Method of lithiation electrodes for energy storage devices

1. A method for lithiation of an electrode for use in an energy storage device, the method comprising:

providing a cell assembly including a negative electrode, at least one separator, and a positive electrode, the negative electrode or the positive electrode being an electrode to be lithiated, the cell assembly being disposed in a cell packaging case;

providing a piece of lithium metal with predetermined weight;

attaching the piece of lithium metal to a current collector of the electrode to be lithiated or to a metal tab connected to or from a current collector of the electrode to be lithiated, the piece of lithium metal being positioned above or below the cell assembly such that a lithiation path by which Li ions pass from the piece of lithium metal to the electrode to be lithiated is along a surface of an active layer of the electrode to be lithiated; and,

after said attaching, and with the cell assembly being disposed in the cell packaging case, filling the cell packaging case with an electrolyte containing a lithium salt.

2. The method of claim 1 , further comprising assembling the cell assembly without a dry box or dry room.

3. The method of claim 1 , wherein the cell assembly includes a plurality of negative electrodes, a plurality of separators, and a plurality of positive electrodes.

4. The method of claim 1 , further comprising positioning the piece of lithium metal on a longitudinal axis of the cell assembly.

5. The method of claim 1 , wherein the current collector is formed from a solid metal foil.

6. The method of claim 1 , wherein the attaching includes attaching the piece of lithium metal to the current collector or to the metal tab via a conductive path that does not include the cell packaging case.

7. The method of claim 1 , further comprising, after lithiation of the electrode to be lithiated, removing the remains of the piece of lithium metal from the cell packaging case.