed solution including the ethylene-(meth)acrylic acid copolymer.
10. An aqueous dispersion of an ethylene-carboxylic acid copolymer comprising:
30% by weight or more of an ethylene-(meth)acrylic acid copolymer,
a basic compound,
0.01 to 0.04% by weight of calcium chloride (CaCl 2 ) or 0.07 to 0.3% by weight of sodium sulfite (Na 2 SO 3 ), and
water as the balance.
11. The aqueous dispersion of the ethylene-carboxylic acid copolymer according to claim 10 , wherein the ethylene-(meth)acrylic acid copolymer comprises 70 to 85% by weight of ethylene-derived unit and 15 to 30% by weight of (meth)acrylic acid-derived unit.
12. The aqueous dispersion of the ethylene-carboxylic acid copolymer according to claim 10 , wherein the basic compound is included in an amount of 1 to 12% by weight based on the total weight of the aqueous dispersion.