IP Library Granted Patent US 11,307,493
Granted Patent B2
US 11,307,493 · App. 17/067,526 · Granted Apr 19, 2022

Microlithographic fabrication of structures

Inventors: Vikramjit Singh (Pflugerville, TX); Kang Luo (Austin, TX); Michael Nevin Miller (Austin, TX); Shuqiang Yang (Austin, TX); Frank Y. Xu (Austin, TX)
Assignee: Molecular Imprints, Inc.
G03F7/0002G03F7/7035
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Quick Facts
Patent No.
US 11,307,493
App. No.
17/067,526
Granted
Apr 19, 2022
Kind
B2
Abstract

Micro- and nano-patterns in imprint layers formed on a substrate and lithographic methods for forming such layers. The layers include a plurality of structures, and a residual layer having a residual layer thickness (RLT) that extends from the surface of the substrate to a base of the structures, where the RLT varies across the surface of the substrate according to a predefined pattern.

Claims (33)

1. A method of fabricating a variable depth pattern, the method comprising:

dispensing, on a surface of a substrate, an imprint fluid according to a predetermined pattern;

contacting the imprint fluid with a surface of an imprint lithography template such that the imprint fluid fills features in the surface of the imprint lithography template; and

solidifying the imprint fluid into a patterned layer, thereby forming, in the patterned layer:

structures that correspond to the features of the imprint lithography template, and

a residual layer having a residual layer thickness (RLT) that extends from the surface of the substrate to a base of one of the structures, wherein a first RLT of a first portion of the patterned layer is different from a second RLT of a second portion of the patterned layer, wherein an RLT in a region between the first portion and the second portion varies gradually from the first RLT to the second RLT; and

etching the patterned layer and the substrate, wherein a depth of features etched into the substrate varies according to variation in the RLT, wherein the imprint lithography template is a master template and, after etching, the substrate is a sub-master lithography template.

2. The method of claim 1 , wherein dispensing the imprint fluid comprises dispensing the imprint fluid in a pattern of drops, wherein a volume of the drops varies according to the predetermined pattern.

3. The method of claim 2 , wherein the pattern of drops corresponds to a fixed drop density in a predetermined region.

4. The method of claim 2 , wherein the pattern of drops corresponds to a varying drop density in a predefined region.

5. The method of claim 1 , wherein dispensing the imprint fluid comprises dispensing the imprint fluid with a jetting dispense system.

6. The method of claim 1 , wherein the features in the imprint lithography template have a uniform feature depth.

7. The method of claim 1 , further comprising:

dispensing, on a surface of a second substrate, a second imprint fluid, a volume of which is substantially uniform across the surface of the substrate; and

contacting the second imprint fluid with a surface of the sub-master lithography template such that the imprint fluid fills features in the surface of the sub-master lithography template, thereby forming, in the second imprint fluid, structures and a residual layer having a RLT that varies in accordance with variations in a dimension of features etched into the sub-master lithography template.

8. The method of claim 1 , wherein the features in the imprint lithography template have a varying feature depth.

9. The method of claim 1 , wherein the predetermined pattern corresponds to a diffraction efficiency output map.

10. The method of claim 1 , wherein the structures are nano-structures.

11. The method of claim 1 , wherein the structures are micro-structures.

12. The method of claim 1 , wherein a difference between the first RLT and the second RLT is between 5 nm and 500 nm.

13. A method of patterning an imprint fluid, the method comprising:

dispensing, on a surface of a substrate, the imprint fluid, a volume of which varies across the surface of the substrate according to a predetermined pattern;

contacting the imprint fluid with a surface of an imprint lithography template such that the imprint fluid fills features in the surface of the imprint lithography template, thereby forming, in the imprint fluid, structures and a residual layer having a residual layer thickness (RLT) that extends from the surface of the substrate to a base of one of the structures, wherein the RLT varies across the surface of the substrate according to the volume per unit area of the imprint fluid, wherein a first RLT of a first portion of the patterned layer is different from a second RLT of a second portion of the patterned layer, wherein an RLT in a region between the first portion and the second portion varies gradually from the first RLT to the second RLT;

solidifying the imprint fluid into a patterned layer; and

etching the patterned layer and the substrate, wherein a depth of features etched into the substrate varies according to variation in the RLT, wherein the imprint lithography template is a master template and, after etching, the substrate is a sub-master lithography template.

14. The method of claim 13 , wherein dispensing the imprint fluid comprises dispensing the imprint fluid in a predefined pattern that corresponds to a volume needed to fill the features in the imprint lithography template.

15. An optical device comprising:

a substrate; and

a polymer imprint resist on a surface of the substrate, the polymer imprint resist comprising:

a plurality of structures forming a diffraction pattern; and

a residual layer having a residual layer thickness (RLT) that extends from the surface of the substrate to a base of one of the plurality of structures, wherein the RLT varies across the surface of the substrate according to a predefined pattern, wherein a depth of each structure of the plurality of structures varies according to

variation in the RLT, wherein variations in the RLT correspond to a diffraction efficiency mapping of a different diffraction grating having a uniform RLT.

16. The device of claim 15 , wherein the polymer imprint resist is an Ultra Violet light curable Nano-Imprint Lithography (UV-NIL) resist.

Assignments (3)
SECURITY INTEREST Recorded Oct 28, 2025
From: MAGIC LEAP, INC.; MENTOR ACQUISITION ONE, LLC; MOLECULAR IMPRINTS, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 073388/0027 →
SECURITY INTEREST Recorded May 24, 2022
From: MOLECULAR IMPRINTS, INC.; MENTOR ACQUISITION ONE, LLC; MAGIC LEAP, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 060338/0665 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 13, 2020
From: SINGH, VIKRAMJIT; LUO, KANG; MILLER, MICHAEL NEVIN; YANG, SHUQIANG; XU, FRANK Y.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 054039/0015 →