Polyurethane polymer having a hardness of less than or equal to 60 shore A and good abrasion resistance
The present invention relates to a novel thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, to compositions containing this polyurethane polymer, to the uses thereof and to articles containing this polyurethane polymer.
1. A roller or a wheel, comprising: a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, obtained by reacting the following components
(A) one or more essentially linear polyether polyols and/or polyester polyols, where a total amount of component (A) has an average molecular weight Mn in a range from 500 g/mol to 5000 g/mol, Mn having been calculated from an OH number determined according to DIN53240,
(B) one or more diisocyanates comprising 2-methyl-1,5-diisocyanatopentane, 1,4-diisocyanatobutane (BDI), 1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2,2,4-trimethyl-1,6-diisocyanatohexane, 2,4,4-trimethyl-1,6-diisocyanatohexane, or diphenylmethane diisocyanate isomer mixtures having a diphenylmethane 4,4′-diisocyanate content of >96% by weight,
(C) one or more linear diols having a molecular weight of 62 g/mol to 500 g/mol,
(D) optionally in the presence of one or more catalysts,
(E) optionally in the presence of one or more additives, auxiliaries additions, or a combination thereof, and
(F) optionally in the presence of one or more monofunctional chain terminators,
wherein the reaction is performed in a solvent-free fashion and comprises:
1) providing and reacting a mixture made up of the total amount of component (A), a portion of component (B) and optionally a portion or a total amount of component (D), component (E), component (F), or a combination thereof to give an NCO-functional prepolymer, wherein there is a molar ratio of component (B) to component (A) in a range from 1.1:1.0 to 5.0:1.0,
2) reacting the NCO-functional prepolymer with a total amount of component (C) to obtain an OH-functional prepolymer, optionally in the presence of a further portion of component (D), component (E), component (F), or a combination thereof,
3) reacting the OH-functional prepolymer with a remaining amount of component (B) and any remaining amount of component (D), component (E), component (F), or a combination thereof to obtain a thermoplastically processible polyurethane, wherein during all process steps there is a molar ratio of component (B) to a sum total of component (A) and component (C) in a range from 0.9:1.0 to 1.2:1.0.
2. The roller or the wheel according to claim 1 , wherein the roller or the wheel is part of a transport container, a suitcase, a sports bag, a leisure bag, a pannier, furniture, a medical device, a hospital bed, a shopping trolley, a lift, or an escalator.
3. The roller or the wheel according to claim 1 , wherein the rollers or the wheel is a drive rollers or a pressure rollers.
4. The roller or wheel according to claim 1 , wherein the polyurethane composition comprises an additive and is also plasticizer-free.
5. The roller or the wheel according to claim 4 , wherein the roller or the wheel is part of a transport container, a suitcase, a sports bag, a leisure bag, a pannier, furniture, a medical device, a hospital bed, a shopping trolley, a lift, or an escalator.
6. The roller or the wheel according to claim 4 , wherein the roller or the wheel is a drive roller.
7. A shoe sole, comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, obtained by reacting the following components
(A) one or more essentially linear polyether polyols and/or polyester polyols, where a total amount of component (A) has an average molecular weight Mn in a range from 500 g/mol to 5000 g/mol, Mn having been calculated from an OH number determined according to DIN53240,
(B) one or more diisocyanates comprising 2-methyl-1,5-diisocyanatopentane, 1,4-diisocyanatobutane (BDI), 1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2,2,4-trimethyl-1,6-diisocyanatohexane, 2,4,4-trimethyl-1,6-diisocyanatohexane, or diphenylmethane diisocyanate isomer mixtures having a diphenylmethane 4,4′-diisocyanate content of >96% by weight,
(C) one or more linear diols having a molecular weight of 62 g/mol to 500 g/mol,
(D) optionally in the presence of one or more catalysts,
(E) optionally in the presence of one or more additives, auxiliaries additions, or a combination thereof, and
(F) optionally in the presence of one or more monofunctional chain terminators,
wherein the reaction is performed in a solvent-free fashion and comprises:
1) providing and reacting a mixture made up of the total amount of component (A), a portion of component (B) and optionally a portion or a total amount of component (D), component (E), component (F), or a combination thereof to give an NCO-functional prepolymer, wherein there is a molar ratio of component (B) to component (A) in a range from 1.1:1.0 to 5.0:1.0,
2) reacting the NCO-functional prepolymer with a total amount of component (C) to obtain an OH-functional prepolymer, optionally in the presence of a further portion of component (D), component (E), component (F), or a combination thereof,
3) reacting the OH-functional prepolymer with a remaining amount of component (B) and any remaining amount of component (D), component (E), component (F), or a combination thereof to obtain a thermoplastically processible polyurethane, wherein during all process steps there is a molar ratio of component (B) to a sum total of component (A) and component (C) in a range from 0.9:1.0 to 1.2:1.0.
8. The shoe sole according to claim 7 , wherein the shoe sole is a shoe outsole.
9. The shoe sole according to claim 7 , wherein the polyurethane composition comprises an additive and is also plasticizer-free.
10. The shoe sole according to claim 9 , wherein the shoe sole is a shoe outsole.
11. An elastic bearing element or an elastic connecting element, comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, obtained by reacting the following components
(A) one or more essentially linear polyether polyols and/or polyester polyols, where a total amount of component (A) has an average molecular weight Mn in a range from 500 g/mol to 5000 g/mol, Mn having been calculated from an OH number determined according to DIN53240,
(B) one or more diisocyanates comprising 2-methyl-1,5-diisocyanatopentane, 1,4-diisocyanatobutane (BDI), 1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2,2,4-trimethyl-1,6-diisocyanatohexane, 2,4,4-trimethyl-1,6-diisocyanatohexane, or diphenylmethane diisocyanate isomer mixtures having a diphenylmethane 4,4′-diisocyanate content of >96% by weight,
(C) one or more linear diols having a molecular weight of 62 g/mol to 500 g/mol,
(D) optionally in the presence of one or more catalysts,
(E) optionally in the presence of one or more additives, auxiliaries additions, or a combination thereof, and
(F) optionally in the presence of one or more monofunctional chain terminators,
wherein the reaction is performed in a solvent-free fashion and comprises:
1) providing and reacting a mixture made up of the total amount of component (A), a portion of component (B) and optionally a portion or a total amount of component (D), component (E), component (F), or a combination thereof to give an NCO-functional prepolymer, wherein there is a molar ratio of component (B) to component (A) in a range from 1.1:1.0 to 5.0:1.0,
2) reacting the NCO-functional prepolymer with a total amount of component (C) to obtain an OH-functional prepolymer, optionally in the presence of a further portion of component (D), component (E), component (F), or a combination thereof,
3) reacting the OH-functional prepolymer with a remaining amount of component (B) and any remaining amount of component (D), component (E), component (F), or a combination thereof to obtain a thermoplastically processible polyurethane, wherein during all process steps there is a molar ratio of component (B) to a sum total of component (A) and component (C) in a range from 0.9:1.0 to 1.2:1.0.
12. The elastic bearing element or an elastic connecting element according to claim 11 , wherein the elastic bearing element or the elastic connecting element is a damper bearing, a spring seat, a door stop damper, or a bearing sleeve.
13. The elastic bearing element according to claim 11 , wherein the polyurethane composition comprises an additive and is also plasticizer-free.
14. The elastic bearing element or the elastic connecting element according to claim 13 , wherein the elastic bearing element or the elastic connecting element is a damper bearing, a spring seat, a door stop damper, or a bearing sleeve.
15. A component for automobile interiors, comprising a thermoplastically processible polyurethane polymer having a hardness of 60 Shore A, obtained by the components and process according to claim 1 .
16. The component for automobile interiors according to claim 15 , wherein the component for automobile interiors is part of a roller blind, a sliding cover, a louvre shutter, a cupholder, a gearshift cover, a storage compartment, a door handle, a charging cradle, an anti-slip mat, an injection-moulded gaiter, a blow-moulded gaiter, a flexible seal, a rotary switch, a pushbutton switch, or a door stop.
17. The component for automobile interiors according to claim 15 , wherein the polyurethane composition comprises an additive and is also plasticizer-free.
18. The component for automobile interiors according claim 17 , wherein the component for automobile interiors is part of a roller blind, a sliding cover, a louvre shutter, a cupholder, a gearshift cover, a storage compartment, a door handle, a charging cradle, an anti-slip mat, an injection-moulded gaiter, a blow-moulded gaiter, a flexible seal, a rotary switch, a pushbutton switch, or a door stop.