Method of increasing efficiency of chemical additives in a papermaking system
A method of increasing chemical efficiency of chemical additives in a papermaking system includes the steps of providing thick stock pulp comprising soluble lignin, process water, and at least about 2% by weight of cellulosic fiber based on total weight of thick stock pulp, and adding at least one organic polymer to the thick stock pulp to reduce the amount of soluble lignin therein. The organic polymer is chosen from cationic polymers, non-ionic polymers and combinations thereof.
1. A method of increasing chemical efficiency of chemical additives in a papermaking system, said method comprising the steps of:
providing thick stock pulp comprising soluble lignin, process water, and at least about 2% by weight of cellulosic fiber based on total weight of thick stock pulp, and
adding at least one organic polymer to the thick stock pulp to reduce the amount of soluble lignin therein; and
wherein the organic polymer is chosen from water dispersions of cationic polyacrylamides, water dispersions of polyethylene oxides, and combinations thereof,
wherein the cationic polyacrylamide has a molecular weight of from about 1,000,000 to about 10,000,000 Da,
wherein the polyethylene oxide has a molecular weight of greater than about 1,000,000 and less than about 10 million Da, and
wherein the organic polymer is added to the thick stock pulp in an amount of from about 0.05 to about 5 pounds per ton of oven dried pulp.
2. The method of claim 1 wherein the thick stock pulp is free of an enzyme.
3. The method of claim 1 wherein the thick stock pulp comprises at least about 3% by weight of the cellulosic fibers based on a total weight of the thick stock pulp and wherein the cellulosic fibers are derived from NSSC pulp, UBK pulp, OCC pulp, deinked pulp, virgin fiber, mechanical pulp, thermomechanical pulp or combinations thereof.
4. The method of claim 1 wherein the cationic polyacrylamides are derived from at least one monomer chosen from diallyldimethylammonium chloride, N,N-dialkylamminoalkyl (meth)acrylate and quaternaries thereof, N,N-dialkylamminoalkyl (meth) acrylamide and quaternaries thereof, epichlorohydrin-dimethylamine and combinations thereof.
5. The method of claim 1 wherein the reduction in the amount of soluble lignin in the process water is evidenced by at least a 5% reduction in absorbance in a UV-VIS spectra measured at about 280 nm after 24 hours as compared to process water that is free of the at least one organic polymer.
6. The method of claim 1 wherein the process water exhibits a chemical oxygen demand that is reduced by at least about 5% as compared to the chemical oxygen demand of process water that is free of at least one laccase enzyme and the at least one organic polymer.
7. The method of claim 1 further comprising the step of adding an inorganic coagulant to the process water wherein the inorganic coagulant is chosen from aluminum sulfate, aluminum chloride, aluminum chlorohydrate, polyaluminum chloride, polyaluminum sulfate, iron (III) chloride, iron (III) sulfate, iron (II) chloride, iron (II) sulfate, polyferrous sulfate, and combinations thereof.
8. The method of claim 1 further comprising the steps of
providing thin stock pulp, and
adding the at least one organic polymer to the thin stock pulp simultaneously with the step of adding the at least one organic polymer to the thick stock pulp.
9. The method of claim 1 that increases a pulp yield production by at least 1% as measured in tons of pulp produced per day.