Solid state pretreatment of active materials for negative electrodes in electrochemical cells
Provided are methods for solid state pretreatment of active materials (e.g., prelithiation of silicon monoxide) while forming treated negative active material structures. Also provided are the formed structures, negative electrodes comprising these structures, and electrochemical cells comprising these electrodes. In some examples, silicon monoxide structures are mixed with lithium hydroxide structures or some other lithium-containing structures. The mixture is heated in an inert environment to form treated negative active material structures. These treated structures comprise various lithium-containing components, some of which trap lithium. When an electrochemical cell, formed with these treated negative active material structures, is initially charged and additional new lithium ions are introduced into the negative electrodes (e.g., from the positive electrode), a larger portion of these new lithium ions forms reversible components (rather than irreversible components) in the negative electrode than, for example, in a conventional cell without any such treatment.
1. A method of solid state pretreatment of active material structures to form treated negative active material structures for negative electrodes in electrochemical cells, the method comprising:
combining the active material structures and treatment material structures in a mixer,
the active material structures comprising SiO X such that X is between 0.9 and 1.0, and
the treatment material structures comprising a metal hydroxide or a metal oxide;
mixing the active material structures and the treatment material structures using the mixer thereby forming a mixture and ensuring uniform distribution of the active material structures and the treatment material structures in the mixture; and
heating the mixture of the active material structures and the treatment material structures in an environment comprising nitrogen and hydrogen thereby forming the treated negative active material structures, wherein:
the treated negative active material structures comprise one or more electrochemically active materials and one or more electrochemically inactive materials, and
the one or more electrochemically inactive materials comprise at least Li 6 Si 2 O 7 .
2. The method of claim 1 , wherein the metal hydroxide or the metal oxide of the treatment material structures comprises lithium.
3. The method of claim 1 , wherein the metal hydroxide or the metal oxide of the treatment material structures comprises one of lithium hydroxide (LiOH), lithium oxide (Li 2 O), or lithium peroxide (Li 2 O 2 ).
4. The method of claim 1 , wherein the metal hydroxide or the metal oxide of the treatment material structures comprises lithium oxide (LiO X ) such that X is between 0.5 and 1.
5. The method of claim 1 , wherein the mixture of the active material structures and the treatment material structures is heated to between 800° C. and 1000° C.
6. The method of claim 1 , wherein heating of the mixture of the active material structures and the treatment material structures removes water generated by reacting the active material structures and the treatment material structures.
7. The method of claim 1 , further comprising separating an unreacted portion of the treatment material structures from the treated negative active material structures.
8. The method of claim 1 , wherein a molar ratio of silicon to lithium in a mixture of the active material structures and the treatment material structures is at least 1.5.
9. The method of claim 1 , wherein a molar ratio of silicon to lithium in a mixture of the active material structures and the treatment material structures is at least 2.
10. The method of claim 1 , wherein mixing the active material structures and the treatment material structures comprises reducing size of the active material structures or the treatment material structures.
11. The method of claim 1 , wherein mixing the active material structures and the treatment material structures is performed in a ball mill.
12. The method of claim 1 , wherein separating an unreacted portion of the treatment material structures from the treated negative active material structures comprises: washing the treated negative active material structures with water; and drying the treated negative active material structures using a combination of heating and vacuum.
13. The method of claim 1 , wherein water content of the treated negative active material structures is less than 2% by weight.
14. The method of claim 1 , wherein heating the mixture of the active material structures and the treatment material structures is performed for a period between 30 minutes and 2 hours.
15. The method of claim 1 , wherein heating the mixture of the active material structures and the treatment material structures is performed at approximately 900° C.
16. The method of claim 1 , further comprising:
combining the treated negative active material structures with a polymer binder and a conductive additive to form a slurry; and
coating the slutty onto a current collector substrate.
17. The method of claim 1 , wherein the active material structures are in a form of particles, rods, tubes, or flakes.
18. The method of claim 1 , wherein the metal hydroxide or the metal oxide of the treatment material structures comprises lithium oxide (LiO X ) such that X is between 0.6 and 9.
19. The method of claim 1 , wherein a mean principal dimension of the treatment material structures is between 0.1 micrometers and 20 micrometers.
20. The method of claim 1 , wherein a mean principal dimension of the active material structures is between 0.1 micrometers and 20 micrometers.