Liquid (meth)acrylic composition comprising a multistage polymer and a (meth)acrylic monomer, its method of preparation and its use
The present invention relates to a liquid (meth)acrylic composition comprising a (meth)acrylic monomer, a (meth)acrylic polymer and a multistage polymer. In particular the present invention it relates to liquid composition comprising a (meth)acrylic monomer, a (meth)acrylic polymer and a multistage polymer that can be used as a syrup and especially as a syrup for impregnation.
1. An impregnation process for impregnating a fibrous substrate, wherein said fibrous substrate comprises fibres having an aspect ratio of at least 1000 and said process comprises a step of impregnating said fibrous substrate with a liquid composition comprising:
a) a (meth)acrylic polymer (P1), having a mass average molecular weight Mw of less than 100,000 g/mol,
b) a multistage polymer in the form of core shell particles having a multilayer structure comprising at least one layer (A) comprising a polymer (A1) having a glass transition temperature below 0° C. and another layer (B) comprising a polymer (B1) having a glass transition temperature over 30° C., said layer (A) is made in the first stage of a multistage process forming the core for the polymer particle having the multilayer structure and
c) a (meth)acrylic monomer (M1) wherein the multistage polymer to monomer ratio by weight in the liquid composition is between 1/99 and 25/75.
2. The impregnation process according to claim 1 , wherein the (meth)acrylic polymer (P1) has a mass average molecular weight Mw between 5,000 g/mol and 70,000 g/mol.
3. The impregnation process according to claim 1 , wherein the (meth)acrylic polymer (P1) has a mass average molecular weight Mw between 6,000 g/mol and 50,000 g/mol.
4. The impregnation process according to claim 1 , wherein said multistage polymer is in form of core shell particles having a multilayer structure comprising at least one layer (A) comprising a polymer (A1) having a glass transition temperature below −5° C. and another layer (B) comprising a polymer (B1) having a glass transition temperature over 60° C., said layer (A) is made in the first stage of a multistage process forming the core for the polymer particle having the multilayer structure.
5. The impregnation process according to claim 1 , wherein the multistage polymer to monomer ratio by weight in the liquid composition is between 2/98 and 24/76.
6. The impregnation process according to claim 1 , wherein the (meth) acrylic polymer (P1) is soluble in the (meth)acrylic monomer (M1).
7. The impregnation process according to claim 1 , wherein the monomer (M1) is from the group consisting of acrylic acid, methacrylic acid, alkyl acrylic monomers, and alkyl methacrylic monomers and mixtures thereof, wherein the alkyl group has from 1 to 22 carbons that are either linear, branched or cyclic.
8. The impregnation process according to claim 1 , wherein the monomer (M1) is selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, ethyl acrylate, methacrylic acid, acrylic acid, n-butyl acrylate, iso-butyl acrylate, n-butyl methacrylate, iso-butyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, isobornyl acrylate, isobornyl methacrylate and mixtures thereof.
9. The impregnation process according to claim 1 , wherein the layer (A) is the first layer and that layer (B) comprising polymer (B1) is grafted on layer (A) comprising polymer (A1).
10. The impregnation process according to claim 1 , wherein the polymers (A1) and (B1) are acrylic or methacrylic polymers.
11. The impregnation process according to claim 1 , wherein the polymer (A1) comprises at least 50 weight percent of polymeric units coming from isoprene or butadiene.
12. The impregnation process according to claim 1 , wherein the (meth) acrylic polymer (P1) comprises from 50wt % to 100wt % methyl methacrylate.
13. The impregnation process according to claim 1 , wherein the (meth) acrylic polymer (P1) comprises between 0wt % and 50wt % of a functional monomer.
14. The impregnation process according to claim 13 , wherein the functional monomer is selected from the group consisting of glycidyl (meth)acrylate, acrylic or methacrylic acid, amides derived from acrylic or methacrylic acids, dimethylacrylamide, 2-methoxyethyl acrylate or methacrylate, 2-aminoethyl acrylates or methacrylates that are optionally quaternized, acrylate or methacrylate monomers comprising a phosphonate or phosphate group, alkyl imidazolidinone (meth) acrylates, polyethylene glycol (meth) acrylates.