Quantum dot encapsulation techniques
Quantum dots and methods of making quantum dots are described. A method begins with forming quantum dots having a core-shell structure with a plurality of ligands on the shell structure. The method includes exchanging the plurality of ligands with a plurality of second ligands. The plurality of second ligands have a weaker binding affinity to the shell structure than the plurality of first ligands. The plurality of second ligands are then exchanged with hydrolyzed alkoxysilane to form a monolayer of hydrolyzed alkoxysilane on a surface of the shell structure. The method includes forming a barrier layer around the shell structure by using the hydrolyzed alkoxysilane as a nucleation center.
1. A method of making barrier layer coated quantum dots, the method comprising:
forming a solution of reverse micro-micelles using surfactants;
incorporating quantum dots into the reverse micro-micelles;
individually coating the quantum dots with a barrier layer to form the barrier layer coated quantum dots; and
performing an acid etch treatment of the barrier layer coated quantum dots.
2. The method of claim 1 , further comprising isolating the barrier layer coated quantum dots with the surfactants of the reverse micro-micelles disposed on the barrier layer after the performing of the acid etch treatment.
3. The method of claim 1 , wherein the incorporating of the quantum dots into the reverse micro-micelles comprises forming a first mixture of the quantum dots and the solution of reverse micelles.
4. The method of claim 1 , wherein the individually coating of the quantum dots with the barrier layer includes:
forming a second mixture of a precursor and the first mixture; and
forming a third mixture of a catalyst and the second mixture.
5. The method of claim 1 , wherein the performing of the acid etch treatment of the barrier layer quantum dots comprises forming a fourth mixture of an acid and the third mixture.
6. The method of claim 1 , wherein the performing of the acid etch treatment of the barrier layer quantum dots comprises:
selectively removing the catalyst; and
forming a fourth mixture of an acid and the third mixture.
7. The method of claim 1 , wherein the acid comprises acetic acid, hydrochloric acid, nitric acid, or a fatty acid.
8. The method of claim 1 , wherein the barrier layer coated quantum dots have a quantum yield between 50% to about 70%.