Illumination device
To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100° C. to the emission intensity at 25° C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.
1. An illumination device comprising:
a holding case;
a plurality of light emitting device disposed at the holding case, each of the plurality of light emitting devices comprises a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and a phosphor; and
a diffusion plate disposed over the plurality of light emitting devices and diffusing the light from the plurality of light emitting devices;
wherein the phosphor comprises a red emitting phosphor containing Mn 4+ as an activated element and a green emitting phosphor.
2. An illumination device according to claim 1 , wherein the red emitting phosphor contains at least one element selected from the group consisting of alkali metal elements, alkaline earth metal elements and Zn, at least one element selected from the group consisting of Si, Ti, Zr, Hf, Sn, Al, Ga and In, and at least one member selected from halogen elements.
3. An illumination device according to claim 1 , wherein the red emitting phosphor has a chemical composition represented by the following formula (1′):
M I′ 2 M IV′ F 6 :R (1′) wherein M I′ is at least one element selected from the group consisting of K and Na, M IV′ is at least one metal element selected from the group consisting of Groups 4 and 14 of the Periodic Table comprising at least Si, and R is an activated element comprising at least Mn 4′ .
4. An illumination device according to claim 3 , wherein the proportion of Mn based on the total mols of M IV′ and Mn is at least 0.1 mol % and at most 40 mol %.
5. An illumination device according to claim 1 , wherein the red emitting phosphor having a specific surface area is at most 1.3 m 2 /g.
6. An illumination device according to claim 1 , wherein the particle size distribution of the red emitting phosphor has one peak value.
7. An illumination device according to claim 1 , wherein the quantile deviation of the particle size distribution is at most 0.6.
8. An illumination device according to claim 3 , wherein M I′ is K.
9. An illumination device according to claim 3 , wherein M IV′ is Si.
10. An illumination device according to claim 1 , wherein the red emitting phosphor has a weight-average median diameter D50 of at least 10 μm and at most 30 μm.
11. An illumination device according to claim 1 , wherein the specific surface area of the red emitting phosphor is at most 1.0 m 2 /g.
12. An illumination device according to claim 1 , wherein the quantile deviation of the particle size distribution is at most 0.25.
13. An illumination device according to claim 1 , wherein the green emitting phosphor has the emission peak wavelength between 500 nm and 550 nm.
14. An illumination device according to claim 1 , wherein the phosphor comprises β-SiAlON activated by europium.
15. An illumination device according to claim 1 , wherein the phosphor comprises a phosphor represented by RE 3 M 5 O 12 :Ce (wherein RE is at least one element selected from the group consisting of Y, Tb, Gd, Lu, and Sm, and M is at least one element selected from the group consisting of Al, Ga and Sc).
16. An illumination device according to claim 1 , wherein the phosphor comprises more red emitting phosphors consisting of (Sr,Ca)AlSiN 3 :Eu.
17. An illumination device according to claim 1 used as a backlight of an image display.
18. An image display device comprising: an illumination device according to claim 1 , and a color filter.